Technical Papers
Jun 2, 2020

Rheological and Mechanical Evaluation of Polyurethane Prepolymer-Modified Asphalt Mixture with Self-Healing Abilities

Publication: Journal of Materials in Civil Engineering
Volume 32, Issue 8

Abstract

The objective of this study was to evaluate the effect of an innovative UV light-activated self-healing polyurethane prepolymer (SPP) on the rheological, mechanical, and self-healing properties of asphalt mixture. This new additive combines polymer modification and self-healing capability into one modifier in order to enhance the mechanical properties of asphalt mixture, while increasing its crack healing rate. For this purpose, asphalt mixtures were prepared with asphalt binder modified with three percentages (5%, 10%, and 15%) of self-healing polyurethane prepolymer. A self-healing test was performed to evaluate the rate of crack healing in asphalt mixtures prepared with or without self-healing polyurethane. Furthermore, a Semi-Circular Bending test and a Loaded Wheel Tracking test were conducted to study the fatigue and rutting resistances of the prepared samples. Asphalt binder was also extracted from the samples and was tested using the dynamic shear rheometer and bending beam rheometer. An increase in the crack healing rate was observed with 5% and 10% self-healing polymer; however, when the SPP percentage was increased to 15%, the healing efficiency was affected adversely. The addition of SPP also led to an improvement in the cracking and rutting resistances. Results from the rheological test showed that SPP resulted in an increase in the high-temperature grading while the low-temperature grading was not affected. Furthermore, multiple stress creep recovery test results showed an improvement in the elastic recovery and rutting resistance of the binder extracted from aged and unaged asphalt mixtures.

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Data Availability Statement

All data, models, and code generated or used during the study appear in the published article.

Acknowledgments

The authors would also like to acknowledge the laboratory support from the Louisiana Transportation Research Center (LTRC).

