Technical Papers
Jul 5, 2023

Experimental Study on the Droplet Transport and Dynamic Behavior in Flow Channel with Microprotrusions of PEMFC

Publication: Journal of Energy Engineering
Volume 149, Issue 5

Abstract

Water management plays a crucial role in the performance of proton exchange membrane fuel cells (PEMFC). In this paper, to speed up the removal of water in the flow channel, the microprotrusions are fabricated on the flow channel surface by using laser remelting, and the surface is then sprayed with nanohydrophobic materials. The contact angle of the surface after spraying the hydrophobic material and laser processing increases from 115° to 132° when only the hydrophobic material is sprayed. Through visualization experiments, the movements of droplets in the smooth and microstructured flow channel are compared at different gas inlet pressures and different water inlet mass flows. The results show that the contact form of droplets with smooth surface is a solid-liquid contact, whereas there is also a liquid-gas contact with a microstructured surface. The main movement form of droplets in the smooth flow channel is sliding, whereas in the microstructured flow channel it is rolling. Under different experimental conditions, the movement speed of droplets in the microstructured flow channel is faster than that of the smooth flow channel, which indicates that the flow channel with microprotrusions has a better drag reduction performance. As the gas inlet pressure increases, the initial diameter of the droplet gradually decreased, and the velocity of the droplet increases. The water inlet mass flow has little effect on the oscillation amplitude of the droplets in the smooth flow channel, whereas in the microstructured flow channel, the droplet oscillation amplitude increases with the increase of the water inlet velocity. This work provides a new choice for the design of a flow channel.

Get full access to this article

View all available purchase options and get full access to this article.

Data Availability Statement

Some or all data, models, or code that support the findings of this study are available from the corresponding author upon reasonable request (Figs. 116).

Acknowledgments

This work was supported by the Postgraduate Research & Practice Innovation Program of Jiangsu Province (Grant No. KYCX21_3353), the Carbon Peak and Carbon Neutral Technology Innovation Fund Project of Jiangsu Province (Grant No. BE2022001-4), and the Yangzhou Industrial Foresight and Common Key Technologies Project (Grant No. YZ20222028).

