An Investigation on the Effect of Aging on Chemical and Mechanical Properties of Asphalt Binders
Publication: Journal of Materials in Civil Engineering
Volume 34, Issue 10
Abstract
The asphalt binder is exposed to aging conditions during production, placement, and service. This results in physical hardening, oxidation, and volatilization of the asphalt binder. The aging phenomenon affects the performance and, in turn, affects the pavement’s service life. Understanding the aging behavior of asphalt binders in terms of physical and chemical properties will help to extend the pavement’s service life. In the present study, the aging effect of the asphalt binder was investigated using chemomechanical evaluation. Five asphalt binders, namely viscosity grade 30 (VG30), viscosity grade 40 (VG40), polymer-modified binder (PMB), crumb rubber–modified binder (CRMB), and Sasobit-modified binder (SMB) at three aging levels (unaged, short, and long term) were selected for the investigation. The rolling thin-film oven (RTFO) and pressure aging vessel (PAV) were used to simulate short- and long-term aging conditions. Dynamic shear rheometer (DSR), Fourier-transform infrared (FTIR) spectroscopy, surface free energy (SFE), and thin-layer chromatography–flame ionization detector (TLC-FID) tests were performed to analyze the aging behavior of asphalt binders. Further, multiple stress creep and recovery (MSCR) and linear amplitude sweep (LAS) tests were performed to understand the effect of aging on rutting and fatigue damage of binders. From the FTIR test, the aging of binders showed a substantial increase in the formation of ketones and sulfoxide functional groups. The asphaltenes and resins contents increased, whereas aromatics and saturate contents reduced after aging. The higher asphaltenes content increases the stiffness of aged binders and improves rutting resistance. At the same time, aging is detrimental to the fatigue resistance of asphalt binders. Again, it is observed from the results that aging decreases the dispersive component of SFE and increases in the polar component. The effect of aging is less pronounced in PMB and CRMB than in unmodified binders (VG30 and VG40). This study will help in understanding the interrelation among chemomechanical behavior of a binder at different aging levels and will be useful for the selection of a better performing binder for field applications.
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Data Availability Statement
All data, models, and code generated or used during the study appear in the published paper.
References
AASHTO. 2012. Standard method of test for estimating fatigue resistance of asphalt binders using the linear amplitude sweep. AASHTO TP 101. Washington, DC: AASHTO.
AASHTO. 2013. Standard method of test for multiple stress creep recovery (MSCR) test of asphalt binder using a dynamic shear rheometer (DSR). AASHTO TP 70. Washington, DC: AASHTO.
Aguiar-Moya, J. P., J. Salazar-Delgado, A. Baldi-Sevilla, F. Leiva-Villacorta, and L. Loria-Salazar. 2015. “Effect of aging on adhesion properties of asphalt mixtures with the use of bitumen bond strength and surface energy measurement tests.” Transp. Res. Rec. 2505 (1): 57–65. https://doi.org/10.3141/2505-08.
Ali, S. A., M. Zaman, R. Ghabchi, M. A. Rahman, S. Ghos, and S. Rani. 2020. “Effect of additives and aging on moisture-induced damage potential of asphalt mixes using surface free energy and laboratory-based performance tests.” Int. J. Pavement Eng. 23 (2): 285–296. https://doi.org/10.1080/10298436.2020.1742335.
Apeagyei, A. K. 2011. “Laboratory evaluation of antioxidants for asphalt binders.” Constr. Build. Mater. 25 (1): 47–53. https://doi.org/10.1016/j.conbuildmat.2010.06.058.
ASTM. 2015. Standard test method for determining the rheological properties of asphalt binder using a dynamic shear rheometer. ASTM D7175-15. West Conshohocken, PA: ASTM International.
ASTM. 2019a. Standard practice for accelerated aging of asphalt binder using a pressurized aging vessel (PAV). ASTM D6521-19a. West Conshohocken, PA: ASTM International.
