Abstract

Supplementary cementitious materials (SCMs) play a significant role in improving the durability of cement-based materials by restricting moisture and aggressive ion transfer through capillary pores. Phosphorous slag (PS), as a SCM, is a waste product that seems to be capable of enhancing durability and mechanical properties of cement-based materials because of its chemical components. In order to investigate its effects, fresh and hardened cement mortars prepared with various amounts of PS were studied in this research project. Moreover, surface area is a key factor in SCM performance. Therefore, the effects of surface area on PS performance were also investigated. The main results show that various amounts of PS have an insignificant effect on the results of flow table tests, regardless of surface area. However, PS significantly improves the capability of cement mortars to retain their initial workability. Plus, as surface area increases, the capability of PS-incorporated mortars to retain their initial workability improves. Additionally, findings of hardened mortar analysis show that the pozzolanic reaction of PS occurs slowly and it can be argued that the impact of PS on hardened mortars does not depend on surface area. For example, findings show that the effects of the lowest and highest surface areas tested are about the same on compressive strength, electrical resistivity, and chloride diffusivity. Plus, the mechanical and durability properties of PS-incorporated mortars are usually lower than those of reference mixtures after short periods of moist curing. By contrast, PS-incorporated mortars have better mechanical and durability properties in comparison with reference mixtures after longer periods of moist curing. In order to shed light on PS performance, its performance was compared with a well-known SCM, silica fume (SF). The outcomes show that PS is not as active as SF. Interestingly, PS contributes to strength gain after longer periods of moist curing, while SF improves mechanical and durability properties even after short periods of moist curing.

Get full access to this article

View all available purchase options and get full access to this article.

Data Availability Statement

All data, models, and code generated or used during the study appear in the published article.

Acknowledgments

This research study is supported by the Nano Beton Amin Factory, Qom, Iran, and the Concrete Technology Department of the Road, Housing, and Urban Development Research Center (BHRC) in Tehran. The authors are immensely grateful to the technicians and staff of these research centers.