References

Amamiya, I., and S. Tanaka. 2019. “Current topics proposed by PEFC manufacturers, etc. Current status and topics of fuel cells for FCV: In hydrogen, fuel cell project evaluation, and issue sharing week.” [In Japanese.] Accessed June 20, 2019. https://www.nedo.go.jp/content/100895101.pdf.
Andersson, M., A. Mularczyk, A. Lamibrac, S. B. Beale, J. Eller, W. Lehnert, and F. N. Büchi. 2018. “Modeling and synchrotron imaging of droplet detachment in gas channels of polymer electrolyte fuel cells.” J. Power Sources 404 (Nov): 159–171. https://doi.org/10.1016/j.jpowsour.2018.10.021.
Anyanwu, I. S., Z. Niu, D. Jiao, A. U. H. Najmi, Z. Liu, and K. Jiao. 2020. “Liquid water transport behavior at GDL-channel interface of a wave-like channel.” Energies 13 (11): 2726–2745. https://doi.org/10.3390/en13112726.
Bao, Z., Z. Niu, and K. Jiao. 2019. “Analysis of single- and two-phase flow characteristics of 3D fine mesh flow field of proton exchange membrane fuel cells.” J. Power Sources 438 (Oct): 226995. https://doi.org/10.1016/j.jpowsour.2019.226995.
Bozorgnezhad, A., M. Shams, H. Kanani, M. Hasheminasab, and G. Ahmadi. 2016. “Two-phase flow and droplet behavior in microchannels of PEM fuel cell.” Int. J. Hydrogen Energy 41 (42): 19164–19181. https://doi.org/10.1016/j.ijhydene.2016.09.043.
Cano, Z. P., D. Banham, S. Ye, A. Hintennach, J. Lu, M. Fowler, and Z. Chen. 2018. “Batteries and fuel cells for emerging electric vehicle markets.” Nat. Energy 3 (4): 279–289. https://doi.org/10.1038/s41560-018-0108-1.
Chen, R., Y. Qin, S. Ma, and Q. Du. 2020. “Numerical simulation of liquid water emerging and transport in the flow channel of PEMFC using the volume of fluid method.” Int. J. Hydrogen Energy 45 (54): 29861–29873. https://doi.org/10.1016/j.ijhydene.2019.07.169.
Chen, X., Z. Yu, X. Wang, W. Li, Y. Chen, C. Jin, G. Gong, and Z. Wan. 2021. “Influence of wave parallel flow field design on the performance of PEMFC.” J. Energy Eng. 147 (1): 04020080. https://doi.org/10.1061/(ASCE)EY.1943-7897.0000735.
Chen, X., Y. Zhang, S. Xu, and F. Dong. 2023. “Bibliometric analysis for research trends and hotspots in heat and mass transfer and its management of proton exchange membrane fuel cells.” Appl. Energy 333 (Mar): 120611. https://doi.org/10.1016/j.apenergy.2022.120611.
Hickner, M. A., N. P. Siegel, K. S. Chen, D. N. McBrayer, D. S. Hussey, D. L. Jacobson, and M. Arif. 2006. “Real-time imaging of liquid water in an operating proton exchange membrane fuel cell.” J. Electrochem. Soc. 153 (5): A902–A908. https://doi.org/10.1149/1.2184893.
Hussaini, I. S., and C.-Y. Wang. 2009. “Visualization and quantification of cathode channel flooding in PEM fuel cells.” J. Power Sources 187 (2): 444–451. https://doi.org/10.1016/j.jpowsour.2008.11.030.
Itaoka, K., A. Saito, and K. Sasaki. 2017. “Public perception on hydrogen infrastructure in Japan: Influence of rollout of commercial fuel cell vehicles.” Int. J. Hydrogen Energy 42 (11): 7290–7296. https://doi.org/10.1016/j.ijhydene.2016.10.123.
Jiao, K., et al. 2021. “Designing the next generation of proton-exchange membrane fuel cells.” Nature 595 (7867): 361–369. https://doi.org/10.1038/s41586-021-03482-7.
Kramer, D., J. Zhang, R. Shimoi, E. Lehmann, A. Wokaun, K. Shinohara, and G. G. Scherer. 2005. “In situ diagnostic of two-phase flow phenomena in polymer electrolyte fuel cells by neutron imaging: Part A. Experimental, data treatment, and quantification.” Electrochim. Acta 50 (13): 2603–2614. https://doi.org/10.1016/j.electacta.2004.11.005.
Liu, H. C., W. M. Yang, J. Tan, and L. S. Cheng. 2019. “A fin-shaped flow channel enhances water removal performance in a proton exchange membrane fuel cell.” Fuel Cells 19 (1): 51–59. https://doi.org/10.1002/fuce.201800079.
Liu, Y., X. Luo, Z. Tu, and S. H. Chan. 2021. “Droplet dynamics in a proton exchange membrane fuel cell with ejector-based recirculation.” Energy Fuels 35 (14): 11533–11544. https://doi.org/10.1021/acs.energyfuels.1c01623.
Liu, Y., Z. Tu, and S. H. Chan. 2023. “Performance analysis and dynamic characteristics of a proton exchange membrane fuel cell with dual recirculation pumps for air-free applications.” J. Power Sources 566 (May): 232926–232934. https://doi.org/10.1016/j.jpowsour.2023.232926.
Madadi, F., A. Rezaeian, H. Edris, and M. Zhiani. 2020. “Influence of surface roughness and hydrophobicity of bipolar plates on PEM performance.” Surf. Coat. Technol. 389 (May): 125676–125685. https://doi.org/10.1016/j.surfcoat.2020.125676.
