The Characterization of Carbide Slag by Carbonation Curing and Its Enhancement Performance in Blended Cement Paste
Publication: Journal of Materials in Civil Engineering
Volume 36, Issue 1
Abstract
Capturing and using solid waste effectively has become a focus of attention. During this study, carbide slag (CS), a calcium-rich waste, was treated through carbonation. The characteristics of CS and carbonated carbide slag (CCS) were examined, and their influence on blended cement paste performance was investigated. The results showed that and were the main mineral composition in CS and CCS, respectively. The pH value of CS decreased with carbonation time, and the CS could absorb using a carbonation treatment. The presence of CCS in blended cement pastes accelerated cement hydration. It was found that cement pastes with CS had a reduced compressive strength, whereas the incorporation of less than 10% CCS improved the compressive strength. Calcium monocarbonate was detected in the hydration product of blended cement paste with CCS because of the reaction of in CCS with aluminate. In summary, carbonated carbide slag, as a novel -storage material, can enhance the performance of blended cement paste. This research promotes the application of CS as supplementary cementitious materials in cement-based materials.
Get full access to this article
View all available purchase options and get full access to this article.
Data Availability Statement
Some or all data, models, or code that support the findings of this study are available from the corresponding author upon reasonable request.
Acknowledgments
This research was supported by the Natural Science Foundation of the Jiangsu Higher Education Institutions of China (22KJB560030); the National Natural Science Foundation of China (52271230); Science and Technology program of Jiangsu province (BZ2020012); Key Research and Development Plan Science and Technology Demonstration Project of Shandong Province, Integrated Innovation and Demonstration of New Green Building Materials (2021SFGC0903); and the first batch of major scientific and technological research in China’s building materials industry “to select the best candidates for key research ” projects and joint projects of CNBM Innovation Technology Academy Co., Ltd.
References
Altiner, M. 2019. “Use of Taguchi approach for synthesis of calcite particles from calcium carbide slag for fixation by accelerated mineral carbonation.” Arabian J. Chem. 12 (4): 531–540. https://doi.org/10.1016/j.arabjc.2018.02.015.
Bai, J., H. Zhang, and L. Xiao. 2021. “Formation mechanism of carbide slag composite sustained-alkalinity-release particles for the source control of acid mine drainage.” Sci. Rep. 11 (1): 23793. https://doi.org/10.1038/s41598-021-03277-w.
Bonavetti, V., V. Rahhal, and E. Irassar. 2001. “Studies on the carboaluminate formation in limestone filler-blended cements.” Cem. Concr. Res. 31 (6): 853–859. https://doi.org/10.1016/S0008-8846(01)00491-4.
Cai, L., X. Li, B. Ma, and Y. Lv. 2018. “Effect of binding materials on carbide slag based high utilization solid-wastes autoclaved aerated concrete (HUS-AAC): Slurry, physic-mechanical property and hydration products.” Constr. Build. Mater. 188 (Nov): 221–236. https://doi.org/10.1016/j.conbuildmat.2018.08.115.
Chang, J., Y. Gu, and W. S. Ansari. 2020. “Mechanism of blended steel slag mortar with curing exposed to sulfate attack.” Constr. Build. Mater. 251 (Aug): 118880. https://doi.org/10.1016/j.conbuildmat.2020.118880.
Chen, T., M. Bai, and X. Gao. 2021a. “Carbonation curing of cement mortars incorporating carbonated fly ash for performance improvement and sequestration.” J. Util. 51 (Sep): 101633. https://doi.org/10.1016/j.jcou.2021.101633.
Chen, Z., R. Li, and J. Liu. 2021b. “Preparation and properties of carbonated steel slag used in cement cementitious materials.” Constr. Build. Mater. 283 (May): 122667. https://doi.org/10.1016/j.conbuildmat.2021.122667.
Dhandapani, Y., and M. Santhanam. 2017. “Assessment of pore structure evolution in the limestone calcined clay cementitious system and its implications for performance.” Cem. Concr. Compos. 84 (Nov): 36–47. https://doi.org/10.1016/j.cemconcomp.2017.08.012.
