Interaction of Superplasticizers with : Understanding the Superplasticizer Compatibility with Cement
Publication: Journal of Materials in Civil Engineering
Volume 35, Issue 9
Abstract
The incompatibility between the superplasticizer (SP) and cement can cause problems with the cementitious materials’ fresh and hardened qualities, such as unstable workability, uncontrollable setting times, excessive air entrainment, and so on. In this paper, five various types of SPs were prepared. Their interaction with pure tricalcium aluminate () and its hydration products were investigated and their effect on the generation of Ettringite (AFt) and single-sulfur calcium sulphoaluminate hydrate (AFm) in paste and their compatibility with cement were also studied. The results demonstrate that after 15 min of cement hydration, the AFt and AFm content of mixture with polycarboxylate SP and sulfonated acetone-formaldehyde superplasticizer (PCA-SAF) is 124.6% and 24.8% higher than that of SAF, respectively, which decreases the consumption of SPs molecules and improves the compatibility of SAF with cement. Compared with polynaphthalene sulfonate superplasticizer (PNS), PCA-PNS dramatically enhanced the SP’s compatibility with cement. Accelerating the production of AFt and AFm during the early stages of cement hydration may be one method to increase SP–cement compatibility.
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Data Availability Statement
Some or all data, models, or code that support the findings of this study are available from the corresponding author upon reasonable request.
Acknowledgments
The authors gratefully acknowledge the financial support from Funding: This work was supported by the National Natural Science Foundation of China (Grant Nos. 52130806, 51978318, and 52008191).
Author contributions: Xuping Ji—conceptualization, methodology, investigation, formal analysis, writing (original draft, review, and editing); Tinghong Pan—conceptualization, methodology, writing (review and editing, supervision, formal analysis); Wenhao Zhao—conceptualization, methodology, writing (review and editing); Jianzhong Liu—conceptualization, methodology, investigation, formal analysis; Jianfang Sha—methodology, investigation, formal analysis, writing (review and editing); and Fangyu Han—methodology, investigation, formal analysis.
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Published In
Journal of Materials in Civil Engineering
Volume 35 • Issue 9 • September 2023
Copyright
© 2023 American Society of Civil Engineers.
History
Received: Jul 8, 2022
Accepted: Jan 25, 2023
Published online: Jun 17, 2023
Published in print: Sep 1, 2023
Discussion open until: Nov 17, 2023
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