Performance Evaluation of Lime Mortars with Metakaolin and CMC for Restoration Application
Publication: Journal of Materials in Civil Engineering
Volume 32, Issue 10
Abstract
The degradation of ancient buildings has attracted much attention, and plane lime mortar cannot meet the requirements of utilization in special environmental loads or buildings. In order to improve the hydraulic properties and freeze-thaw resistance of lime mortars, both carboxymethyl cellulose (CMC) and metakaolin were added to plane lime mortars in this study. The performance of lime mortars with different additives was evaluated. The experimental results showed that the combined effect of CMC and metakaolin on compressive strength of lime mortars could be divided into three stages according to the curing age. The early compressive strength of blended mortars is improved. With increasing curing ages, the compressive strength varied in accordance with the phase transition of hydration and carbonation products. Furthermore, blended mortar with a long curing age exhibits better freeze-thaw resistance. These results suggest that the combined action of metakaolin and CMC played a significant role in the properties of lime mortars, which is generally beneficial for restoration applications, especially for ancient buildings in cold regions.
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Data Availability Statement
All data, models, and code generated or used during the study appear in the published article.
Acknowledgments
The financial support for this work from the National Key R&D Program of China (No. 2018YFC1901502) is gratefully acknowledged. This work was also financially supported by the National Natural Science Foundation of China (Grant No. 51674183) and Natural Science Foundation of Hubei Province of China (Grant No. 2018CFB468). Finally, thanks are given to Aurora Robledo Cabrera for providing the technical support.
References
Andrejkovičová, S., C. Alves, A. Velosa, and F. Rocha. 2015. “Bentonite as a natural additive for lime and lime–metakaolin mortars used for restoration of adobe buildings.” Cem. Concr. Compos. 60 (Jul): 99–110. https://doi.org/10.1016/j.cemconcomp.2015.04.005.
Arandigoyen, M., and J. I. Alvarez. 2007. “Pore structure and mechanical properties of cement-lime mortars.” Cem. Concr. Res. 37 (5): 767–775. https://doi.org/10.1016/j.cemconres.2007.02.023.
Arizzi, A., and G. Cultrone. 2018. “Comparing the pozzolanic activity of aerial lime mortars made with metakaolin and fluid catalytic cracking catalyst residue: A petrographic and physical-mechanical study.” In Vol. 184 of Construction and building materials, 382–390. New York: Elsevier.
ASTM. 2003. Standard guide for repointing. ASTM E2260-03. West Conshohocken, PA: ASTM.
Biswal, D. R., and R. P. Singh. 2004. “Characterisation of carboxymethyl cellulose and polyacrylamide graft copolymer.” Carbohydr. Polym. 57 (4): 379–387. https://doi.org/10.1016/j.carbpol.2004.04.020.
CNS (Chinese National Standard). 2009. Standard for test method of performance on building mortar. Beijing: CNS.
Collepardi, M. 1990. “Degradation and restoration of masonry walls of historical buildings.” Mater. Struct. 23 (2): 81–102. https://doi.org/10.1007/BF02472568.
Dai, M., C. Peng, H. Liu, J. Wang, I. Ali, and I. Naz. 2019. “Analysis and imitation of organic Sanhetu concrete discovered in an ancient Chinese tomb of Qing Dynasty.” J. Archaeolog. Sci.: Rep. 26 (Aug): 101918. https://doi.org/10.1016/j.jasrep.2019.101918.
de Silva, P. S., and F. P. Glasser. 1992. “Phase relation in the system relevant to metakaolin—Calcium hydroxide hydration.” Cem. Concr. Res. 23 (3): 627–639. https://doi.org/10.1016/0008-8846(93)90014-Z.
Ergenç, D., A. Sierra-Fernandez, M. del Mar Barbero-Barrera, L. S. Gomez-Villalba, and R. Fort. 2020. “Assessment on the performances of air lime-ceramic mortars with nano- and nano- additions.” Constr. Build. Mater. 232 (Jan): 117163. https://doi.org/10.1016/j.conbuildmat.2019.117163.
Fortes-Revilla, C., S. Martínez-Ramírez, and M. T. Blanco-Varela. 2006. “Modelling of slaked lime–metakaolin mortar engineering characteristics in terms of process variables.” Cem. Concr. Compos. 28 (5): 458–467. https://doi.org/10.1016/j.cemconcomp.2005.12.006.
Franco, A. P., and A. L. R. Mercê. 2006. “Complexes of carboxymethylcellulose in water. 1: , and .” React. Funct. Polym. 66 (6): 667–681. https://doi.org/10.1016/j.reactfunctpolym.2005.10.018.
Gonçalves, T. D., L. Pel, and J. D. Rodrigues. 2008. “Worsening of dampness and salt damage after restoration interventions: Use of water repellent additives in plasters and renders.” In Proc., 1st Historical Mortars Conference. Lisbon, Portugal: Laboratório Nacional de Engenharia Civil.