Escalante-Garcia, J. I. 2003. “Nonevaporable water from neat OPC and replacement materials in composite cements hydrated at different temperatures.” Cem. Concr. Res. 33 (11): 1883–1888. https://doi.org/10.1016/S0008-8846(03)00208-4.
Fang, D., L. Huang, Z. Fang, Q. Zhang, Q. Shen, Y. Li, X. Xu, and F. Ji. 2018. “Evaluation of porous calcium silicate hydrate derived from carbide slag for removing phosphate from wastewater.” Chem. Eng. J. 354 (Dec): 1–11. https://doi.org/10.1016/j.cej.2018.08.001.
Guo, W., Z. Zhang, Y. Bai, G. Zhao, Z. Sang, and Q. Zhao. 2021. “Development and characterization of a new multi-strength level binder system using soda residue-carbide slag as composite activator.” Constr. Build. Mater. 291 (Jul): 123367. https://doi.org/10.1016/j.conbuildmat.2021.123367.
Hanjitsuwan, S., T. Phoo-ngernkham, and N. Damrongwiriyanupap. 2017. “Comparative study using portland cement and calcium carbide residue as a promoter in bottom ash geopolymer mortar.” Constr. Build. Mater. 133 (Feb): 128–134. https://doi.org/10.1016/j.conbuildmat.2016.12.046.
He, D., J. Shu, X. Zeng, Y. Wei, M. Chen, D. Tan, and Q. Liang. 2022. “Synergistic solidification/ stabilization of electrolytic manganese residue and carbide slag.” Total. Environ. 810 (Mar): 152175. https://doi.org/10.1016/j.scitotenv.2021.152175.
He, Z., R. Cai, E. Chen, and S. Tang. 2019. “The investigation of early hydration and pore structure for limestone powder wastes blended cement pastes.” Constr. Build. Mater. 229 (Dec): 116923. https://doi.org/10.1016/j.conbuildmat.2019.116923.
Horpibulsuk, S., V. Munsrakest, A. Udomchai, A. Chinkulkijniwat, and A. Arulrajah. 2014. “Strength of sustainable non-bearing masonry units manufactured from calcium carbide residue and fly ash.” Constr. Build. Mater. 71 (Nov): 210–215. https://doi.org/10.1016/j.conbuildmat.2014.08.033.
Hou, G., Z. Yan, J. Sun, H. Naguib, B. Lu, and Z. Zhang. 2021. “Microstructure and mechanical properties of CO2-cured steel slag brick in pilot-scale.” Constr. Build. Mater. 271 (Feb): 121581. https://doi.org/10.1016/j.conbuildmat.2020.121581.
Jansen, D., F. Goetz-Neunhoeffer, B. Lothenbach, and J. Neubauer. 2012. “The early hydration of ordinary portland cement (OPC): An approach comparing measured heat flow with calculated heat flow from QXRD.” Cem. Concr. Res. 42 (1): 134–138. https://doi.org/10.1016/j.cemconres.2011.09.001.
Khan, R. I., W. Ashraf, and J. Olek. 2021. “Amino acids as performance-controlling additives in carbonation-activated cementitious materials.” Cem. Concr. Res. 147 (Sep): 106501. https://doi.org/10.1016/j.cemconres.2021.106501.
Le Cornec, D., Q. Wang, L. Galoisy, G. Renaudin, L. Izoret, and G. Calas. 2017. “Greening effect in slag cement materials.” Cem. Concr. Compos. 84 (Nov): 93–98. https://doi.org/10.1016/j.cemconcomp.2017.08.017.
Li, X., and K. Scrivener. 2022. “Impact of ZnO on hydration and C-S-H morphology at early ages.” Cem. Concr. Res. 154 (Apr): 106734. https://doi.org/10.1016/j.cemconres.2022.106734.