References

AASHTO. 2011. Standard specification for recovery of asphalt binder from solution by Abson method (ASTM designation D1856-09). AASHTO R59-11. Washington, DC: AASHTO.
AASHTO. 2013. Standard method of test for multiple stress creep recovery (MSCR) test of asphalt binder using a dynamic shear rheometer (DSR). AASHTO TP70. Washington, DC: AASHTO.
AASHTO. 2014. Standard method of test for quantitative extraction of asphalt binder from hot mix asphalt (HMA). AASHTO T164. Washington, DC: AASHTO.
AASHTO. 2015. Standard practice for grading or verifying the performance grade of an asphalt binder. AASHTO R29-15. Washington, DC: AASHTO.
AASHTO. 2017a. Standard practice for superpave volumetric design for asphalt mixtures. AASHTO R35. Washington, DC: AASHTO.
AASHTO. 2017b. Standard specification for performance-graded asphalt binder. AASHTO M320. Washington, DC: AASHTO.
AASHTO. 2017c. Standard specification for superpave volumetric mix design. AASHTO M323. Washington, DC: AASHTO.
AASHTO. 2018. Standard method of test for estimating fatigue resistance of asphalt binders using the linear amplitude sweep. AASHTO TP101-12. Washington, DC: AASHTO.
Aguirre, M. A., M. M. Hassan, S. Shirzad, S. Cooper, L. N. Mohammad, and I. I. Negulescu. 2019. “Laboratory testing of self-healing fibers in asphalt mixtures prepared with recycled materials.” Transp. Res. Rec. 2673 (4): 513–523. https://doi.org/10.1177/0361198119836978.
Aguirre, M. A., M. M. Hassan, S. Shirzad, L. N. Mohammad, and S. B. Cooper. 2017. “Performance of asphalt rejuvenators in hot-mix asphalt containing recycled asphalt shingles.” Transp. Res. Rec. 2633 (1): 108–116. https://doi.org/10.3141/2633-13.
Al-Mansoori, A., J. Norambuena-Contrerasa, R. Micaelo, and A. Garcia. 2018. “Self-healing of asphalt mastic by the action of polymeric capsules containing rejuvenators.” Constr. Build. Mater. 161 (Feb): 330–339. https://doi.org/10.1016/j.conbuildmat.2017.11.125.
Anderson, M., D. King, D. Hanson, and P. B. Blankenship. 2011. “Evaluation of the relationship between asphalt binder properties and non-load related cracking.” J. Assoc. Asphalt Paving Technol. 80 (Mar): 615–661.
ASTM. 2016. Standard test method for evaluation of asphalt mixture cracking resistance using the semi-circular bend test (SCB) at intermediate temperatures. ASTM D8044-16. West Conshohocken, PA: ASTM.
Becker, Y., M. P. Méndez, and Y. Rodríguez. 2001. “Polymer modified asphalt.” Vision Tecnologica 9 (1): 39–50.
Bulatovic, V. O., V. Rek, and K. J. Markovic. 2014. “Effect of polymer modifiers on the properties of bitumen.” J. Elastomers Plast. 46 (5): 448–469. https://doi.org/10.1177/0095244312469964.
Carrera, V., P. Partal, M. García-Morales, C. Gallegos, and A. Pérez-Lepe. 2010. “Effect of processing on the rheological properties of poly-urethane/urea bituminous products.” Fuel Process. Technol. 91 (9): 1139–1145. https://doi.org/10.1016/j.fuproc.2010.03.028.
Elkashef, M., J. Podolsky, C. Williams, and E. Cochran. 2017. “Preliminary examination of soybean oil derived material as a potential rejuvenator through Superpave criteria and asphalt bitumen rheology.” Constr. Build. Mater. 149 (Sep): 826–836. https://doi.org/10.1016/j.conbuildmat.2017.05.195.
Ghosh, B., K. V. Chellappan, and M. W. Urban. 2011. “Self-healing inside a scratch of oxetane-substituted chitosan-polyurethane (OXE-CHI-PUR) networks.” J. Mater. Chem. 21 (38): 14473–14486. https://doi.org/10.1039/c1jm12321a.
Karve, M., N. K. Patel, and S. Polara. 2016. “Modification of asphalt using castor oil based polyurethane.” Int. J. Sci. Res. 5 (9): 159–161.
Li, R., J. Chen, T. Zhou, and J. Pei. 2016. “Preparation and characterization of novel light induced self-healing materials for cracks in asphalt pavements.” Constr. Build. Mater. 105 (Feb): 336–342. https://doi.org/10.1016/j.conbuildmat.2015.12.004.
Louisiana Department of Transportation and Development. 2016. Louisiana standard specifications for roads and bridges. Baton Rouge, LA: Louisiana Dept. of Transportation and Development.
Norambuena-Contrerasa, J., and A. Garcia. 2016. “Self-healing of asphalt mixture by microwave and induction heating.” Mater. Des. 106 (Sep): 404–414. https://doi.org/10.1016/j.matdes.2016.05.095.
Notani, M., and M. Mokhtarnejad. 2018. “Investigating the rheological and self-healing capability of toner-modified asphalt binder.” Proc. Inst. Civ. Eng. Constr. Mater. 1–9. https://doi.org/10.1680/jcoma.17.00072.