Grilo, J., A. Santos Silva, P. Faria, A. Gameiro, R. Veiga, and A. Velosa. 2014. “Mechanical and mineralogical properties of natural hydraulic lime-metakaolin mortars in different curing conditions.” In Construction and building materials, 287–294. New York: Elsevier.
He, C., B. Osbaeck, and E. Makovicky. 1995. “Pozzolanic reactions of six principal clay minerals: Activation, reactivity assessments and technological effects.” Cem. Concr. Res. 25 (8): 1691–1702. https://doi.org/10.1016/0008-8846(95)00165-4.
Hu, D., H. Wang, and L. Wang. 2016. “Physical properties and antibacterial activity of quaternized chitosan/carboxymethyl cellulose blend films.” LWT–Food Sci. Technol. 65 (Jan): 398–405. https://doi.org/10.1016/j.lwt.2015.08.033.
Izaguirre, A., J. Lanas, and J. I. Álvarez. 2009. “Effect of water-repellent admixtures on the behaviour of aerial lime-based mortars.” Cem. Concr. Res. 39 (11): 1095–1104. https://doi.org/10.1016/j.cemconres.2009.07.026.
Izaguirre, A., J. Lanas, and J. I. Álvarez. 2011. “Characterization of aerial lime-based mortars modified by the addition of two different water-retaining agents.” Cem. Concr. Compos. 33 (2): 309–318. https://doi.org/10.1016/j.cemconcomp.2010.09.008.
Klimesch, D. S., and A. Ray. 1998. “DTA–TGA of unstirred autoclaved metakaolin–lime–quartz slurries. The formation of hydrogarnet.” Thermochim. Acta 316 (2): 149–154. https://doi.org/10.1016/S0040-6031(98)00307-4.
Klimesch, D. S., and A. Ray. 1999. “DTA-TGA evaluations of the CaO–Al2O3–SiO2–H2O system treated hydrothermally.” Thermochim. Acta 334 (1): 115–122. https://doi.org/10.1016/S0040-6031(99)00140-9.
Lanas, J., R. Sirera, and J. I. Alvarez. 2006. “Study of the mechanical behavior of masonry repair lime-based mortars cured and exposed under different conditions.” Cem. Concr. Res. 36 (5): 961–970. https://doi.org/10.1016/j.cemconres.2005.12.003.
Li, D., Z. Li, C. Lv, G. Zhang, and Y. Yin. 2018. “A predictive model of the effective tensile and compressive strengths of concrete considering porosity and pore size.” Constr. Build. Mater. 170 (May): 520–526. https://doi.org/10.1016/j.conbuildmat.2018.03.028.
Liang, C., B. Pan, Z. Ma, Z. He, and Z. Duan. 2020. “Utilization of curing to enhance the properties of recycled aggregate and prepared concrete: A review.” In Cement and concrete composites, 103446. New York: Elsevier.
Liang, C. Y., and R. H. Marchessault. 1959. “Infrared spectra of crystalline polysaccharides. I. Hydrogen bonds in native celluloses.” J. Polymer Sci. 37 (132): 385–395. https://doi.org/10.1002/pol.1959.1203713209.
Liu, H., Y. Zhao, C. Peng, S. Song, and A. López-Valdivieso. 2018. “Lime mortars—The role of carboxymethyl cellulose on the crystallization of calcium carbonate.” Constr. Build. Mater. 168 (Apr): 169–177. https://doi.org/10.1016/j.conbuildmat.2018.02.119.
Liu, H., Y. Zhao, C. Peng, S. Song, and A. López–Valdivieso. 2016. “Improvement of compressive strength of lime mortar with carboxymethyl cellulose.” J. Mater. Sci. 51 (20): 9279–9286. https://doi.org/10.1007/s10853-016-0174-3.
Maravelaki-Kalaitzaki, P., A. Bakolas, and A. Moropoulou. 2003. “Physico-chemical study of Cretan ancient mortars.” Cem. Concr. Res. 33 (5): 651–661. https://doi.org/10.1016/S0008-8846(02)01030-X.
Martínez-García, C., B. González-Fonteboa, D. Carro-López, and F. Martínez-Abella. 2019. “Impact of mussel shell aggregates on air lime mortars. Pore structure and carbonation.” J. Cleaner Prod. 215 (Apr): 650–668. https://doi.org/10.1016/j.jclepro.2019.01.121.
Mishra, P. C., V. K. Singh, K. K. Narang, and N. K. Singh. 2003. “Effect of carboxymethyl-cellulose on the properties of cement.” Mater. Sci. Eng. A 357 (1): 13–19. https://doi.org/10.1016/S0921-5093(02)00832-8.