ASTM. 2019b. Standard test method for effect of heat and air on a moving film of asphalt (rolling thin-film oven test). ASTM D2872. West Conshohocken, PA: ASTM International.
BIS (Bureau of Indian Standards). 1978a. Methods for testing tar and bituminous materials: Determination of penetration test. IS 1203. New Delhi, India: BIS.
BIS (Bureau of Indian Standards). 1978b. Methods for testing tar and bituminous materials: Determination of softening point test. IS 1205. New Delhi, India: BIS.
Camargo, I. G. D. N., B. Hofko, J. Mirwald, and H. Grothe. 2020. “Effect of thermal and oxidative aging on asphalt binders rheology and chemical composition.” Materials 13 (19): 4438. https://doi.org/10.3390/ma13194438.
Cao, W., Y. Wang, and C. Wang. 2019. “Fatigue characterization of bio-modified asphalt binders under various laboratory aging conditions.” Constr. Build. Mater. 208 (Jan): 686–696. https://doi.org/10.1016/j.conbuildmat.2019.03.069.
Chen, Y., S. Dong, H. Wang, R. Gao, and Z. You. 2020. “Using surface free energy to evaluate the fracture performance of asphalt binders.” Constr. Build. Mater. 240 (Apr): 118004. https://doi.org/10.1016/j.conbuildmat.2020.118004.
Corbett, L. W. 1969. “Composition of asphalt based on generic fractionation, using solvent deasphaltening, elution-adsorption chromatography, and densimetric characterization.” Anal. Chem. 41 (4): 576–579. https://doi.org/10.1021/ac60273a004.
Deef-Allah, E., and M. Abdelrahman. 2021. “Investigating the relationship between the fatigue cracking resistance and thermal characteristics of asphalt binders extracted from field mixes containing recycled materials.” Transp. Eng. 4 (Jun): 100055. https://doi.org/10.1016/j.treng.2021.100055.
Domingos, M. D. I., and A. L. Faxina. 2015. “Rheological analysis of asphalt binders modified with Elvaloy® terpolymer and polyphosphoric acid on the multiple stress creep and recovery test.” Mater. Struct. 48 (5): 1405. https://doi.org/10.1617/s11527-013-0242-y.
Elico Marketing Pvt. Ltd. 2019. SEO-phoenix contact angle analyzer manual. Maharashtra, India: Author.
Gaestel, C., R. Smadja, and K. A. Lamminan. 1971. “Contribution à la connaissance des propriétés des bitumes routiers.” Rev. Gentile Routes et Aérodromes 466 (Jun): 85–94.
Hamedi, G. H., H. Ghahremani, and D. Saedi. 2020. “Investigation the effect of short term aging on thermodynamic parameters and thermal cracking of asphalt mixtures modified with nanomaterials.” Road Mater. Pavement Des. 22 (12): 2838–2865. https://doi.org/10.1080/14680629.2020.1808520.
Hofko, B., F. Handle, L. Eberhardsteiner, M. Hospodka, R. Blab, J. Füssl, and H. Grothe. 2015. “Alternative approach toward the aging of asphalt binder.” Transp. Res. Rec. 2505 (1): 24–31. https://doi.org/10.3141/2505-04.
Hofko, B., L. Porot, A. F. Cannone, L. Poulikakos, L. Huber, X. Lu, and H. Grothe. 2018. “FTIR spectral analysis of bituminous binders: Reproducibility and impact of ageing temperature.” Mater. Struct. 51 (2): 1–16. https://doi.org/10.1617/s11527-018-1170-7.
Hou, X., S. Lv, Z. Chen, and F. Xiao. 2018. “Applications of Fourier transform infrared spectroscopy technologies on asphalt materials.” Measurement 121 (Jun): 304–316. https://doi.org/10.1016/j.measurement.2018.03.001.
Howson, J. E., A. Bhasin, E. Masad, D. N. Little, R. L. Lytton, and H. Claros. 2007. “Influence of material factors on surface free energy and performance related parameters.” In Proc., Int. Conf.: Advanced Characterisation of Pavement and Soil Engineering Materials, 1621–1630. Athens, Greece: CRC Press.