Nishida, K., Y. Kono, M. Sato, and D. Mizuguchi. 2016. “Acceleration of liquid water removal from cathode electrode of PEFC by combination of channel hydrophilization and diffusion medium perforation.” ECS Trans. 75 (14): 227–236. https://doi.org/10.1149/07514.0227ecst.
Nishida, K., R. Taniguchi, Y. Ishizaki, S. Tsushima, and S. Hirai. 2015. “Impacts of channel wettability and flow direction on liquid water transport in the serpentine flow field of a polymer electrolyte fuel cell.” J. Power Sources 275 (Feb): 447–457. https://doi.org/10.1016/j.jpowsour.2014.11.059.
Ous, T., and C. Arcoumanis. 2007. “Visualization of water droplets during the operation of PEM fuel cells.” J. Power Sources 173 (1): 137–148. https://doi.org/10.1016/j.jpowsour.2007.04.075.
Qin, Y., Q. Guo, R. Chen, Y. Zhuang, and Y. Wang. 2021. “Numerical investigation of water droplet impact on PEM fuel cell flow channel surface.” Renewable Energy 168 (May): 750–763. https://doi.org/10.1016/j.renene.2020.12.075.
Qiu, D., L. Peng, P. Yi, X. Lai, and W. Lehnert. 2018. “Flow channel design for metallic bipolar plates in proton exchange membrane fuel cells: Experiments.” Energy Convers. Manage. 174 (Oct): 814–823. https://doi.org/10.1016/j.enconman.2018.08.070.
Rahimi-Esbo, M., A. Ramiar, A. A. Ranjbar, and E. Alizadeh. 2017. “Design, manufacturing, assembling, and testing of a transparent PEM fuel cell for investigation of water management and contact resistance at dead-end mode.” Int. J. Hydrogen Energy 42 (16): 11673–11688. https://doi.org/10.1016/j.ijhydene.2017.02.030.
Shao, H., D. Qiu, L. Peng, P. Yi, and X. Lai. 2019. “Modeling and analysis of water droplet dynamics in the dead-ended anode gas channel for proton exchange membrane fuel cells.” Renewable Energy 138 (Aug): 842–851. https://doi.org/10.1016/j.renene.2019.02.028.
Shen, J., L. Zeng, Z. Liu, and W. Liu. 2019. “Performance investigation of PEMFC with rectangle blockages in gas channel based on field synergy principle.” Heat Mass Transfer 55 (3): 811–822. https://doi.org/10.1007/s00231-018-2473-5.
Wang, X., Y. Qin, S. Wu, X. Shangguan, J. Zhang, and Y. Yin. 2020. “Numerical and experimental investigation of baffle plate arrangement on proton exchange membrane fuel cell performance.” J. Power Sources 457 (May): 228034. https://doi.org/10.1016/j.jpowsour.2020.228034.
Wei, Y., Y. Zhao, and H. Yun. 2021. “Research on PEMFC internal temperature predictions and thermal management strategy based on a Kalman algorithm.” J. Energy Eng. 147 (3): 04021010. https://doi.org/10.1061/(ASCE)EY.1943-7897.0000753.
Wu, R., Y. M. Li, R. Chen, and X. Zhu. 2014. “Emergence of droplets from a bundle of tubes into a micro-channel gas stream: Application to the two-phase dynamics in the cathode of proton exchange membrane fuel cell.” Int. J. Heat Mass Transfer 75 (Aug): 668–684. https://doi.org/10.1016/j.ijheatmasstransfer.2014.04.009.
Wu, Y., J. I. S. Cho, T. P. Neville, Q. Meyer, R. Ziesche, P. Boillat, M. Cochet, P. R. Shearing, and D. J. L. Brett. 2018. “Effect of serpentine flow-field design on the water management of polymer electrolyte fuel cells: An in-operando neutron radiography study.” J. Power Sources 399 (Sep): 254–263. https://doi.org/10.1016/j.jpowsour.2018.07.085.
Xie, X., B. Yin, S. Xu, X. Chen, F. Dong, Y. Yu, X. Zhang, and H. Jia. 2021. “Influence of perforated gas diffusion layer micropore shape parameters on water removal in a proton exchange membrane fuel cell flow channel.” Int. J. Energy Res. 45 (10): 14630–14643. https://doi.org/10.1002/er.6724.
Yang, X. G., F. Y. Zhang, A. L. Lubawy, and C. Y. Wang. 2004. “Visualization of liquid water transport in a PEFC.” Electrochem. Solid-State Lett. 7 (11): A408. https://doi.org/10.1149/1.1803051.
Yin, Y., X. Shangguan, X. Ma, J. Zhang, and Y. Qin. 2019. “Influence of corner structure of fuel cell serpentine channel on water removal.” Int. J. Hydrogen Energy 45 (54): 29812–29823. https://doi.org/10.1016/j.ijhydene.2019.08.200.
Zhang, Q., R. Lin, L. Técher, and X. Cui. 2016. “Experimental study of variable operating parameters effects on overall PEMFC performance and spatial performance distribution.” Energy 115 (Nov): 550–560. https://doi.org/10.1016/j.energy.2016.08.086.
Zhang, Q., Z. Tong, S. Tong, and Z. Cheng. 2020. “Research on low-temperature heat exchange performance of hydrogen preheating system for PEMFC engine.” Int. J. Hydrogen Energy 45 (55): 30966–30979. https://doi.org/10.1016/j.ijhydene.2020.08.076.
Zhang, S., S. Xu, and F. Dong. 2023. “Effect of the shape parameter on droplet behavior in multiple channels of a proton-exchange membrane fuel cell.” J. Energy Eng. 149 (1): 04022047. https://doi.org/10.1061/(ASCE)EY.1943-7897.0000874.

