Technical Papers
May 18, 2022

Preparation of High-Luminescent Materials and Application of Luminescent Coatings in Road Engineering

Publication: Journal of Materials in Civil Engineering
Volume 34, Issue 8

Abstract

With the development of the highway industry and new materials, long-afterglow luminescent material as a new energy storage and environmental protection material has gradually been applied to night lighting. In this study, SrAl2O4:Eu2+, Dy3+ long-afterglow materials were prepared by the solid-state reaction method. The luminescent properties were improved by changing the process parameters. The single-factor test results indicated that the luminescent properties were highest when flux content, calcination temperature, calcination time, and doping ratio of Eu and Dy were 5%, 1,300°C, 2 h and 11, respectively. Then, long-afterglow materials with high luminescence were prepared by adding a pore-forming agent. The structural characteristics and optical properties of the products were analyzed. X-ray diffraction (XRD) and scanning electron microscopy (SEM) analysis indicated that the addition of pore-forming agent did not change the crystal structure of the material but changed the surface morphology of the long-afterglow materials. The surface morphology of the products changed from flat and dense to a convex structure after adding pore-forming agent, and some connected pore structures were produced. The afterglow performance of products was continuously improved with the increase of pore-forming agent content. Finally, luminescent coatings were prepared by combining with fluorine-containing resin, and the performance was studied. The stability of luminescent coatings decreased with the increase of the filler:binder ratio, and the best ratio was 0.51. The luminous performance of coatings was best when the amount of long-afterglow phosphor was 40%. The luminescent coatings had good adhesion with the road surface, and the luminescence could last for more than 7 h in a dark environment.

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Data Availability Statement

Some or all data, models, or code that support the findings of this study are available from the corresponding author upon reasonable request.

Acknowledgments

The research was financially supported by National Natural Science Foundation of China (51978115), Chongqing Technology Innovation and application development special project (CSTC2019JSCX-MSXM1685), and the open fund of National & Local Joint Engineering Laboratory of Traffic Civil Engineering Materials, Chongqing Jiaotong University. The views in the paper only reflect those of the authors and not necessarily the views of the sponsors.

