Technical Papers
Sep 2, 2021

Physical and Antiaging Properties of Rodlike Nano-ZnO–Modified Asphalt

Publication: Journal of Materials in Civil Engineering
Volume 33, Issue 11

Abstract

Asphalt aging is the main cause of fatigue failure of asphalt pavement. The performance of rodlike nano-ZnO is better than that of nano-ZnO in all aspects, and rodlike nanomaterials can reduce the agglomeration phenomenon of powder like nanomaterials in asphalt. Therefore, in this paper, rodlike nano-ZnO particles were added to asphalt to improve its aging resistance. Asphalt was modified by adding different amounts of rodlike nano-ZnO particles. The penetration (25°C), softening point, and ductility (5°C) of rodlike nano-ZnO–modified asphalt were tested. The aging of rodlike nano-ZnO–modified asphalt was simulated by thin film oven test (TFOT) and ultraviolet (UV) aging. The dynamic shear rheological (DSR) properties of modified asphalt before and after aging were studied, and the mechanism was explained using UV-visible-infrared absorption test, Fourier transform infrared (FITR) spectroscopy, and scanning electron microscopy. Rodlike nano-ZnO particles can increase the softening point of asphalt and reduce the penetration (25°C), which has a positive effect on the ductility (5°C), but when the content is 3%, the ductility of asphalt will be affected. The complex shear modulus (G*) and phase angle (δ) of the composites can be improved using rodlike nano-ZnO. With the increase of the amount of rodlike nano-ZnO, the performance change rate of modified asphalt before and after aging decreases gradually. When the content of rodlike nano-ZnO is 3%, the modified asphalt has the best UV absorption capacity, does not affect other physical properties, and can significantly improve the drying and hardening of the microsurface after aging. Therefore, rodlike nano-ZnO can significantly improve the UV resistance of asphalt.

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Data Availability Statement

Some or all data, models, or code that support the findings of this study are available from the corresponding author upon reasonable request.

Acknowledgments

The authors appreciate the support of the National Natural Science Foundation of China (51978084) and the Postgraduate Scientific Research Innovation Project of Changsha University of Science and Technology (SJCX202003).

