Influence of Thermo-Oxidative Aging on the Properties of SBS-Modified Asphalt Binders
Publication: Journal of Materials in Civil Engineering
Volume 35, Issue 3
Abstract
The superior performance of styrene-butadiene-styrene (SBS) modified asphalt makes it widely used in asphalt pavement construction. However, SBS-modified asphalt pavement still faces an aging problem. Aging causes the performance of asphalt materials to decline and many pavement diseases. The dosage of SBS commonly used in industry is generally between 3% and 4.5%, and the performance of SBS with a high dosage needs to be explored. Therefore, in this paper, 12 modified binders were prepared with blending amounts of 3%, 5%, and 7% and the type of modifiers as linear and star. The softening point increment (SPI), viscosity aging index (VAI), rutting factor index (RFI), complex modulus aging index (CMAI), and phase angle aging index (PAAI) were used to study the antiaging performance of SBS-modified asphalt. Fourier transform infrared spectroscopy (FTIR) and gel permeation chromatography (GPC) were used to study the microscopic and structural changes that occur during the aging process of modified asphalt. The result shows that when the amount of the same type of modifier is 3%–7%, the higher the amount of modifier, the better the performance of the modified asphalt. At the same content, a star modifier is not necessarily better than a linear modifier. For the same type of modifier, the larger the amount, the better the antiaging performance of the modified asphalt. Given an increase in aging time, the deterioration of the asphalt performance will deepen. Aging leads to the enhanced high-temperature performance of asphalt. The macroscopic performance of asphalt aging can be explained by the microscopic view. The aging process of modified asphalt is the cumulative process of oxidation products.
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Data Availability Statement
Some or all of the data, models, or code that support the findings of this study are available from the corresponding author on reasonable request.
Acknowledgments
This study was supported by the National Key R&D Program of China (No. 2018YFE0103800), the Special Fund for Basic Scientific Research of Central College of Chang’an University (Nos. 300102219308 and 300102219316), science and technology plan project of Zhejiang highway and transportation management center (No. 211821200009), and science and technology planning project of Zhejiang Provincial Department of transportation (No. 2021041). The authors gratefully acknowledge their financial support.
References
Airey, G. D. 2003. “Rheological properties of styrene butadiene styrene polymer modified road bitumens.” Fuel 82 (14): 1709–1719. https://doi.org/10.1016/S0016-2361(03)00146-7.
ASTM. 2013. Standard test method for penetration of bituminous materials. ASTM D5. West Conshohocken, PA: ASTM.
ASTM. 2014. Standard test method for softening point of bitumen (ring-and-ball apparatus). ASTM D36. West Conshohocken, PA: ASTM.
ASTM. 2015a. Standard test method for determining the rheological properties of asphalt binder using a dynamic shear rheometer. ASTM D7175. West Conshohocken, PA: ASTM.
ASTM. 2015b. Standard test method for viscosity determination of asphalt at elevated temperatures using a rotational viscometer. ASTM D4402. West Conshohocken, PA: ASTM.
ASTM. 2017. Standard test method for ductility of asphalt materials. ASTM D113. West Conshohocken, PA: ASTM.
Bai, M. 2017. “Investigation of low-temperature properties of recycling of aged SBS modified asphalt binder.” Constr. Build. Mater. 150 (Sep): 766–773. https://doi.org/10.1016/j.conbuildmat.2017.05.206.
Chen, H., and B. Wang. 2008. “Modification of rutting factor of SBS block copolymer modified-asphalt.” J. Tongji Univ. Nat. Sci. Ed. 36 (10): 1384–1387. https://doi.org/10.3321/j.issn:0253-374X.2008.10.014.
Cong, P., J. Wang, Z. Zhou, and H. Zhang. 2020. “Preparation of rejuvenating agent and property evaluation of rejuvenated SBS modified asphalt binders.” Constr. Build. Mater 233 (Feb): 117911. https://doi.org/10.1016/j.conbuildmat.2019.117911.