Praticò, F. G., A. Casciano, and D. Tramontana. 2011. “Pavement life-cycle cost and asphalt binder quality: Theoretical and experimental investigation.” J. Constr. Eng. Manage. 137 (2): 99–107. https://doi.org/10.1061/(ASCE)CO.1943-7862.0000264.
Química, D. D. I., and Q. Física. 2010. “Physico chemical modification of asphalt bitumens by reactive agents.” Ph.D. dissertation, Universidad de Huelva.
Shirzad, S., M. M. Hassan, M. A. Aguirre, S. Cooper, and I. I. Negulescu. 2018. “Effects of light-activated self-healing polymers on the rheological behaviors of asphalt binder containing recycled asphalt shingles.” Transp. Res. Rec. 2672 (28): 301–310. https://doi.org/10.1177/0361198118772726.
Shirzad, S., M. M. Hassan, M. A. Aguirre, L. N. Mohammad, S. Cooper, and I. I. Negulescu. 2017. “Microencapsulated sunflower oil for rejuvenation and healing of asphalt mixtures.” J. Mater. Civ. Eng. 29 (9): 04017147. https://doi.org/10.1061/(ASCE)MT.1943-5533.0001988.
Shirzad, S., M. M. Hassan, M. A. Aguirre, L. N. Mohammad, S. Cooper, and I. I. Negulescu. 2019a. “Mechanical and self-healing performances of asphalt mixtures containing recycled asphalt materials and light-activated self-healing polymer.” J. Mater. Civ. Eng. 31 (11): 04019254. https://doi.org/10.1061/(ASCE)MT.1943-5533.0002903.
Shirzad, S., M. M. Hassan, and L. Mohammad. 2019b. “Rheological properties of asphalt binder modified with recycled asphalt materials and light-activated self-healing.” J. Constr. Build. Mater. 220: 187–195.
Tabaković, A., W. Post, D. Cantero, O. Copuroglu, S. J. Garcia, and E. Schlangen. 2015. “The reinforcement and healing of asphalt mastic mixtures by rejuvenator encapsulation in alginate compartmented fibres.” Smart Mater. Struct. 25 (8): 12. https://doi.org/10.1088/0964-1726/25/8/084003.
Tabaković, A., and E. Schlangen. 2015. “Self-healing technology for asphalt pavements.” In Self-healing materials, 285–306. Cham, Switzerland: Springer.
Wang, J., J. Yuan, F. Xiao, Z. Li, J. Wang, and Z. Xu. 2018. “Performance investigation and sustainability evaluation of multiple-polymer asphalt mixtures in airfield pavement.” J. Cleaner Prod. 189 (Jul): 67–77. https://doi.org/10.1016/j.jclepro.2018.03.208.
Xu, S., A. Tabakovic, X. Liu, and E. Schlangen. 2018. “Calcium alginate capsules encapsulating rejuvenator as healing system for asphalt mastic.” Constr. Build. Mater. 169 (Apr): 379–387. https://doi.org/10.1016/j.conbuildmat.2018.01.046.
Yao, H., Q. Dai, and Z. You. 2015. “Fourier transform infrared spectroscopy characterization of aging-related properties of original and nano-modified asphalt binders.” Constr. Build. Mater. 101 (Dec): 1078–1087. https://doi.org/10.1016/j.conbuildmat.2015.10.085.
Yildirim, Y. 2007. “Polymer modified asphalt binders.” Constr. Build. Mater. 21 (1): 66–72. https://doi.org/10.1016/j.conbuildmat.2005.07.007.
Yu, R., X. Zhu, X. Zhou, Y. Kou, M. Zhang, and C. Fang. 2018. “Rheological properties and storage stability of asphalt modified with nanoscale polyurethane emulsion.” Pet. Sci. Technol. 36 (1): 85–90. https://doi.org/10.1080/10916466.2017.1405028.
Zaumanis, M., R. B. Mallick, L. Poulikakos, and R. Frank. 2014. “Influence of six rejuvenators on the performance properties of reclaimed asphalt pavement (RAP) binder and 100% recycled asphalt mixtures.” Constr. Build. Mater. 71 (Nov): 538–550. https://doi.org/10.1016/j.conbuildmat.2014.08.073.
Zhou, F., P. Karki, and S. Im. 2017. “Development of a simple fatigue cracking test for asphalt binders.” Transp. Res. Rec. 2632 (1): 79–87. https://doi.org/10.3141/2632-09.

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Go to Journal of Materials in Civil Engineering
Journal of Materials in Civil Engineering
Volume 32Issue 8August 2020

History

Received: Nov 21, 2019
Accepted: Feb 11, 2020
Published online: Jun 2, 2020
Published in print: Aug 1, 2020
Discussion open until: Nov 2, 2020

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Authors

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Sharareh Shirzad, S.M.ASCE [email protected]
Graduate Research Assistant, Dept. of Construction Management, Louisiana State Univ., Baton Rouge, LA 70803. Email: [email protected]
CETF Distinguished Professor, Dept. of Construction Management, Louisiana State Univ., Baton Rouge, LA 70803 (corresponding author). ORCID: https://orcid.org/0000-0001-8087-8232. Email: [email protected]
Louay N. Mohammad, F.ASCE [email protected]
Irma-Louise Rush Stewart Professor, Dept. of Civil and Environmental Engineering, Louisiana State Univ., Baton Rouge, LA 70803. Email: [email protected]

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