References

Ali, S. I. A., A. Ismail, M. R. Karim, N. I. M. Yusoff, R. A. Al-Mansob, E. J. R. M. Aburkaba, and P. Design. 2017. “Performance evaluation of Al2O3 nanoparticle-modified asphalt binder.” Road Mater. Pavement Des. 18 (6): 1251–1268. https://doi.org/10.1080/14680629.2016.1208621.
Apostolidis, P., X. Liu, S. Erkens, and T. Scarpas. 2020. “Oxidative aging of epoxy asphalt.” Int. J. Pavement Eng. 13 (3): 1–11. https://doi.org/10.1080/10298436.2020.1806278.
Arabani, M., S. A. Tahami, and G. H. Hamedi. 2018. “Performance evaluation of dry process crumb rubber-modified asphalt mixtures with nanomaterial.” Road Mater. Pavement Des. 19 (5): 1241–1258. https://doi.org/10.1080/14680629.2017.1302356.
Bi, Y., S. Wu, J. Pei, Y. Wen, R. J. C. Li, and B. Materials. 2020. “Correlation analysis between aging behavior and rheological indices of asphalt binder.” Constr. Build. Mater. 264 (Dec): 120176. https://doi.org/10.1016/j.conbuildmat.2020.120176.
Cao, Z., X. Huang, J. Yu, X. Han, R. Wang, and Y. Li. 2020. “Study on all-components regeneration of ultraviolet aged SBS modified asphalt for high-performance recycling.” J. Cleaner Prod. 276 (Dec): 123376. https://doi.org/10.1016/j.jclepro.2020.123376.
Chen, F., M. Song, X. Ma, and X. Zhu. 2019. “Assess the impacts of different autonomous trucks’ lateral control modes on asphalt pavement performance.” Transp. Res. Part C: Emerging Technol. 103 (Jun): 17–29. https://doi.org/10.1016/j.trc.2019.04.001.
Elkholy, S. A., A. M. M. Abd El-Rahman, M. El-Shafie, and Z. L. Abo-Shanab. 2018. “Physical and rheological properties of modified sulfur asphalt binder.” Int. J. Pavement Res. Technol. 11 (2): 838–845. https://doi.org/10.1016/j.ijprt.2018.07.005.
Fan, Z., and A. P. Watkinson. 2011. “Kinetics and structural evolution during aging of Coker vapor deposits.” Heat Transfer Eng. 32 (3–4): 237–247. https://doi.org/10.1080/01457632.2010.495608.
Fang, C., R. Yu, S. Liu, and Y. Li. 2013. “Nanomaterials applied in asphalt modification: A review.” J. Mater. Sci. Technol. 29 (7): 589–594. https://doi.org/10.1016/j.jmst.2013.04.008.
Hasan, Z., R. O. Kamran, F. Mohammad, G. Ahmad, and F. Hosein. 2012. “Evaluation of different conditions on the mixing bitumen and carbon nano-tubes.” J. Civ. Environ. Eng. 12 (6): 53–59. https://doi.org/120106-3838-IJCEE-IJENS.
Hosseinnezhad, S., M. Zadshir, X. Yu, H. Yin, B. K. Sharma, and E. J. F. Fini. 2019. “Differential effects of ultraviolet radiation and oxidative aging on bio-modified binders.” Pet. Sci. Technol. 251 (Sep): 45–56. https://doi.org/10.1016/j.fuel.2019.04.029.
Hou, X., F. Xiao, J. Wang, and S. J. F. Amirkhanian. 2018. “Identification of asphalt aging characterization by spectrophotometry technique.” Fuel 226 (Aug): 230–239. https://doi.org/10.1016/j.fuel.2018.04.030.
Hu, J., S. Wu, Q. Liu, M. I. G. Hernández, Z. Wang, S. Nie, G. J. C. Zhang, and B. Materials. 2018. “Effect of ultraviolet radiation in different wavebands on bitumen.” Constr. Build. Mater. 159 (Jan): 479–485. https://doi.org/10.1016/j.conbuildmat.2017.10.117.
Ji, T., L. Xiao, and F. Chen. 2020. “Parametric analysis of the drainage performance of porous asphalt pavement based on a 3D FEM method.” J. Mater. Civ. Eng. 32 (12): 04020383. https://doi.org/10.1061/(ASCE)MT.1943-5533.0003468.
Jin, J., Y. Gao, Y. Wu, S. Liu, R. Liu, H. Wei, G. Qian, and J. J. P. T. Zheng. 2021. “Rheological and adhesion properties of nano-organic palygorskite and linear SBS on the composite modified asphalt.” Powder Technol. 377 (Jan): 212–221. https://doi.org/10.1016/j.powtec.2020.08.080.
Jin, J., Y. Tan, R. Liu, J. Zheng, and J. Zhang. 2019. “Synergy effect of attapulgite, rubber, and diatomite on organic montmorillonite-modified asphalt.” J. Mater. Civ. Eng. 31 (2): 04018388. https://doi.org/10.1061/(ASCE)MT.1943-5533.0002601.