Liu, J., N. Farzadnia, C. Shi, and X. Ma. 2019. “Shrinkage and strength development of UHSC incorporating a hybrid system of SAP and SRA.” Cem. Concr. Compos. 97 (Mar): 175–189. https://doi.org/10.1016/j.cemconcomp.2018.12.029.
Lu, B., P. He, J. Liu, Z. Peng, B. Song, and X. Hu. 2021. “Microstructure of portland cement paste subjected to different concentrations and further water curing.” J. Util. 53 (Nov): 101714. https://doi.org/10.1016/j.jcou.2021.101714.
Lu, B., C. Shi, Z. Cao, M. Guo, and J. Zheng. 2019. “Effect of carbonated coarse recycled concrete aggregate on the properties and microstructure of recycled concrete.” J. Cleaner Prod. 233 (Oct): 421–428. https://doi.org/10.1016/j.jclepro.2019.05.350.
Lu, B., C. Shi, J. Zhang, and J. Wang. 2018. “Effects of carbonated hardened cement paste powder on hydration and microstructure of portland cement.” Constr. Build. Mater. 186 (Oct): 699–708. https://doi.org/10.1016/j.conbuildmat.2018.07.159.
Lu, L., P. Zhao, S. Wang, and Y. Chen. 2011. “Effects of calcium carbide residue and high-silicon limestone on synthesis of belite-barium calcium sulphoaluminate cement.” J. Inorg. Organomet. Polym. Mater. 21 (4): 900–905. https://doi.org/10.1007/s10904-011-9560-0.
Ma, M., H. Mehdizadeh, M. Z. Guo, and T. C. Ling. 2021a. “Effect of direct carbonation routes of basic oxygen furnace slag (BOFS) on strength and hydration of blended cement paste.” Constr. Build. Mater. 304 (Oct): 124628. https://doi.org/10.1016/j.conbuildmat.2021.124628.
Ma, Z., H. Liao, L. Wang, and F. Cheng. 2021b. “Effects of iron/silicon/magnesium/aluminum on CaO carbonation of in steel slag-based building materials during carbonation curing.” Constr. Build. Mater. 298 (Sep): 123889. https://doi.org/10.1016/j.conbuildmat.2021.123889.
Mao, Y., H. Wu, W. Wang, M. Jia, and X. Che. 2020. “Pretreatment of municipal solid waste incineration fly ash and preparation of solid waste source sulphoaluminate cementitious material.” J. Hazard. Mater. 385 (Mar): 121580. https://doi.org/10.1016/j.jhazmat.2019.121580.
Ouyang, X., L. Wang, S. Xu, Y. Ma, and G. Ye. 2020. “Surface characterization of carbonated recycled concrete fines and its effect on the rheology, hydration and strength development of cement paste.” Cem. Concr. Compos. 114 (Nov): 103809. https://doi.org/10.1016/j.cemconcomp.2020.103809.
Ozekmekci, M., and M. Copur. 2020. “Synthesis of and trimethyl borate by reaction of ulexite and methanol in the presence of CO2.” J. Util. 42 (Dec): 101321. https://doi.org/10.1016/j.jcou.2020.101321.
Panesar, D. K., and R. Zhang. 2020. “Performance comparison of cement replacing materials in concrete: Limestone fillers and supplementary cementing materials—A review.” Constr. Build. Mater. 251 (Aug): 118866. https://doi.org/10.1016/j.conbuildmat.2020.118866.
Phoo-ngernkham, T., C. Phiangphimai, D. Intarabut, S. Hanjitsuwan, N. Damrongwiriyanupap, L. Y. Li, and P. Chindaprasirt. 2020. “Low cost and sustainable repair material made from alkali-activated high-calcium fly ash with calcium carbide residue.” Constr. Build. Mater. 247 (Jun): 118543. https://doi.org/10.1016/j.conbuildmat.2020.118543.
Qin, Y., K. Zhang, and X. He. 2022. “Characteristics and mechanism of adsorption of tartaric acid by carbide slag ascertained and applied to prepare a binder.” J. Cleaner Prod. 337 (Feb): 130477. https://doi.org/10.1016/j.jclepro.2022.130477.