Cui, Y., S. Cui, and L. Guo. n.d. “Research on performance and mechanism of recycled SBS modified asphalt.” J. Build. Mater. 1–13.
Dong, W., W. Guan, and W. Huang. 2018. “Low-temperature performance analysis of SBS modified asphalt under different aging process.” J. Build. Mater. 21 (2): 268–274. https://doi.org/10.3969/j.issn.1007-9629.2018.02.015.
Geng, J., Q. Zhang, and J. Dai. 2011. “Degradation process of SBS in modified asphalt based on gel permeation chromatography analysis.” New Build. Mater. 38 (5): 87–90. https://doi.org/10.3969/j.issn.1001-702X.2011.05.025.
Lamontagne, J., P. Dumas, V. Mouillet, and J. Kister. 2001. “Comparison by Fourier transform infrared (FTIR) spectroscopy of different aging techniques: Application to road bitumens.” Fuel 80 (4): 483–488. https://doi.org/10.1016/S0016-2361(00)00121-6.
Leng, B., M. Chen, and S. Wu. 2014. “Research on physical properties of recycled asphalt with waste vegetable oil.” Highway 59 (2): 175–179.
Li, D., Z. Li, and Y. Guo. 2014. “A study on the influence and improvement measures of colloidal asphaltene on crude oil.” Appl. Mech. Mater. 556–562 (May): 571–574. https://doi.org/10.4028/www.scientific.net/AMM.556-562.571.
Li, H., X. Huang, and H. Wang. 2005. “Water aging of asphalt during its service life of pavements.” Acta Petrolei Sin. (Pet. Process. Sect.) 21 (4): 75–78. https://doi.org/10.3969/j.issn.1001-8719.2005.04.012.
Lu, X., and U. Isacsson. 1997. “Rheological characterization of styrene-butadiene-styrene copolymer modified bitumens.” Constr. Build. Mater. 11 (1): 23–32. https://doi.org/10.1016/S0950-0618(96)00033-5.
Lu, X., and U. Isacsson. 1998. “Chemical and rheological evaluation of ageing properties of SBS polymer modified bitumens.” Fuel 77 (9–10): 961–972. https://doi.org/10.1016/S0016-2361(97)00283-4.
Lu, X., and U. Isacsson. 2002. “Effect of ageing on bitumen chemistry and rheology.” Constr. Build. Mater. 16 (1): 15–22. https://doi.org/10.1016/S0950-0618(01)00033-2.
Lu, X., U. Isacsson, and J. Ekblad. 1998. “Low-temperature properties of styrene–butadiene–styrene polymer modified bitumens.” Constr. Build. Mater. 12 (8): 405–414. https://doi.org/10.1016/S0950-0618(98)00032-4.
Luo, Y., K. Zhang, P. Li, J. Yang, and X. Xie. 2019. “Performance evaluation of stone mastic asphalt mixture with different high viscosity modified asphalt based on laboratory tests.” Constr. Build. Mater. 225 (Nov): 214–222. https://doi.org/10.1016/j.conbuildmat.2019.07.119.
Ma, J., G. Sun, D. Sun, F. Yu, M. Hu, and T. Lu. 2021. “Application of gel permeation chromatography technology in asphalt materials: A review.” Constr. Build. Mater. 278 (Apr): 122386. https://doi.org/10.1016/j.conbuildmat.2021.122386.
Moghaddam, T. B., and H. Baaj. 2016. “The use of rejuvenating agents in production of recycled hot mix asphalt: A systematic review.” Constr. Build. Mater. 114 (Jul): 805–816. https://doi.org/10.1016/j.conbuildmat.2016.04.015.
Ruan, Y., R. R. Davison, and C. J. Glover. 2003. “The effect of long-term oxidation on the rheological properties of polymer modified asphalts.” Fuel 82 (14): 1763–1773. https://doi.org/10.1016/S0016-2361(03)00144-3.