Li, C., S. Wu, B. Shu, Y. Li, Z. J. C. Chen, and B. Materials. 2019. “Microwave absorption and anti-aging properties of modified bitumen contained SiC attached layered double hydroxides.” Constr. Build. Mater. 227 (Dec): 116714. https://doi.org/10.1016/j.conbuildmat.2019.116714.
Lv, S., S. Wang, T. Guo, C. Xia, J. Li, and G. J. A. S. Hou. 2018. “Laboratory evaluation on performance of compound-modified asphalt for rock asphalt/styrene–butadiene rubber (SBR) and rock asphalt/nano-CaCO3.” Appl. Sci. 8 (6): 1009. https://doi.org/10.3390/app8061009.
Mahali, I., and U. C. Sahoo. 2019. “Rheological characterization of nanocomposite modified asphalt binder.” Int. J. Pavement Res. Technol. 12 (6): 589–594. https://doi.org/10.1007/s42947-019-0070-8.
Ministry of Transport. 2011. Standard test methods of bitumen and bituminous mixtures for highway engineering. JTG E20-2011. Washington, DC: Ministry of Transport.
Pérez-Martínez, M., P. Marsac, T. Gabet, S. Pouget, and F. Hammoum. 2017. “Ageing evolution of foamed warm mix asphalt combined with reclaimed asphalt pavement.” Mater. Constr. 67 (327): 125. https://doi.org/10.3989/mc.2017.04716.
Qian, G., H. Yu, D. Jin, X. Bai, X. J. R. M. Gong, and P. Design. 2020. “Different water environment coupled with ultraviolet radiation on ageing of asphalt binder.” Road Mater. Pavement Des. 6 (2): 1–14. https://doi.org/10.1080/14680629.2020.1760920.
Qing, Z., L. Qi-Cheng, L. Peng, C. Chuan-Sheng, K. J. R. M. Jiang-Rong, and P. Design. 2020. “Study on modification mechanism of nano-ZnO/polymerised styrene butadiene composite-modified asphalt using density functional theory.” Road Mater. Pavement Des. 21 (5): 1426–1438. https://doi.org/10.1080/14680629.2018.1552888.
Sadeghpour Galooyak, S., M. Palassi, A. Goli, and H. Zanjirani Farahani. 2015. “Performance evaluation of nano-silica modified bitumen.” Int. J. Transp. Eng. 3 (1): 55–66. https://doi.org/10.22119/IJTE.2015.13377.
Shafabakhsh, G., S. Mirabdolazimi, M. J. C. Sadeghnejad, and B. Materials. 2014. “Evaluation the effect of nano-TiO2 on the rutting and fatigue behavior of asphalt mixtures.” Constr. Build. Mater. 54 (Mar): 566–571. https://doi.org/10.1016/j.conbuildmat.2013.12.064.
Tanzadeh, J., R. Tanzadeh, H. Nazari, and N. Kamvar. 2017. “Fatigue evaluation of hot mix asphalt (HMA) mixtures modified by optimum percent of TiO2 nanoparticles.” In Proc., Advanced Engineering Forum, 55–62. London: Trans Tech Publication.
Wang, C., S. Luo, C. Liu, X. Liu, and C. Chen. 2020a. “Photocatalytic performance of single crystal ZnO nanorods and ZnO nanorods films under natural sunlight.” Inorg. Chem. Commun. 114 (Apr): 107842. https://doi.org/10.1016/j.inoche.2020.107842.
Wang, D., Q. Liu, Q. Yang, C. Tovar, Y. Tan, M. J. R. M. Oeser, and P. Design. 2021. “Thermal oxidative and ultraviolet ageing behaviour of nano-montmorillonite modified bitumen.” Road Mater. Pavement Des. 22 (1): 121–139. https://doi.org/10.1080/14680629.2019.1619619.
Wang, F., L. Zhang, X. Zhang, H. Li, and S. J. P. Wu. 2020b. “Aging mechanism and rejuvenating possibility of SBS copolymers in asphalt binders.” Polymers (Basel) 12 (1): 92. https://doi.org/10.3390/polym12010092.
Wang, J., H. Zhang, C. J. C. Zhu, and B. Materials. 2020c. “Effect of multi-scale nanocomposites on performance of asphalt binder and mixture.” Constr. Build. Mater. 243 (May): 118307. https://doi.org/10.1016/j.conbuildmat.2020.118307.
Wei, H., X. Bai, G. Qian, F. Wang, Z. Li, J. Jin, and Y. J. M. Zhang. 2019. “Aging mechanism and properties of SBS modified bitumen under complex environmental conditions.” Materials (Basel) 12 (7): 1189. https://doi.org/10.3390/ma12071189.