Jafari, M., and A. Babazadeh. 2016. “Evaluation of polyphosphoric acid-modified binders using multiple stress creep and recovery and linear amplitude sweep tests.” Road Mater. Pavement Des. 17 (4): 859–876. https://doi.org/10.1080/14680629.2015.1132631.
Kakar, M. R., M. O. Hamzah, M. N. Akhtar, and D. Woodward. 2016. “Surface free energy and moisture susceptibility evaluation of asphalt binders modified with surfactant-based chemical additive.” J. Cleaner Prod. 112 (Jan): 2342–2353. https://doi.org/10.1016/j.jclepro.2015.10.101.
Kleizienė, R., M. Panasenkienė, and A. Vaitkus. 2019. “Effect of aging on chemical composition and rheological properties of neat and modified bitumen.” Materials 12 (24): 4066. https://doi.org/10.3390/ma12244066.
Koyun, A., J. Büchner, M. P. Wistuba, and H. Grothe. 2020. “Rheological, spectroscopic and microscopic assessment of asphalt binder ageing.” Road Mater. Pavement Des. 23 (1): 80–97. https://doi.org/10.1080/14680629.2020.1820891.
Kumar, A., R. Choudhary, and A. Kumar. 2021. “Aging characteristics of asphalt binders modified with waste tire and plastic pyrolytic chars.” PLoS One 16 (8): e0256030. https://doi.org/10.1371/journal.pone.0256030.
Lamontagne, J., P. Dumas, V. Mouillet, and J. Kister. 2001. “Comparison by Fourier transform infrared (FTIR) spectroscopy of different ageing techniques: Application to road bitumens.” Fuel 80 (4): 483–488. https://doi.org/10.1016/S0016-2361(00)00121-6.
Lesueur, D. 2009. “The colloidal structure of bitumen: Consequences on the rheology and on the mechanisms of bitumen modification.” Adv. Colloid Interface Sci. 145 (1–2): 42–82. https://doi.org/10.1016/j.cis.2008.08.011.
Li, B., J. Yang, X. Li, X. Liu, F. Han, and L. Li. 2015. “Effect of short-term aging process on the moisture susceptibility of asphalt mixtures and binders containing Sasobit warm mix additive.” Adv. Mater. Sci. Eng. 2015: 1–18. https://doi.org/10.1155/2015/425827.
Lin, M. S., K. M. Lunsford, C. J. Glover, R. R. Davison, and J. A. Bullin. 1995. “The effects of asphaltenes on the chemical and physical characteristics of asphalt.” In Asphaltenes, 155–176. Boston: Springer.
Lu, X., and U. Isacsson. 2002. “Effect of ageing on bitumen chemistry and rheology.” Constr. Build. Mater. 16 (1): 15–22. https://doi.org/10.1016/S0950-0618(01)00033-2.
Mouillet, V., J. Lamontagne, F. Durrieu, J. P. Planche, and L. Lapalu. 2008. “Infrared microscopy investigation of oxidation and phase evolution in bitumen modified with polymers.” Fuel 87 (7): 1270–1280. https://doi.org/10.1016/j.fuel.2007.06.029.
Mullapudi, R. S., K. G. Deepika, and K. S. Reddy. 2019. “Relationship between chemistry and mechanical properties of RAP binder blends.” J. Mater. Civ. Eng. 31 (7): 04019124. https://doi.org/10.1061/(ASCE)MT.1943-5533.0002769.
Mullapudi, R. S., and K. Sudhakar Reddy. 2020a. “An investigation on the relationship between FTIR indices and surface free energy of RAP binders.” Road Mater. Pavement Des. 21 (5): 1326–1340. https://doi.org/10.1080/14680629.2018.1552889.