References

AASHTO. 2017. Standard test method for surface resistivity indicating concrete’s ability to resist chloride ion penetration. AASHTO T357-17. Washington, DC: AASHTO.
ACI (American Concrete Institute). 2010. Report on chemical admixtures. ACI 212. Farmington Hills, MI: ACI.
Ahmadi, B., and M. Shekarchi. 2010. “Use of natural zeolite as a supplementary cementitious material.” Cem. Concr. Compos. 32 (2): 134–141. https://doi.org/10.1016/j.cemconcomp.2009.10.006.
Alaghebandian, N., S. Mirvalad, and A. A. S. Javid. 2020. “Durability of self-consolidating concrete and mortar mixtures containing ternary and quaternary cement blends exposed to simulated marine environment.” Constr. Build. Mater. 259 (Oct): 119767. https://doi.org/10.1016/j.conbuildmat.2020.119767.
ASTM. 2016. Standard guide for examination of hardened concrete using scanning electron microscopy. ASTM C1723-16. West Conshohocken, PA: ASTM.
ASTM. 2018a. Standard specification for concrete aggregate. C33/C33M-18. West Conshohocken, PA: ASTM.
ASTM. 2018b. Standard test method for thermogravimetric analysis of hydraulic cement. ASTM C1872-18e2. West Conshohocken, PA: ASTM.
ASTM. 2020. Standard test method for flow of hydraulic cement mortar. ASTM C1437-20. West Conshohocken, PA: ASTM.
Balapour, M., A. A. Ramezanianpour, and E. Hajibandeh. 2017. “An investigation on mechanical and durability properties of mortars containing nano and micro RHA.” Constr. Build. Mater. 132 (Feb): 470–477. https://doi.org/10.1016/j.conbuildmat.2016.12.017.
BSI (British Standard Institution). 2009. Testing hardened concrete: Part 3: Compressive strength test of specimens. BS EN 12390-3. London: BSI.
BSI (British Standard Institution). 2011. Testing concrete—Part 122: Method for determination of water absorption. BS EN 1881-122. London: BSI.
Chang, J., X. Cheng, F. Liu, L. Lu, and B. Teng. 2001. “Influence of fast-setting/early-strength agent on high phosphorous slag content cement.” Cem. Concr. Res. 31 (2): 213–216. https://doi.org/10.1016/S0008-8846(00)00450-6.
Chari, M. N., M. Shekarchi, and P. Ghod. 2016. “A simple practical method for determination of moisture transfer coefficient of mature concrete using a combined experimental-numerical approach.” Comput. Concr. 18 (3): 367–388. https://doi.org/10.12989/cac.2016.18.3.367.
Chari, M. N., M. Shekarchi, J. Sobhani, and M. N. Chari. 2016. “The effect of temperature on the moisture transfer coefficient of cement-based mortars: An experimental investigation.” Constr. Build. Mater. 102 (Part 1): 306–317. https://doi.org/10.1016/j.conbuildmat.2015.10.065.
Chen, J. S., B. Zhao, X. M. Wang, Q. L. Zhang, and L. Wang. 2010. “Cemented backfilling performance of yellow phosphorus slag.” Int. J. Miner. Metall. Mater. 17 (1): 121–126. https://doi.org/10.1007/s12613-010-0121-2.
Chen, X., K. Fang, H. Yang, and H. Peng. 2011. “Hydration kinetics of phosphorus slag-cement paste.” J. Wuhan Univ. Technol., Mater. Sci. Ed. 26 (1): 142–146. https://doi.org/10.1007/s11595-011-0186-4.
Chen, X., L. Zeng, and K. Fang. 2009. “Anti-crack performance of phosphorus slag concrete.” Wuhan Univ. J. Nat. Sci. 14 (1): 80–86. https://doi.org/10.1007/s11859-009-0117-9.
Deliang, H., S. Yu, L. Tianlu, W. Tao, L. Xiaodong, and Z. Jinhua. 2020. “Mechanical and durability properties of self-compacting concrete made with fly ash microbeads and phosphorous slag powder.” J. Adhes. Sci. Technol. 34 (14): 1572–1590. https://doi.org/10.1080/01694243.2020.1714116.
Gao, P., X. Lu, C. Yang, X. Li, N. Shi, and S. Jin. 2008. “Microstructure and pore structure of concrete mixed with superfine phosphorous slag and superplasticizer.” Constr. Build. Mater. 22 (5): 837–840. https://doi.org/10.1016/j.conbuildmat.2006.12.015.
Ghiasvand, E., A. A. Ramezanianpour, and A. M. Ramezanianpour. 2014. “Effect of grinding method and particle size distribution on the properties of portland-pozzolan cement.” Constr. Build. Mater. 53 (Feb): 547–554. https://doi.org/10.1016/j.conbuildmat.2013.11.072.
Hajforoush, M., R. Madandoust, and M. Kazemi. 2019. “Effects of simultaneous utilization of natural zeolite and magnetic water on engineering properties of self-compacting concrete.” Asian J. Civ. Eng. 20 (2): 289–300. https://doi.org/10.1007/s42107-018-00106-w.
Hu, J. 2017. “Comparison between the effects of superfine steel slag and superfine phosphorus slag on the long-term performances and durability of concrete.” J. Therm. Anal. Calorim. 128 (3): 1251–1263. https://doi.org/10.1007/s10973-017-6107-9.
Kanthe, V. N., S. V. Deo, and M. Murmu. 2018. “Effect of fly ash and rice husk ash on strength and durability of binary and ternary blend cement mortar.” Asian J. Civ. Eng. 19 (8): 963–970. https://doi.org/10.1007/s42107-018-0076-6.
Khalooee, S., B. Ahmadi, A. Askarinejad, and M. Nekooei. 2021. “Tackling the issues of self-compacting concrete containing high volume of waste glass aggregate by zeolite.” Struct. Concr. 22 (S1): E207–E227. https://doi.org/10.1002/suco.202000252.
Lee, S. T., R. D. Hooton, S. S. Kim, and E. K. Kim. 2006. “Effect of fineness of high-alumina ground granulated blast furnace slag on magnesium sulphate attack.” Mag. Concr. Res. 58 (5): 301–311. https://doi.org/10.1680/macr.2006.58.5.301.
Li, D. X., L. Chen, Z. Z. Xu, and Z. M. Luo. 2002. “A blended cement containing blast furnace slag and phosphorous slag.” J. Wuhan Univ. Technol., Mater. Sci. Ed. 17 (2): 62–65. https://doi.org/10.1007/BF02832625.
Libre, N. A., R. Khoshnazar, and M. Shekarchi. 2010. “Relationship between fluidity and stability of self-consolidating mortar incorporating chemical and mineral admixtures.” Constr. Build. Mater. 24 (7): 1262–1271. https://doi.org/10.1016/j.conbuildmat.2009.12.009.
