Technical Papers
Mar 31, 2021

Concrete Prepared Using Electrolyzed Water Revealed Benefits in Controlling the Early Age Properties

Publication: Journal of Materials in Civil Engineering
Volume 33, Issue 6

Abstract

To facilitate rapid hardening of concrete and to increase production rate, particularly at the precast manufacturing site, the use of electrolyzed water containing molecular hydrogen (H2) and hydroxyl ions (OH-) would be an effective alternative to the existing chemical set accelerators. In this study, electrolysis of water was performed by applying direct current (DC) voltage for 30 min using Pt and Ti electrodes separated by a polymeric membrane. Two types of concrete specimens were prepared using normal distilled water (CC) and 30-min electrolyzed water (30MEC) to compare the impact of electrolyzed water on the performances of concrete. The results revealed that the use of electrolyzed water for the fabrication of concrete (30MEC) not only improves the physical properties (e.g., bulk densities, apparent porosity, and water absorption) but also enhances the compressive strength by approximately 14.4%, 9.3%, and 4.9% and flexural strength by (approximately 16.7%, 12.8%, and 5.3%) than that of the concrete fabricated using normal water (CC) cured for 3, 7, and 28 days, respectively. The accelerated chemical reaction of cement particle due to the presence of OH- ions in the electrolyzed water may lead to improve the physical and mechanical properties of concrete. Finally, the plausible mechanism behind the early setting and strength gaining capability of electrolyzed water-based concrete has been explained based on the Fourier-transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), and Mercury intrusion porosity (MIP) analysis.

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Data Availability Statement

All data, models, and code generated or used during the study appear in the published article.

Acknowledgments

SERB-DST, Govt. of India (Project No. YSS/2015/001393) is sincerely acknowledged for their funding to execute this research program. Author Sumit Chakraborty gratefully acknowledges the H2020’s Marie-Curie Individual Fellowship Action for the Grant No. 838623.