Mullapudi, R. S., and K. Sudhakar Reddy. 2020b. “Relationship between rheological properties of RAP binders and cohesive surface free energy.” J. Mater. Civ. Eng. 32 (6): 04020137. https://doi.org/10.1061/(ASCE)MT.1943-5533.0003199.
Naskar, M., K. S. Reddy, T. K. Chaki, M. K. Divya, and A. P. Deshpande. 2013. “Effect of ageing on different modified bituminous binders: Comparison between RTFOT and radiation ageing.” Mater. Struct. 46 (7): 1227–1241. https://doi.org/10.1617/s11527-012-9966-3.
Nivitha, M. R., E. Prasad, and J. M. Krishnan. 2016. “Ageing in modified bitumen using FTIR spectroscopy.” Int. J. Pavement Eng. 17 (7): 565–577. https://doi.org/10.1080/10298436.2015.1007230.
Oliver, J. W. 2009. “Changes in the chemical composition of Australian bitumens.” Road Mater. Pavement Des. 10 (3): 569–586. https://doi.org/10.1080/14680629.2009.9690214.
Petersen, J. C. 2000. “Chemical composition of asphalt as related to asphalt durability.” In Vol. 40 of Developments in petroleum science, 363–399. Amsterdam, Netherlands: Elsevier.
Petersen, J. C., and R. Glaser. 2011. “Asphalt oxidation mechanisms and the role of oxidation products on age hardening revisited.” Road Mater. Pavement Des. 12 (4): 795–819. https://doi.org/10.1080/14680629.2011.9713895.
Poulikakos, L. D., S. dos Santos, M. Bueno, S. Kuentzel, M. Hugener, and M. N. Partl. 2014. “Influence of short and long term aging on chemical, microstructural and macro-mechanical properties of recycled asphalt mixtures.” Constr. Build. Mater. 51 (Jan): 414–423. https://doi.org/10.1016/j.conbuildmat.2013.11.004.
Qu, X., Q. Liu, M. Guo, D. Wang, and M. Oeser. 2018. “Study on the effect of aging on physical properties of asphalt binder from a microscale perspective.” Constr. Build. Mater. 187 (Oct): 718–729. https://doi.org/10.1016/j.conbuildmat.2018.07.188.
Rocha Segundo, I., S. Landi, A. Margaritis, G. Pipintakos, E. Freitas, C. Vuye, J. Blom, T. Tytgat, S. Denys, and J. Carneiro. 2020. “Physicochemical and rheological properties of a transparent asphalt binder modified with nano-TiO2.” Nanomaterials 10 (11): 2152. https://doi.org/10.3390/nano10112152.
Saboo, N., and P. Kumar. 2016. “Analysis of different test methods for quantifying rutting susceptibility of asphalt binders.” J. Mater. Civ. Eng. 28 (7): 04016024. https://doi.org/10.1061/(ASCE)MT.1943-5533.0001553.
Singh, B., N. Saboo, and P. Kumar. 2017. “Use of Fourier transform infrared spectroscopy to study ageing characteristics of asphalt binders.” Pet. Sci. Technol. 35 (16): 1648–1654. https://doi.org/10.1080/10916466.2017.1350710.
Singh, D., S. Girimath, and P. K. Ashish. 2018. “Performance evaluation of polymer-modified binder containing reclaimed asphalt pavement using multiple stress creep recovery and linear amplitude sweep tests.” J. Mater. Civ. Eng. 30 (3): 04018004. https://doi.org/10.1061/(ASCE)MT.1943-5533.0002176.
Sirin, O. S., D. K. Paul, and E. Kassem. 2018. “State of the art study on aging of asphalt mixtures and use of antioxidant additives.” Adv. Civ. Eng. 2018: 1–18. https://doi.org/10.1155/2018/3428961.
Soenen, H., X. Lu, and O. V. Laukkanen. 2016. “Oxidation of bitumen: Molecular characterization and influence on rheological properties.” Rheol. Acta 55 (4): 315–326. https://doi.org/10.1007/s00397-016-0919-6.