Lin, K. L., W. C. Chang, D. F. Lin, H. L. Luo, and M. C. Tsai. 2008. “Effects of nano-SiO2 and different ash particle sizes on sludge ash-cement mortar.” J. Environ. Manage. 88 (4): 708–714. https://doi.org/10.1016/j.jenvman.2007.03.036.
Lin, Y. Q., M. J. Rao, H. Q. Yang, J. Z. Li, and Y. Shi. 2015. “Study on microstructures and macroproperties in cement-based materials adding phosphorous slag.” Supplement, Mater. Res. Innovations 19 (S10): 122–127. https://doi.org/10.1179/1432891715Z.0000000002122.
Liu, D. M., K. H. Fang, and H. S. Yang. 2009. “Research on the strengthening effect of phosphorus slag powder on cement-based materials.” Key Eng. Mater. 405–406 (Jan): 356–360. https://doi.org/10.4028/www.scientific.net/KEM.405-406.356.
Liu, X. W., L. Yang, and B. Zhang. 2013. “Utilization of phosphorus slag and fly ash for the preparation of ready-mixed mortar.” Appl. Mech. Mater. 423–426 (Sep): 987–992. https://doi.org/10.4028/www.scientific.net/AMM.423-426.987.
Mohan, A., and K. M. Mini. 2018. “Strength and durability studies of SCC incorporating silica fume and ultrafine GGBS.” Constr. Build. Mater. 171 (May): 919–928. https://doi.org/10.1016/j.conbuildmat.2018.03.186.
Najimi, M., J. Sobhani, B. Ahmadi, and M. Shekarchi. 2012. “An experimental study on durability properties of concrete containing zeolite as a highly reactive natural pozzolan.” Constr. Build. Mater. 35 (Oct): 1023–1033. https://doi.org/10.1016/j.conbuildmat.2012.04.038.
Naseroleslami, R., and M. Nemati Chari. 2019. “The effects of calcium stearate on mechanical and durability aspects of self-consolidating concretes incorporating silica fume/natural zeolite.” Constr. Build. Mater. 225 (Nov): 384–400. https://doi.org/10.1016/j.conbuildmat.2019.07.144.
Nemati Chari, M., R. Naseroleslami, and M. Shekarchi. 2019. “The impact of calcium stearate on characteristics of concrete.” Asian J. Civ. Eng. 20 (7): 1007–1020. https://doi.org/10.1007/s42107-019-00161-x.
Nemati Chari, M., and M. Shekarchizadeh. 2017. “A simplified method for determination of the moisture transfer coefficient of concrete.” Int. J. Civ. Eng. 15 (8): 1131–1142. https://doi.org/10.1007/s40999-017-0243-2.
NT (Nordtest) BUILD. 1991. Chloride migration coefficent from non-steady state migration experiment. Espoo, Finland: NORDTEST.
Pang, M., Z. Sun, M. Chen, J. Lang, J. Dong, X. Tian, and J. Sun. 2020. “Influence of phosphorus slag on physical and mechanical properties of cement mortars.” Materials 13 (10): 1–17. https://doi.org/10.3390/ma13102390.
Peiwei, G., D. Min, and F. Naiqian. 2001. “The influence of superplasticizer and superfine mineral powder on the flexibility, strength and durability of HPC.” Cem. Concr. Res. 31 (5): 703–706. https://doi.org/10.1016/S0008-8846(00)00484-1.
Peng, Y., J. Zhang, J. Liu, J. Ke, and F. Wang. 2015. “Properties and microstructure of reactive powder concrete having a high content of phosphorous slag powder and silica fume.” Constr. Build. Mater. 101 (Part 1): 482–487. https://doi.org/10.1016/j.conbuildmat.2015.10.046.
Pourkhorshidi, A. R., J. Sobhani, and A. A. Ramezanianpour. 2021. “A geochemical assessment method for identification of natural pozzolans as supplementary cementitious material.” Adv. Cem. Res. 618 (12): 1–11. https://doi.org/10.1680/jadcr.21.00078.
Ramezanianpour, A. A., A. Kazemian, M. A. Moghaddam, F. Moodi, and A. M. Ramezanianpour. 2016. “Studying effects of low-reactivity GGBFS on chloride resistance of conventional and high strength concretes.” Mater. Struct. 49 (7): 2597–2609. https://doi.org/10.1617/s11527-015-0670-y.
Ramezanianpour, A. A., R. Mousavi, M. Kalhori, J. Sobhani, and M. Najimi. 2015. “Micro and macro level properties of natural zeolite containing concretes.” Constr. Build. Mater. 101 (Part 1): 347–358. https://doi.org/10.1016/j.conbuildmat.2015.10.101.
Sabet, F. A., N. A. Libre, and M. Shekarchi. 2013. “Mechanical and durability properties of self-consolidating high performance concrete incorporating natural zeolite, silica fume and fly ash.” Constr. Build. Mater. 44 (Jul): 175–184. https://doi.org/10.1016/j.conbuildmat.2013.02.069.
Şakir, E., C. Arslantürk, and Ş. Kurbetci. 2011. “Influence of fly ash and silica fume on the consistency retention and compressive strength of concrete subjected to prolonged agitating.” Constr. Build. Mater. 25 (3): 1277–1281. https://doi.org/10.1016/j.conbuildmat.2010.09.024.
Senff, L., D. Hotza, W. L. Repette, V. M. Ferreira, and J. A. Labrincha. 2010. “Mortars with nano-SiO2 and micro-SiO2 investigated by experimental design.” Constr. Build. Mater. 24 (8): 1432–1437. https://doi.org/10.1016/j.conbuildmat.2010.01.012.
Wang, H., X. Sun, J. Wang, and P. J. M. Monteiro. 2016. “Permeability of concrete with recycled concrete aggregate and pozzolanic materials under stress.” Materials 10 (1): 1–12. https://doi.org/10.3390/ma10010001.
Wang, H. L., J. J. Wang, X. Y. Sun, and W. L. Jin. 2013. “Improving performance of recycled aggregate concrete with superfine pozzolanic powders.” J. Central South Univ. 20 (12): 3715–3722. https://doi.org/10.1007/s11771-013-1899-7.
Yang, R., R. Yu, Z. Shui, X. Gao, X. Xiao, X. Zhang, Y. Wang, and Y. He. 2019. “Low carbon design of an Ultra-High Performance Concrete (UHPC) incorporating phosphorous slag.” J. Cleaner Prod. 240 (Dec): 118–157. https://doi.org/10.1016/j.jclepro.2019.118157.
Zapata, L. E., G. Portela, O. M. Suárez, and O. Carrasquillo. 2013. “Rheological performance and compressive strength of superplasticized cementitious mixtures with micro/nano-SiO2 additions.” Constr. Build. Mater. 41 (Apr): 708–716. https://doi.org/10.1016/j.conbuildmat.2012.12.025.
Zhang, Z., Q. Wang, and J. Yang. 2017. “Hydration mechanisms of composite binders containing phosphorus slag at different temperatures.” Constr. Build. Mater. 147 (Aug): 720–732. https://doi.org/10.1016/j.conbuildmat.2017.04.202.

