Technical Papers
May 4, 2020

Insights into Determination of Gas Breakthrough in Saturated Compacted Gaomiaozi Bentonite

Publication: Journal of Materials in Civil Engineering
Volume 32, Issue 7

Abstract

Gas breakthrough pressure is of great importance for evaluating the sealing efficiency and assessing the long-term performance of saturated buffering materials with low permeability in the deep geological disposal of high-level radioactive waste. In this study, to investigate gas breakthrough properties, step-by-step (SBS), residual capillary pressure, and mercury intrusion porosimetry tests were conducted on saturated Gaomiazoi (GMZ) bentonite specimens. Results show that, compared with the other two methods, only SBS tests can accurately measure the gas breakthrough pressure. Meanwhile, the results of gas injection tests by the SBS method indicate that gas intrusion into a specimen in the inlet accompanied by water displacement at the outlet is not an instantaneous process. Therefore, the time required for pore pressure equilibrium during each pressure step was calculated, which is in inverse proportion to the intrinsic permeability of the compacted bentonite materials. Furthermore, the gas injection tests also show that gas breakthrough could also occur at lower pressure levels, i.e., snap-off pressure, which is far below the value of the breakthrough pressure. The differences between the breakthrough pressure and the snap-off pressure could be induced by the hysteretic behavior of the bentonite material during the drainage and imbibition processes. The delayed re-imbibition of water will induce further gas migration through the interconnected pore space and a lower capillary pressure. Experimental results in this work are very useful for the engineering design and safety assessments of the repository.

Get full access to this article

View all available purchase options and get full access to this article.

Data Availability Statement

All data, models, and code generated or used during the study appear in the published article.

Acknowledgments

The financial support of the National Nature Science Foundation of China (41527801, 41672271, and 41807237) and the Shanghai Pujiang Program (18PJ1410200) is greatly acknowledged.