References

Ahmed, M. S. 2009. “Effect of magnetic water on engineering properties of concrete.” AL-Rafdain Eng. J. 17 (1): 71–82. https://doi.org/10.33899/rengj.2009.38451.
Aïtcin, P. C., and R. Flatt. 2015. Science and technology of concrete admixtures. 1st ed. Cambridge, UK: Woodhead Publishing.
Arvaniti, E. C., M. C. Juenger, S. A. Bernal, J. Duchesne, L. Courard, S. Leroy, J. L. Provis, A. Klemm, and N. De Belie. 2015. “Determination of particle size, surface area, and shape of supplementary cementitious materials by different techniques.” Mater Struct. 48 (11): 3687–3701. https://doi.org/10.1617/s11527-014-0431-3.
ASTM. 2015a. Standard test method for relative density (specific gravity) and absorption of coarse aggregate. ASTM C127-15. West Conshohocken, PA: ASTM.
ASTM. 2015b. Standard test method for relative density (specific gravity) and absorption of fine aggregate. ASTM C128-15. West Conshohocken, PA: ASTM.
ASTM. 2015c. Standard test method for slump of hydraulic-cement concrete. ASTM C143/C143M-15A. West Conshohocken, PA: ASTM.
ASTM. 2016a. Standard test method for dry and wet bulk density, water absorption, and apparent porosity of thin sections of glass-fibre reinforced concrete. ASTM C948-81.C. West Conshohocken, PA: ASTM.
ASTM. 2016b. Standard test method for pulse velocity through concrete. ASTM C597-16. West Conshohocken, PA: ASTM.
ASTM. 2017. Standard specification for blended hydraulic cements. ASTM C595/C595M–20. ASTM: West Conshohocken, PA: ASTM.
ASTM. 2018. Standard specification for concrete aggregates. ASTM C33/C33M-18. West Conshohocken, PA: ASTM.
BIS (Bureau of Indian Standards). 1959. Methods of tests for strength of concrete. IS: 516. New Delhi, India: BIS.
BIS (Bureau of Indian Standards). 2000. Plain and reinforced concrete code of practice. IS: 456. New Delhi, India: BIS.
BIS (Bureau of Indian Standards). 2009. Concrete mix proportioning—Guidelines. IS: 10262. New Delhi, India: BIS.
BIS (Bureau of Indian Standards). 2016. Coarse and fine aggregate for concrete-specification. IS: 383. New Delhi, India: BIS.
Bower, J. 2001. The healthy house. 4th ed., edited by J. Bower. Bloomington, IN: The Healthy House Institute.
Cai, R., Z. He, S. Tang, T. Wu, and E. Chen. 2018. “The early hydration of metakaolin blended cements by non-contact impedance measurement.” Cem. Concr. Compos. 92 (Sep): 70–81. https://doi.org/10.1016/j.cemconcomp.2018.06.001.
Chakraborty, S., B. W. Jo, and M. A. Sikandar. 2016. “Hydration mechanism of the hydrogen-rich water based cement paste.” J. Phys. Chem. C. 120 (15): 8198–8209. https://doi.org/10.1021/acs.jpcc.6b01444.
Chakraborty, S., S. P. Kundu, A. Roy, B. Adhikari, and S. B. Majumder. 2013. “Effect of jute as fiber reinforcement controlling the hydration characteristics of cement matrix.” Ind. Eng. Chem. Res. 52 (3): 1252–1260. https://doi.org/10.1021/ie300607r.
Chakraborty, S., R. Mandal, S. Chattopadhyay, and S. Chakraborty. 2019. “Investigation on the effectiveness of electrolyzed water in controlling the early age properties of cement mortar.” Constr. Build. Mater. 211 (Jun): 1–11. https://doi.org/10.1016/j.conbuildmat.2019.03.237.
Clara, J. J., and P. K. Sugirtha. 2016. “Study of SEM/EDXS and FTIR for fly ash to determine the chemical changes of ash in marine environment.” Int. J. Sci. Res. 5 (7): 1688–1693.
Çomak, B. 2018. “Effects of use of alkaline mixing waters on engineering properties of cement mortars.” Eur. J. Environ. Civ. Eng. 22 (6): 736–754. https://doi.org/10.1080/19648189.2016.1217794.
Gettu, R., A. Patel, V. Rathi, S. Prakasan, A. S. Basavaraj, S. Palaniappan, and S. Maity. 2019. “Influence of supplementary cementitious materials on the sustainability parameters of cements and concretes in the Indian context.” Mater. Struct. 52 (1): 1–11. https://doi.org/10.1617/s11527-019-1321-5.
Huang, W., H. Kazemi-Kamyab, W. Sun, and K. Scrivener. 2017. “Effect of cement substitution by limestone on the hydration and microstructural development of ultra-high performance concrete (UHPC).” Cem. Concre. Compos. 77 (Mar): 86–101. https://doi.org/10.1016/j.cemconcomp.2016.12.009.
Jo, B. W., S. Chakraborty, and H. Kim. 2016. “Efficacy of alkali-treated jute as fibre reinforcement in enhancing the mechanical properties of cement mortar.” Mater. Struct. 49 (3): 1093–1104. https://doi.org/10.1617/s11527-015-0560-3.
Jo, B. W., S. Chakraborty, M. A. Sikandar, H. Kim, and K. H. Kim. 2015. “Hydrogen-rich water revealed benefits in controlling the physical and mechanical performances of cement mortar.” Constr. Build. Mater. 100 (Dec): 31–39. https://doi.org/10.1016/j.conbuildmat.2015.09.014.
Jo, B. W., M. A. Sikandar, S. Chakraborty, and Z. Baloch. 2017. “Investigation of corrosion assessment of hydrogen-rich water based cement mortars.” J. Ceram. Process. Res. 18 (4): 305–312. https://doi.org/10.36410/jcpr.2017.18.4.305.
Kou, S. C., B. J. Zhan, and C. S. Poon. 2014. “Use of a CO2 curing step to improve the properties of concrete prepared with recycled aggregates.” Cem. Concr. Compos. 45 (Jan): 22–28. https://doi.org/10.1016/j.cemconcomp.2013.09.008.
Li, W., Z. Luo, C. Long, C. Wu, W. H. Duan, and S. P. Shah. 2016. “Effects of nanoparticle on the dynamic behaviors of recycled aggregate concrete under impact loading.” Mater. Des. 112 (Dec): 58–66. https://doi.org/10.1016/j.matdes.2016.09.045.
Luo, Y., C. Wang, C. Luo, Q. Huang, S. Wang, and X. Peng. 2016. “Effect of electrical field on TSA failure of cement-based materials.” Cem. Concr. Res. 90 (Dec): 19–26. https://doi.org/10.1016/j.cemconres.2016.09.011.