Weigel, S., D. J. R. M. Stephan, and P. Design. 2018. “Relationships between the chemistry and the physical properties of bitumen.” Road Mater. Pavement Des. 19 (7): 1636–1650. https://doi.org/10.1080/14680629.2017.1338189.
Xie, X., T. Hui, Y. Luo, H. Li, G. Li, and Z. Wang. 2020. “Research on the properties of low temperature and anti-UV of asphalt with nano-ZnO/nano-TiO2/copolymer SBS composite modified in high-altitude areas.” Adv. Mater. Sci. Eng. 2020 (2): 1–15. https://doi.org/10.1155/2020/9078731.
Xing, C., L. Liu, Y. Cui, and D. J. F. Ding. 2020. “Analysis of base bitumen chemical composition and aging behaviors via atomic force microscopy-based infrared spectroscopy.” Fuel 264 (Mar): 116845. https://doi.org/10.1016/j.fuel.2019.116845.
Xu, X., H. Guo, X. Wang, M. Zhang, Z. Wang, B. J. C. Yang, and B. Materials. 2019. “Physical properties and anti-aging characteristics of asphalt modified with nano-zinc oxide powder.” Constr. Build. Mater. 224 (Nov): 732–742. https://doi.org/10.1016/j.conbuildmat.2019.07.097.
Yang, S., K. Yan, B. He, W. He, D. Wang, and H. Wang. 2018. “Ultraviolet and PAV aging procedures influence on rheological characteristics of Sasobit/SBS modified binder containing titanium dioxide nanoparticles.” Pet. Sci. Technol. 36 (19): 1524–1530. https://doi.org/10.1080/10916466.2018.1476535.
Yin, L., X. Yang, A. Shen, H. Wu, Z. Lyu, B. J. C. Li, and B. Materials. 2021. “Mechanical properties and reaction mechanism of microwave-activated crumb rubber-modified asphalt before and after thermal aging.” Constr. Build. Mater. 267 (Jan): 120773. https://doi.org/10.1016/j.conbuildmat.2020.120773.
Yu, H., X. Bai, G. Qian, H. Wei, X. Gong, J. Jin, and Z. J. P. Li. 2019. “Impact of ultraviolet radiation on the aging properties of SBS-modified asphalt binders.” Polymers (Basel) 11 (7): 1111. https://doi.org/10.3390/polym11071111.
Zhang, H., Z. Chen, G. Xu, and C. J. F. Shi. 2018. “Evaluation of aging behaviors of asphalt binders through different rheological indices.” Fuel 221 (Jun): 78–88. https://doi.org/10.1016/j.fuel.2018.02.087.
Zhang, H. B., H. L. Zhang, N. X. Ke, J. H. Huang, and C. Z. Zhu. 2015. “The effect of different nanomaterials on the long-term aging properties of bitumen.” Pet. Sci. Technol. 33 (4): 388–396. https://doi.org/10.1080/10916466.2014.986279.
Zhang, H.-L., M.-M. Su, S.-F. Zhao, Y.-P. Zhang, and Z.-P. Zhang. 2016. “High and low temperature properties of nano-particles/polymer modified asphalt.” Constr. Build. Mater. 114 (2): 323–332. https://doi.org/10.1016/j.conbuildmat.2016.03.118.

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Go to Journal of Materials in Civil Engineering
Journal of Materials in Civil Engineering
Volume 33Issue 11November 2021

History

Received: Jan 5, 2021
Accepted: Mar 19, 2021
Published online: Sep 2, 2021
Published in print: Nov 1, 2021
Discussion open until: Feb 2, 2022

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Zhongming He [email protected]
Professor, School of Traffic and Transportation Engineering, Changsha Univ. of Science and Technology, Changsha, Hunan 410004, China. Email: [email protected]
Tangxin Xie [email protected]
Graduate Student, School of Traffic and Transportation Engineering, Changsha Univ. of Science and Technology, Changsha, Hunan 410004, China. Email: [email protected]
Associate Professor, School of Architecture and Design, Changsha Vocational and Technical College, Changsha, Hunan 410217, China. Email: [email protected]
Panpan Wang [email protected]
Ph.D. Candidate, School of Traffic and Transportation Engineering, Changsha Univ. of Science and Technology, Changsha, Hunan 410004, China (corresponding author). Email: [email protected]

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