References

Al-Bazali, T. M., J. Zhang, M. E. Chenevert, and M. M. Sharma. 2005. “Measurement of the sealing capacity of shale caprocks.” In Proc., SPE Annual Technology Conf. and Exhibition. Dallas: Society of Petroleum Engineers. https://doi.org/10.2118/96100-MS.
Boulin, P. F., P. Bretonnier, V. Vassil, A. Samouillet, M. Fleury, and J. M. Lombard. 2013. “Sealing efficiency of caprocks: Experimental investigation of entry pressure measurement methods.” Mar. Pet. Geol. 48 (48): 20–30. https://doi.org/10.1016/j.marpetgeo.2013.07.010.
Brace, W. F., J. B. Walsh, and W. T. Frangos. 1968. “Permeability of granite under high pressure.” J. Geophys. Res. 73 (6): 2225–2236. https://doi.org/10.1029/JB073i006p02225.
Busch, A., and A. Amann-Hildenbrand. 2013. “Predicting capillarity of mudrocks.” Mar. Pet. Geol. 45 (4): 208–223. https://doi.org/10.1016/j.marpetgeo.2013.05.005.
Cui, L. Y., W. M. Ye, Q. Wang, Y. G. Chen, B. Chen, and Y. J. Cui. 2019. “Investigation on gas migration in saturated bentonite using the residual capillary pressure technique with consideration of temperature.” Process Saf. Environ. Prot. 125 (May): 269–278. https://doi.org/10.1016/j.psep.2019.03.036.
Cuss, R. J., J. F. Harrington, D. J. Noy, A. Wikman, and P. Sellin. 2011. “Large scale gas injection test (Lasgit): Results from two gas injection tests.” Phys. Chem. Earth. Parts A/B/C 36 (17–18): 1729–1742. https://doi.org/10.1016/j.pce.2011.07.022.
Delage, P., and G. Lefebvre. 1984. “Study of the structure of a sensitive Champlain clay and of its evolution during consolidation.” Can. Geotech. J. 21 (1): 21–35. https://doi.org/10.1139/t84-003.
Dewhurst, D. N., R. M. Jones, and M. D. Raven. 2002. “Microstructural and petrophysical characterization of Muderong Shale: Application to top seal risking.” Pet. Geosci. 8 (4): 371–383. https://doi.org/10.1144/petgeo.8.4.371.
Duan, Z., C. A. Davy, F. Agostini, L. Jeannin, D. Troadec, and F. Skoczylas. 2014. “Gas recovery potential of sandstones from tight gas reservoirs.” Int. J. Rock Mech. Min. Sci. 65 (Jan): 75–85. https://doi.org/10.1016/j.ijrmms.2013.11.011.
Egermann, P., J.-M. Lombard, and P. Bretonnier. 2006. “A fast and accurate method to measure threshold capillary pressure of caprocks under representative conditions.” In Proc., Int. Symp. of the Society of Core Analysts. Inverurie, Scotland: SKM Services Limited.
Graham, J., K. G. Halayko, H. Hume, T. Kirkham, M. Gray, and D. Oscarson. 2002. “A capillarity-advective model for gas break-through in clays.” Eng. Geol. 64 (2): 273–286. https://doi.org/10.1016/S0013-7952(01)00106-5.
Harrington, J. F., and S. T. Horseman. 1999. “Gas transport properties of clays and mudrocks.” Geol. Soc., London, Spec. Publ. 158 (1): 107–124. https://doi.org/10.1144/GSL.SP.1999.158.01.09.
Hildenbrand, A., S. Schlömer, and B. Krooss. 2002. “Gas breakthrough experiments on fine-grained sedimentary rocks.” Geofluids 2 (1): 3–23. https://doi.org/10.1046/j.1468-8123.2002.00031.x.
Hills, G. J., and H. Høiland. 1984. “Pressure dependence of the surface tension of mercury.” J. Colloid Interface Sci. 99 (2): 463–467. https://doi.org/10.1016/0021-9797(84)90134-6.
Horseman, S. T., J. F. Harrington, P. Sellin, R. Pusch, R. N. Yong, and P. Grindrod. 1999. “Gas migration in clay barriers.” Eng. Geol. 54 (1–2): 139–149. https://doi.org/10.1016/S0013-7952(99)00069-1.
Ito, D., K. Akaku, T. Okabe, T. Takahashi, and T. Tsuji. 2011. “Measurement of threshold capillary pressure for seal rocks using the step-by-step approach and the residual pressure approach.” Energy Procedia 4: 5211–5218. https://doi.org/10.1016/j.egypro.2011.02.499.
Kawaura, K., K. Akaku, M. Nakano, D. Ito, T. Takahashi, and S. Kiriakehata. 2013. “Examination of methods to measure capillary threshold pressures of pelitic rock samples.” Energy Procedia 37: 5411–5418. https://doi.org/10.1016/j.egypro.2013.06.459.
Liu, J., F. Agostini, and F. Skoczylas. 2013. “From relative gas permeability to in situ saturation measurements.” Constr. Build. Mater. 40 (Mar): 882–890. https://doi.org/10.1016/j.conbuildmat.2012.11.092.
Liu, J. F., C. A. Davy, J. Talandier, and F. Skoczylas. 2014. “Effect of gas pressure on the sealing efficiency of compacted bentonite-sand plugs.” J. Contam. Hydrol. 170 (Dec): 10–27. https://doi.org/10.1016/j.jconhyd.2014.09.006.
Marschall, P., S. Horseman, and T. Gimmi. 2005. “Characterisation of gas transport properties of the opalinus clay, a potential host rock formation for radioactive waste disposal.” Oil Gas Sci. Technol. 60 (1): 121–139. https://doi.org/10.2516/ogst:2005008.
Monicard, R. 1981. Caractéristiques des roches reservoir: Analyse des carottes, 168. Paris: ÉditionsTechnip.
Ortiz, L., G. Volckaert, and D. Mallants. 2002. “Gas generation and migration in boom clay, a potential host rock formation for nuclear waste storage.” Eng. Geol. 64 (2): 287–296. https://doi.org/10.1016/S0013-7952(01)00107-7.