Sun, L., Y. Wang, and Y. Zhang. 2014. “Aging mechanism and effective recycling ratio of SBS modified asphalt.” Constr. Build. Mater. 70 (Nov): 26–35. https://doi.org/10.1016/j.conbuildmat.2014.07.064.
Wei, C., H. Duan, H. Zhang, and Z. Chen. 2019. “Influence of SBS modifier on aging behaviors of SBS-modified asphalt.” J. Mater. Civ. Eng. 31 (9): 04019184. https://doi.org/10.1061/(ASCE)MT.1943-5533.0002832.
Wu, S., L. Pang, L. Mo, Y. Chen, and G. Chen. 2009. “Influence of aging on the evolution of structure, morphology and rheology of base and SBS modified bitumen.” Constr. Build. Mater. 23 (2): 1005–1010. https://doi.org/10.1016/j.conbuildmat.2008.05.004.
Xu, Z., Z. Chen, Y. Chang, J. Lin, and Z. Chen. 2015. “Application of infrared spectroscopy to detect the dosage of SBS in modified asphalt.” J. Chang'an Univ. Nat. Sci. 35 (2): 7–12. https://dio.org/10.19721/j.cnki.1671-8879.2015.02.002.
Yan, C., W. Huang, P. Lin, Y. Zhang, and Q. Lv. 2019. “Chemical and rheological evaluation of aging properties of high content SBS polymer modified asphalt.” Fuel 252 (Sep): 417–426. https://doi.org/10.1016/j.fuel.2019.04.022.
Yan, C., W. Huang, F. Xiao, L. Wang, and Y. Li. 2018. “Proposing a new infrared index quantifying the aging extent of SBS-modified asphalt.” Road Mater. Pavement Des. 19 (6): 1406–1421. https://doi.org/10.1080/14680629.2017.1318082.
Yang, Z., X. Zhang, Z. Zhang, B. Zou, Z. Zhu, G. Lu, W. Xu, J. Yu, and H. Yu. 2018. “Effect of aging on chemical and rheological properties of bitumen.” Polymers 10 (12): 1345. https://doi.org/10.3390/polym10121345.
Zhang, D., H. Zhang, and C. Shi. 2017. “Investigation of aging performance of SBS modified asphalt with various aging methods.” Constr. Build. Mater. 145 (Aug): 445–451. https://doi.org/10.1016/j.conbuildmat.2017.04.055.
Zhang, H., Z. Chen, G. Xu, and C. Shi. 2018. “Evaluation of aging behaviors of asphalt binders through different rheological indices.” Fuel 221 (Jun): 78–88. https://doi.org/10.1016/j.fuel.2018.02.087.
Zhang, S., H. Hong, H. Zhang, and Z. Chen. 2021. “Investigation of anti-aging mechanism of multi-dimensional nanomaterials modified asphalt by FTIR, NMR and GPC.” Constr. Build. Mater. 305 (Oct): 124809. https://doi.org/10.1016/j.conbuildmat.2021.124809.
Zhao, Y., F. Gu, and X. Huang. 2011. “Analysis on SBS modified asphalt aging characterization based on Fourier transform infrared spectroscopy.” J. Build. Mater. 14 (5): 620–623. https://doi.org/10.3969/j.issn.1007-9629.2011.05.008.
Zhu, C., H. Zhang, D. Zhang, and Z. Chen. 2018. “Influence of base asphalt and SBS modifier on the weathering aging behaviors of SBS modified asphalt.” J. Mater. Civ. Eng. 30 (3): 04017306. https://doi.org/10.1061/(ASCE)MT.1943-5533.0002188.
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Received: Dec 30, 2021
Accepted: Jun 6, 2022
Published online: Dec 16, 2022
Published in print: Mar 1, 2023
Discussion open until: May 16, 2023
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