Information & Authors

Information

Published In

Go to Journal of Energy Engineering
Journal of Energy Engineering
Volume 149Issue 5October 2023

History

Received: Mar 23, 2023
Accepted: May 15, 2023
Published online: Jul 5, 2023
Published in print: Oct 1, 2023
Discussion open until: Dec 5, 2023

Permissions

Request permissions for this article.

ASCE Technical Topics:

Authors

Affiliations

Ph.D. Student, School of Automotive and Traffic Engineering, Jiangsu Univ., 301 Xuefu Rd., Zhenjiang 212013, China. Email: [email protected]
Professor, School of Automotive and Traffic Engineering, Jiangsu Univ., 301 Xuefu Rd., Zhenjiang 212013, China (corresponding author). ORCID: https://orcid.org/0000-0003-1925-5858. Email: [email protected]
Ph.D. Student, School of Automotive and Traffic Engineering, Jiangsu Univ., 301 Xuefu Rd., Zhenjiang 212013, China. Email: [email protected]
Professor, School of Automotive and Traffic Engineering, Jiangsu Univ., 301 Xuefu Rd., Zhenjiang 212013, China. Email: [email protected]
Xuan Xie, Ph.D. [email protected]
School of Automotive and Traffic Engineering, Jiangsu Univ., 301 Xuefu Rd., Zhenjiang 212013, China. Email: [email protected]

Metrics & Citations

Metrics

Citations

Download citation

If you have the appropriate software installed, you can download article citation data to the citation manager of your choice. Simply select your manager software from the list below and click Download.

Cited by

  • Enhancing Proton-Exchange Membrane Fuel-Cell Heat Transfer Performance with Embedded Cooling Channel Design: A Systematic Numerical Study, Journal of Energy Engineering, 10.1061/JLEED9.EYENG-5099, 150, 1, (2024).

View Options

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Media

Figures

Other

Tables

Share

Share

Copy the content Link

Share with email

Email a colleague

Share