References

Bacero, R., D. To, J. Arista, M. Kevin, D. Cruz, and J. Villaneva. 2015. “Evaluation of strontium aluminate in traffic paint pavement markings for rural and unilluminated roads.” J. Eastern Asia Soc. Transp. Stud. 11: 1726–1744. https://doi.org/10.11175/easts.11.1726.
Bethencourt, M., F. J. Botana, M. J. Cano, R. M. Osuna, and M. Marcos. 2004. “Lifetime prediction of waterborne acrylic paints with the AC-DC-AC method.” Prog. Org. Coat. 49 (3): 275–281. https://doi.org/10.1016/j.porgcoat.2003.10.009.
Bi, Y., J. Pei, Z. Chen, L. Zhang, R. Li, and D. Hu. 2021. “Preparation and characterization of luminescent road-marking paint.” Int. J. Pavement Res. Technol. 14 (2): 252–258. https://doi.org/10.1007/s42947-020-0229-3.
Bol, A. A., J. Ferwerda, J. A. Bergwerff, and A. Meijerink. 2002. “Luminescence of nanocrystalline ZnS:Cu2+.” J. Lumin. 99 (4): 325–334. https://doi.org/10.1016/S0022-2313(02)00350-2.
Chen, R., Y. Wang, Y. Hu, Z. Hu, and C. Liu. 2008. “Modification on luminescent properties of SrAl2O4:Eu2+, Dy3+ phosphor by Yb3+ ions doping.” J. Lumin. 128 (7): 1180–1184. https://doi.org/10.1016/j.jlumin.2007.11.094.
Chinese Standard. 1998. Paints and varnishes, cross cut test for paint films. GB/T 9286-1998. Beijing: China Quality Inspection Press.
Chinese Standard. 2006. Paints and varnishes, determination of film hardness, pencil method. GB/T 6739-2006. Beijing: China Quality Inspection Press.
Clabau, F., X. Rocquefelte, S. Jobic, P. Deniard, M. H. Whangbo, A. Garcia, and T. Le Mercier. 2005. “Mechanism of phosphorescence appropriate for the long-lasting phosphors Eu2+dopedSrAl2O4 with codopants Dy3+ and B3+.” Chem. Mater. 17 (15): 3904–3912. https://doi.org/10.1021/cm050763r.
Gultekin, S., S. Yildirim, O. Yilmaz, I. C. Keskin, M. I. Kati, and E. Celik. 2019. “Structural and optical properties of SrAl2O4:Eu2+/Dy3+ phosphors synthesized by flame spray pyrolysis technique.” J. Lumin. 206 (Feb): 59–69. https://doi.org/10.1016/j.jlumin.2018.10.011.
Hai, O., Z. Zhang, Q. Ren, X. Wu, Q. Zhang, B. Zeng, and D. Li. 2018. “The preparation and functional studies of the porous long afterglow luminescent materials.” Dyes Pigm. 156 (Dec): 160–166. https://doi.org/10.1016/j.dyepig.2018.04.007.
Hu, X. W., H. Yang, T. T. Guo, D. H. Shu, W. F. Shan, G. Z. Li, and D. C. Guo. 2018. “Preparation and properties of Eu and Dy co-doped strontium aluminate long afterglow nanomaterials.” Ceram. Int. 44 (7): 7535–7544. https://doi.org/10.1016/j.ceramint.2018.01.157.
Ishigaki, T., H. Mizushina, K. Uematsu, N. Matsushita, M. Yoshimura, K. Toda, and M. Sato. 2010. “Microwave synthesis technique for long phosphorescence phosphor SrAl2O4:Eu2+, Dy3+ using carbon reduction.” Mater. Sci. Eng., B 173 (1–3): 109–112. https://doi.org/10.1016/j.mseb.2009.11.004.
Jiang, H., and B. Xu. 2006. “Preparation of silicate long afterglow photo-luminescent materials by high temperature solid-state reaction.” J. Chin. Ceram. Soc. 34 (9): 1154–1157.
Li, W., J. Wang, Y. Xie, M. Tebyetekerwa, Z. Qiu, J. Tang, S. Yang, M. Zhu, and Z. Xu. 2018. “Water-based fluorescent paint: Presenting a novel approach to study and solve the aggregation caused quench (ACQ) effect in traditional fluorescent materials.” Prog. Org. Coat. 120 (Jul): 1–9. https://doi.org/10.1016/j.porgcoat.2018.03.003.
Li, X., W. Zhang, L. Dong, D. Liu, and Z. Qi. 2019. “Low temperature molten salt synthesis of CeF3 and CeF3:Tb3+ phosphors with efficient luminescence properties.” J. Lumin. 205 (Jan): 122–128. https://doi.org/10.1016/j.jlumin.2018.08.067.
Li, Y., Y. Wang, X. Xu, and Y. Gong. 2009. “Effects of non-stoichiometry on crystallinity, photoluminescence and afterglow properties of Sr2MgSi2O7:Eu2+, Dy3+ phosphors.” J. Lumin. 129 (10): 1230–1234. https://doi.org/10.1016/j.jlumin.2009.06.014.
Lin, Y., Z. Tang, Z. Zhang, X. Wang, and J. Zhang. 2001. “Preparation of a new long afterglow blue-emitting Sr2MgSi2O7-based photoluminescent phosphor.” J. Mater. Sci. Lett. 20 (16): 1505–1506. https://doi.org/10.1023/A:1017930630889.
Liu, T., B. T. Campbell, S. P. Burns, and J. P. Sullivan. 1997. “Temperature- and pressure-sensitive luminescent paints in aerodynamics.” Appl. Mech. Rev. 50 (4): 227–246. https://doi.org/10.1115/1.3101703.
Lu, X., and W. Shu. 2007. “Roles of crystal defects in the persistent luminescence of Eu2+, Dy3+ co-doped strontium aluminate based phosphors.” Rare Met. 26 (4): 305–310. https://doi.org/10.1016/S1001-0521(07)60220-4.
Nance, J., and T. D. Sparks. 2020. “Comparison of coatings for SrAl2O4:Eu2+, Dy3+ powder in waterborne road striping paint under wet conditions.” Prog. Org. Coat. 144 (Jul): 105637. https://doi.org/10.1016/j.porgcoat.2020.105637.
Pan, L., S. Liu, X. Zhang, O. Oderinde, F. Yao, and G. Fu. 2018. “Optimization method for blue Sr2MgSi2O7:Eu2+, Dy3+ phosphors produced by microwave synthesis route.” J. Alloys Compd. 737 (Mar): 39–45. https://doi.org/10.1016/j.jallcom.2017.11.343.
Tang, Z., F. Zhang, Z. Zhang, C. Huang, and Y. Lin. 2000. “Luminescent properties of SrAl2O4: Eu, Dy material prepared by the gel method.” J. Eur. Ceram. Soc. 20 (12): 2129–2132. https://doi.org/10.1016/S0955-2219(00)00092-3.
Van Der Merwe Steyn, W. J. 2008. “Development of autoluminescent surfacings for concrete pavements.” Transp. Res. Rec. 2070 (1): 22–31. https://doi.org/10.3141/2070-04.
Verstegen, J. M. P. J. 1974. “Survey of a group of phosphors, based on hexagonal aluminate and gallate host lattices.” J. Electrochem. Soc. 121 (12): 1623–1627. https://doi.org/10.1149/1.2401756.
Wang, D., Q. Yin, Y. Li, and M. Wang. 2002. “Concentration quenching of Eu2+ in SrO & middot 6Al2O3:Eu2+ phosphor.” J. Mater. Sci. 37 (2): 381–383. https://doi.org/10.1023/A:1013620917213.
Wu, H. Y., Y. H. Hu, and X. J. Wang. 2011. “Investigation of the trap state of Sr2MgSi2O7:Eu2+, Dy3+ phosphor and decay process.” Radiat. Meas. 46 (6–7): 591–594. https://doi.org/10.1016/j.radmeas.2011.04.023.
Xiao, Q., L. Xiao, Y. Liu, X. Chen, and Y. Li. 2010. “Synthesis and luminescence properties of needle-like SrAl2O4:Eu, Dy phosphor via a hydrothermal co-precipitation method.” J. Phys. Chem. Solids 71 (7): 1026–1030. https://doi.org/10.1016/j.jpcs.2010.04.017.
Ye, F., S. Dong, Z. Tian, S. Yao, Z. Zhou, and S. Wang. 2015. “Fabrication and characterization of long-persistent luminescence/polymer (Ca2MgSi2O7:Eu2+, Dy3+/PLA) composite fibers by electrospinning.” Opt. Mater. 45 (Jul): 64–68. https://doi.org/10.1016/j.optmat.2015.03.011.
Zhou, X., G. Ju, T. Dai, Y. Li, H. Wu, Y. Jin, and Y. Hu. 2020. “Strontium substitution enhancing a novel Sm3+-doped barium gallate phosphor with bright and red long persistent luminescence.” J. Lumin. 218 (Feb): 116820. https://doi.org/10.1016/j.jlumin.2019.116820.