Torgal, F., J. Gomes, and S. Jalali. 2008. “Investigations on mix design of tungsten mine waste geopolymeric binder.” Constr. Build. Mater. 22 (9): 1939–1949. https://doi.org/10.1016/j.conbuildmat.2007.07.015.
Tsivilis, S., J. Tsantilas, G. Kakali, E. Chaniotakis, and A. Sakellariou. 2003. “The permeability of portland limestone cement concrete.” Cem. Concr. Res. 33 (9): 1465–1471. https://doi.org/10.1016/S0008-8846(03)00092-9.
Tu, Z., M. Z. Guo, C. S. Poon, and C. Shi. 2016. “Effects of limestone powder on precipitation in cured cement pastes.” Cem. Concr. Compos. 72 (Sep): 9–16. https://doi.org/10.1016/j.cemconcomp.2016.05.019.
Wang, D., C. Shi, N. Farzadnia, Z. Shi, and H. Jia. 2018. “A review on effects of limestone powder on the properties of concrete.” Constr. Build. Mater. 192 (Dec): 153–166. https://doi.org/10.1016/j.conbuildmat.2018.10.119.
Wang, Y., B. Lu, X. Hu, J. Liu, Z. Zhang, X. Pan, and C. Shi. 2021. “Effect of surface treatment on penetrability and microstructure of cement-fly ash–slag ternary concrete.” Cem. Concr. Compos. 123 (Oct): 104194. https://doi.org/10.1016/j.cemconcomp.2021.104194.
Yang, J., J. Zeng, X. He, Y. Su, H. Tan, and B. Strnadel. 2020. “Nano-carbide slag seed as a new type accelerator for portland cement.” Mater. Lett. 278 (Nov): 128464. https://doi.org/10.1016/j.matlet.2020.128464.
Yang, J., Y. Zhang, X. He, Y. Su, H. Tan, M. Ma, and B. Strnadel. 2021. “Heat-cured cement-based composites with wet-grinded fly ash and carbide slag slurry: Hydration, compressive strength and carbonation.” Constr. Build. Mater. 307 (Nov): 124916. https://doi.org/10.1016/j.conbuildmat.2021.124916.
Zhan, B. J., D. X. Xuan, C. S. Poon, and C. J. Shi. 2019. “Mechanism for rapid hardening of cement pastes under coupled -water curing regime.” Cem. Concr. Compos. 97 (Mar): 78–88. https://doi.org/10.1016/j.cemconcomp.2018.12.021.
Zhang, J., H. Tan, X. He, W. Yang, and X. Deng. 2020. “Utilization of carbide slag-granulated blast furnace slag system by wet grinding as low carbon cementitious materials.” Constr. Build. Mater. 249 (Jul): 118763. https://doi.org/10.1016/j.conbuildmat.2020.118763.
Zhang, Y., and X. Zhang. 2008. “Research on effect of limestone and gypsum on , and PC clinker system.” Constr. Build. Mater. 22 (8): 1634–1642. https://doi.org/10.1016/j.conbuildmat.2007.06.013.
Zhao, Y., J. Zhan, G. Liu, M. Zheng, R. Jin, L. Yang, L. Hao, X. Wu, X. Zhang, and P. Wang. 2017. “Evaluation of dioxins and dioxin-like compounds from a cement plant using carbide slag from chlor-alkali industry as the major raw material.” J. Hazard. Mater. 330 (May): 135–141. https://doi.org/10.1016/j.jhazmat.2017.02.018.
Information & Authors
Information
Published In
Copyright
© 2023 American Society of Civil Engineers.
History
Received: Dec 7, 2022
Accepted: Jun 8, 2023
Published online: Oct 25, 2023
Published in print: Jan 1, 2024
Discussion open until: Mar 25, 2024
Authors
Metrics & Citations
Metrics
Citations
Download citation
If you have the appropriate software installed, you can download article citation data to the citation manager of your choice. Simply select your manager software from the list below and click Download.