Information & Authors

Information

Published In

Go to Journal of Materials in Civil Engineering
Journal of Materials in Civil Engineering
Volume 35Issue 1January 2023

History

Received: Aug 14, 2021
Accepted: May 9, 2022
Published online: Oct 31, 2022
Published in print: Jan 1, 2023
Discussion open until: Mar 31, 2023

Permissions

Request permissions for this article.

Authors

Affiliations

Ramin Naseroleslami [email protected]
Graduate Student, Master of Science in Civil Engineering, Tafresh Univ., Tafres 3951879611, Iran. Email: [email protected]
Javad Bakhshi [email protected]
Graduate Student, Master of Science in Civil Engineering, Shahab Danesh Univ., Qom 3711687764, Iran. Email: [email protected]
Assistant Professor, Dept. of Concrete Technology, Road, Housing, and Urban Development Research Centre (BHRC), Tehran 1463917151, Iran (corresponding author). ORCID: https://orcid.org/0000-0002-0682-1980. Email: [email protected]
Mohammad Ali Yaghoobi [email protected]
Quality Control Manager, Nano Beton Amin, Isfahan St., Qom 3736175483, Iran. Email: [email protected]
Mojtaba Haji Mahdi [email protected]
Research and Development Manager, Nano Beton Amin, Isfahan St., Qom 3736175483, Iran. Email: [email protected]

Metrics & Citations

Metrics

Citations

Download citation

If you have the appropriate software installed, you can download article citation data to the citation manager of your choice. Simply select your manager software from the list below and click Download.

View Options

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Media

Figures

Other

Tables

Share

Share

Copy the content Link

Share with email

Email a colleague

Share