Moropoulou, A., A. Bakolas, P. Moundoulas, E. Aggelakopoulou, and S. Anagnostopoulou. 2005. “Strength development and lime reaction in mortars for repairing historic masonries.” Cem. Concr. Compos. 27 (2): 289–294. https://doi.org/10.1016/j.cemconcomp.2004.02.017.
Nežerka, V., Z. Slížková, P. Tesárek, T. Plachý, D. Frankeová, and V. Petráňová. 2014. “Comprehensive study on mechanical properties of lime-based pastes with additions of metakaolin and brick dust.” Cem. Concr. Res. 64 (Oct): 17–29. https://doi.org/10.1016/j.cemconres.2014.06.006.
Nunes, C., and Z. Slížková. 2016. “Freezing and thawing resistance of aerial lime mortar with metakaolin and a traditional water-repellent admixture.” Constr. Build. Mater. 114 (Jul): 896–905. https://doi.org/10.1016/j.conbuildmat.2016.04.029.
Pavlík, V., and M. Užáková. 2016. “Effect of curing conditions on the properties of lime, lime–metakaolin and lime–zeolite mortars.” Constr. Build. Mater. 102 (Part 1): 14–25. https://doi.org/10.1016/j.conbuildmat.2015.10.128.
Pensini, E., C. M. Yip, D. O’Carroll, and B. E. Sleep. 2013. “Carboxymethyl cellulose binding to mineral substrates: Characterization by atomic force microscopy-based force spectroscopy and quartz-crystal microbalance with dissipation monitoring.” J. Colloid Interface Sci. 402: 58–67. https://doi.org/10.1016/j.jcis.2013.03.053.
Schueremans, L., Ö. Cizer, E. Janssens, G. Serré, and K. Van Balen. 2011. “Characterization of repair mortars for the assessment of their compatibility in restoration projects: Research and practice.” Constr. Build. Mater. 25 (12): 4338–4350. https://doi.org/10.1016/j.conbuildmat.2011.01.008.
Sepulcre-Aguilar, A., and F. Hernández-Olivares. 2010. “Assessment of phase formation in lime-based mortars with added metakaolin, portland cement and sepiolite, for grouting of historic masonry.” Cem. Concr. Res. 40 (1): 66–76. https://doi.org/10.1016/j.cemconres.2009.08.028.
Vagenas, N. V., A. Gatsouli, and C. G. Kontoyannis. 2003. “Quantitative analysis of synthetic calcium carbonate polymorphs using FT-IR spectroscopy.” Talanta 59 (4): 831–836. https://doi.org/10.1016/S0039-9140(02)00638-0.
Velosa, A. L., F. Rocha, and R. Veiga. 2009. “Influence of chemical and mineralogical composition of metakaolin on mortar characteristics.” Acta Geodynamica et Geomaterialia 153 (6): 121–126. https://doi.org/10.1016/j.jnucmat.2008.10.004.
Yang, F., B. Zhang, and Q. Ma. 2010. “Study of sticky rice−lime mortar technology for the restoration of historical masonry construction.” Accounts Chem. Res. 43 (6): 936–944. https://doi.org/10.1021/ar9001944.
Zeng, Y., B. Zhang, and X. Liang. 2008. “A case study and mechanism investigation of typical mortars used on ancient architecture in China.” Thermochim. Acta 473 (1): 1–6. https://doi.org/10.1016/j.tca.2008.03.019.
Zhang, M. H., and V. M. Malhotra. 1995. “Characteristics of a thermally activated alumino-silicate pozzolanic material and its use in concrete.” Cem. Concr. Res. 25 (8): 1713–1725. https://doi.org/10.1016/0008-8846(95)00167-0.
Zhang, S., K. Cao, C. Wang, X. Wang, G. Deng, and P. Wei. 2020. “Influence of the porosity and pore size on the compressive and splitting strengths of cellular concrete with millimeter-size pores.” Constr. Build. Mater. 235 (Feb): 117508. https://doi.org/10.1016/j.conbuildmat.2019.117508.
Zhu, P., Y. Hao, H. Liu, D. Wei, S. Liu, and L. Gu. 2019. “Durability evaluation of three generations of 100% repeatedly recycled coarse aggregate concrete.” In Construction and building materials, 442–450. New York: Elsevier.
Zhu, W., X. Chen, L. J. Struble, and E. H. Yang. 2018. “Characterization of calcium-containing phases in alkali-activated municipal solid waste incineration bottom ash binder through chemical extraction and deconvoluted Fourier transform infrared spectra.” J. Cleaner Prod. 192 (Aug): 782–789. https://doi.org/10.1016/j.jclepro.2018.05.049.
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Received: Sep 4, 2019
Accepted: Mar 24, 2020
Published online: Jul 28, 2020
Published in print: Oct 1, 2020
Discussion open until: Dec 28, 2020
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