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Go to Journal of Materials in Civil Engineering
Journal of Materials in Civil Engineering
Volume 34Issue 8August 2022

History

Received: Aug 17, 2021
Accepted: Nov 30, 2021
Published online: May 18, 2022
Published in print: Aug 1, 2022
Discussion open until: Oct 18, 2022

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Bailin Shan [email protected]
Ph.D. Student, School of Civil Engineering, Chongqing Jiaotong Univ., Chongqing 400074, China. Email: [email protected]
Xiaoyu Yang [email protected]
Ph.D. Student, National & Local Joint Engineering Laboratory of Traffic Civil Engineering Materials, Chongqing Jiaotong Univ., Chongqing 400074, China. Email: [email protected]
Xuejuan Cao [email protected]
Professor, School of Material Science and Engineering, Chongqing Jiaotong Univ., Chongqing 400074, China (corresponding author). Email: [email protected]
Ph.D. Student, School of Civil Engineering, Chongqing Jiaotong Univ., Chongqing 400074, China. Email: [email protected]
Boming Tang [email protected]
Professor, School of Civil Engineering, Chongqing Jiaotong Univ., Chongqing 400074, China. Email: [email protected]

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Cited by

  • Combustion Synthesis of SrAl2O4: Eu2+, Dy3+ Phosphorescent Pigments for Glow-in-the-Dark Safety Markings, Nanomaterials, 10.3390/nano13040687, 13, 4, (687), (2023).

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