Tarefder, R. A., and S. S. Yousefi. 2016. “Rheological examination of aging in polymer-modified asphalt.” J. Mater. Civ. Eng. 28 (2): 04015112. https://doi.org/10.1061/(ASCE)MT.1943-5533.0001370.
Wang, F., Y. Xiao, P. Cui, J. Lin, M. Li, and Z. Chen. 2020a. “Correlation of asphalt performance indicators and aging Degrees: A review.” Constr. Build. Mater. 250 (Jul): 118824. https://doi.org/10.1016/j.conbuildmat.2020.118824.
Wang, H., X. Liu, P. Apostolidis, M. van de Ven, S. Erkens, and A. Skarpas. 2020b. “Effect of laboratory aging on chemistry and rheology of crumb rubber modified bitumen.” Mater. Struct. 53 (2): 1–15. https://doi.org/10.1617/s11527-020-1451-9.
Wang, R., Z. Qi, R. Li, and J. Yue. 2020c. “Investigation of the effect of aging on the thermodynamic parameters and the intrinsic healing capability of graphene oxide modified asphalt binders.” Constr. Build. Mater. 230 (Jan): 116984. https://doi.org/10.1016/j.conbuildmat.2019.116984.
Wang, Y., X. Wang, X. Zhou, G. Yang, and L. Zhang. 2021. “Evaluation of the physical and adhesive properties of natural weathering asphalt.” Adv. Mater. Sci. Eng. 2021: 1–10. https://doi.org/10.1155/2021/5783256.
Wasiuddin, N. M., C. M. Fogle, M. M. Zaman, and A. O. Edgar. 2007. “Characterization of thermal degradation of liquid amine anti-strip additives in asphalt binders due to RTFO and PAV-aging.” J. Test. Eval. 35 (4): 387–394.
Wei, J., and Y. Zhang. 2010. “Influence of aging on surface free energy of asphalt binder.” Int. J. Pavement Res. Technol. 3 (6): 343.
Xu, M., Y. Zhang, and P. Zhao. 2021. “Long-term aging performance study of asphalt with different composition.” IOP Conf. Ser.: Earth Environ. Sci. 631 (1): 012050. https://doi.org/10.1088/1755-1315/631/1/012050.
Xu, Y., E. Zhang, and L. Shan. 2019. “Effect of SARA on rheological properties of asphalt binders.” J. Mater. Civ. Eng. 31 (6): 04019086. https://doi.org/10.1061/(ASCE)MT.1943-5533.0002723.
Yang, Z., X. Zhang, Z. Zhang, B. Zou, Z. Zhu, G. Lu, and H. Yu. 2018. “Effect of aging on chemical and rheological properties of bitumen.” Polymers 10 (12): 1345. https://doi.org/10.3390/polym10121345.
Zhang, D., H. Zhang, and C. Shi. 2017. “Investigation of aging performance of SBS modified asphalt with various aging methods.” Constr. Build. Mater. 145 (Aug): 445–451. https://doi.org/10.1016/j.conbuildmat.2017.04.055.
Zhang, H., K. Shen, G. Xu, J. Tong, R. Wang, D. Cai, and X. Chen. 2020. “Fatigue resistance of aged asphalt binders: An investigation of different analytical methods in linear amplitude sweep test.” Constr. Build. Mater. 241 (Apr): 118099. https://doi.org/10.1016/j.conbuildmat.2020.118099.
Ziari, H., A. Amini, and A. Goli. 2020. “The effect of different aging conditions and strain levels on relationship between fatigue life of asphalt binders and mixtures.” Constr. Build. Mater. 244 (May): 118345. https://doi.org/10.1016/j.conbuildmat.2020.118345.
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Published In
Journal of Materials in Civil Engineering
Volume 34 • Issue 10 • October 2022
Copyright
© 2022 American Society of Civil Engineers.
History
Received: Sep 16, 2021
Accepted: Jan 26, 2022
Published online: Jul 20, 2022
Published in print: Oct 1, 2022
Discussion open until: Dec 20, 2022
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