Makul, N., P. Rattanadecho, and A. Pichaicherd. 2017. “Accelerated microwave curing of concrete: A design and performance-related experiments.” Cem. Concr. Compos. 83 (Oct): 415–426. https://doi.org/10.1016/j.cemconcomp.2017.08.007.
Mandal, R., S. Chakraborty, P. Chakraborty, and S. Chakraborty. 2019b. “Development of the electrolyzed water based set accelerated greener cement paste.” Mater. Lett. 243 (May): 46–49. https://doi.org/10.1016/j.matlet.2019.02.017.
Mandal, R., S. Chattopadhyay, S. Chakraborty, P. Chakraborty, and S. Chakraborty. 2019a. “Development of electrolyzed water based concrete: A new approach for early strength gain.” Accessed October 9, 2019. https://ukiericoncretecongress.com/Home/files/Proceedings/pdf/UCC-2019-193.pdf.
Miyandehi, B. M., A. Feizbakhsh, M. A. Yazdi, Q. F. Liu, J. Yang, and P. Alipour. 2016. “Performance and properties of mortar mixed with nano-CuO and rice husk ash.” Cem. Concr. Compos. 74 (Nov): 225–235. https://doi.org/10.1016/j.cemconcomp.2016.10.006.
Monkman, S., M. MacDonald, R. D. Hooton, and P. Sandberg. 2016. “Properties and durability of concrete produced using CO2 as an accelerating admixture.” Cem. Concr. Compos. 74 (Nov): 218–224. https://doi.org/10.1016/j.cemconcomp.2016.10.007.
Muller, A. C. A., and K. L. Scrivener. 2017. “A reassessment of mercury intrusion porosimetry by comparison with 1H NMR relaxometry.” Cem. Concr. Res. 100 (Oct): 350–360. https://doi.org/10.1016/j.cemconres.2017.05.024.
Myrdal, R. 2007. “Accelerating admixtures for concrete state of the art.” Accessed October 9, 2019. https://www.sintef.no/globalassets/sintef-byggforsk/coin/sintef-reports/sbf-bk-a07025_accelerating-admixtures-for-concrete.pdf.
Nawy, E. G. 2008. Concrete construction engineering handbook. Boca Raton, FL: CRC Press.
Ramachandran, V. S. 1995. Concrete admixtures handbook properties. Science and technology. 2nd ed. Park Ridge, NJ: Noyes Publications.
Ramachandran, V. S., and J. J. Beaudoin. 2000. Handbook of analytical techniques in concrete science and technology: Principles, techniques and applications. Amsterdam, Netherlands: Elsevier.
Rixom, R., and N. Mailvaganam. 1999. Chemical admixtures for concrete. 3rd ed. London: E & FN Spon.
Saghiri, M. A., F. Garcia-Godoy, A. Asatourian, M. Lotfi, S. Banava, and K. Khezri-Boukani. 2013. “Effect of pH on compressive strength of some modification of mineral trioxide aggregate.” Medicina Oral Patologia Oral Y Cirugia Bucal 18 (4): 714–720. https://doi.org/10.4317/medoral.18922.
Silva, D. 2009. “Impact of accelerators and retarders on the hydration of portland cement.” Accessed July 29, 2009. http://blogs.cae.tntech.edu/hydration-kinetics/files/2009/08/silva_01_cement-summit-retarders3.pdf.
Snehal, K., B. B. Das, and S. Kumar. 2020. “Influence of integration of phase change materials on hydration and microstructure properties of nanosilica admixed cementitious mortar.” J. Mater. Civ. Eng. 32 (6): 04020108. https://doi.org/10.1061/(ASCE)MT.1943-5533.0003178.
Sobhnamayan, F., S. Sahebi, A. Alborzi, S. Ghorbani, and N. S. Shojaee. 2015. “Effect of different pH values on the compressive strength of calcium-enriched mixture cement.” Iran Endodontic J. 10 (1): 26–29. https://doi.org/10.22037/iej.v10i1.6463.
Statista. 2018. “Global electricity prices in by select country.” Accessed September 18, 2019. https://www.statista.com/statistics/263492/electricity-prices-in-selected-countries/.
Stepkowska, E. T., J. M. Blanes, C. Real, and J. L. Perez-Rodriguez. 2005. “Hydration products in two aged cement pastes.” J. Therm. Anal. Calorim. 82 (3): 731–739. https://doi.org/10.1007/s10973-005-0957-2.
Torres-Carrasco, M., A. del Campo, M. A. de la Rubia, E. Reyes, A. Moragues, and J. F. Fernández. 2017. “New insights in weathering analysis of anhydrous cements by using high spectral and spatial resolution Confocal Raman microscopy.” Cem. Concr. Res. 100 (Oct): 119–128. https://doi.org/10.1016/j.cemconres.2017.06.003.
Wang, L., K. Uji, H. Morozumi, and M. Uemura. 2016. “The experimental study on the strength improvement of concrete introducing different electrolyzed waters.” Accessed October 9, 2019. https://www.claisse.info/2016%20papers/D148.pdf.
Ye, J. Q., and Z. J. Wu. 2000. “Micro-mechanical analysis of splitting failure in concrete reinforced with fiber reinforced plastic rods.” Cem. Concr. Compos. 22 (4): 243–251. https://doi.org/10.1016/S0958-9465(00)00023-8.
Zhang, M. H., J. Islam, and S. Peethamparan. 2012. “Use of nano-silica to increase early strength and reduce setting time of concretes with high volumes of slag.” Cem. Concr. Compos. 34 (5): 650-662. https://doi.org/10.1016/j.cemconcomp.2012.02.005.

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Go to Journal of Materials in Civil Engineering
Journal of Materials in Civil Engineering
Volume 33Issue 6June 2021

History

Received: Apr 4, 2020
Accepted: Nov 16, 2020
Published online: Mar 31, 2021
Published in print: Jun 1, 2021
Discussion open until: Aug 31, 2021

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Dept. of Civil Engineering, Indian Institute of Engineering Science and Technology, ShibpurDhanbad, Howrah, West Bengal 711103, India. ORCID: https://orcid.org/0000-0001-8651-5758. Email: [email protected]
Marie-Curie Individual Fellow, Dept. of Civil and Structural Engineering, Univ. of Sheffield, Sheffield S1 3JD, UK (corresponding author). ORCID: https://orcid.org/0000-0002-1387-0385. Email: [email protected]; [email protected]
Subrata Chakraborty [email protected]
Professor, Dept. of Civil Engineering, Indian Institute of Engineering Science and Technology, Shibpur, Howrah, West Bengal 711103, India. Email: [email protected]

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