Peaceman, D. W. 1978. Interpretation of well-block pressure in numerical simulation. Dallas: Society of Petroleum Engineers.
Purcell, W. R. 1949. “Capillary pressures-their measurement using mercury and the calculation of permeability therefrom.” J. Pet. Technol. 1 (02): 39–48. https://doi.org/10.2118/949039-G.
Rezaeyan, A., S. A. Tabatabaei-Nejad, E. Khodapanah, and M. Kamari. 2015. “Parametric analysis of caprock integrity in relation with CO2 geosequestration: Capillary breakthrough pressure of caprock and gas effective permeability.” Greenhouse Gases Sci. Technol. 5 (6): 714–731. https://doi.org/10.1002/ghg.1516.
Romero, E., A. Gens, and A. Lloret. 1999. “Water permeability, water retention and microstructure of unsaturated compacted boom clay.” Eng. Geol. 54 (1–2): 117–127. https://doi.org/10.1016/S0013-7952(99)00067-8.
Schowalter, T. T. 1979. “Mechanics of secondary hydrocarbon migration and entrapment.” AAPG Bull. 63 (5): 723–760. https://doi.org/10.1306/2f9182ca-16ce-11d7-8645000102c1865d.
Sedighi, M., H. R. Thomas, S. Al Masum, P. J. Vardon, D. Nicholson, and Q. Chen. 2015. “Geochemical modelling of hydrogen gas migration in an unsaturated bentonite buffer.” Geo. Soc., London, Spec. Publ. 415 (1): 189–201. https://doi.org/10.1144/SP415.12.
Senger, R., P. Marschall, and S. Finsterle. 2008. “Investigation of two-phase flow phenomena associated with corrosion in an SF/HLW repository in Opalinus Clay, Switzerland.” [Supplement], Phys. Chem. Earth. 33 (S1): S317–S326. https://doi.org/10.1016/j.pce.2008.10.034.
Skurtveit, E., E. Aker, M. Soldal, M. Angeli, and E. Hallberg. 2010. “Influence of microfractures and fluid pressure on sealing efficiency of caprock: A laboratory study on shale.” In Proc., Conf. on Greenhouse Gas Technologies (GHGT) 10. Amsterdam, Netherlands: RAI Amsterdam Convention Centre.
Thomas, L. K., D. L. Katz, and M. R. Tek. 1968. “Threshold pressure phenomena in porous media.” SPE J. 243 (2): 174–184. https://doi.org/10.2118/1816-PA.
Tiedje, E., and P. Guo. 2014. “Thermal conductivity of bentonite grout containing graphite or chopped carbon fibers.” J. Mater. Civ. Eng. 26 (7): 06014013. https://doi.org/10.1061/(ASCE)MT.1943-5533.0000977.
Tonnet, N., G. Mouronval, P. Chiquet, and D. Broseta. 2011. “Petrophysical assessment of a carbonate-rich caprock for CO2 geological storage purposes.” Energy Procedia 4: 5422–5429. https://doi.org/10.1016/j.egypro.2011.02.527.
Tsang, C. F., J. D. Barnichon, J. Birkholzer, X. L. Li, H. H. Liu, and X. Sillen. 2012. “Coupled thermo-hydro-mechanical processes in the near field of a high-level radioactive waste repository in clay formations.” Int. J. Rock Mech. Min. Sci. 49 (Jan): 31–44. https://doi.org/10.1016/j.ijrmms.2011.09.015.
Vassenden, P., Ø. Sylta, and C. Zwach. 2003. “Secondary migration in a 2D visual laboratory model.” In Proc., European Association of Geoscientists and Engineers (EAGE) Conf. ‘Fault and Top Seals: What Do We Know and Where Do We Go?’ Houten, Netherlands: European Association of Geoscientists and Engineers. https://doi.org/10.3997/2214-4609.201405814.
Wen, Z. J. 2006. “Physical property of china′s buffer material for high-level radioactive waste repositories (in Chinese).” Chin. J. Rock Mech. Eng. 25 (4): 794–800. https://doi.org/10.3321/j.issn:1000-6915.2006.04.014.
Wheeler, S. J., R. S. Sharma, and M. S. R. Buisson. 2003. “Coupling of hydraulic hysteresis and stress–strain behavior in unsaturated soils.” Géotechnique 53 (1): 41–54. https://doi.org/10.1680/geot.2003.53.1.41.
Wiegand, G., and E. U. Franck. 1994. “Interfacial tension between water and non-polar fluids up to 473 k and 2800 bar.” Ber. Bunsen Ges. 98 (6): 809–817. https://doi.org/10.1002/bbpc.19940980608.
Ye, W. M., Y. J. Cui, L. X. Qian, and B. Chen. 2009. “An experimental study of the water transfer through confined compacted GMZ bentonite.” Eng. Geol. 108 (3): 169–176. https://doi.org/10.1016/j.enggeo.2009.08.003.
Ye, W. M., L. Xu, B. Ye, B. Chen, Y. G. Chen, and Y. J. Cui. 2017. “Experimental investigation on gas migration in saturated shanghai soft clay.” Eng. Geol. 222 (May): 20–28. https://doi.org/10.1016/j.enggeo.2017.03.024.
Zhang, F., W. M. Ye, Y. G. Chen, B. Chen, and Y. J. Cui. 2016. “Influences of salt solution concentration and vertical stress during saturation on the volume change behavior of compacted GMZ01 bentonite.” Eng. Geol. 207 (Jun): 48–55. https://doi.org/10.1016/j.enggeo.2016.04.010.
Zweigel, P., E. Lindeberg, A. Moen, and D. Wessel-Berg. 2005. “Towards a methodology for top seal efficacy assessment for underground CO2 storage.” In Proc., Int. Conf. on 7th Greenhouse Gas Control Technologies, 1323–1328. Amsterdam, Netherlands: Elsevier Science. https://doi.org/10.1016/B978-008044704-9/50145-2.

Information & Authors

Information

Published In

Go to Journal of Materials in Civil Engineering
Journal of Materials in Civil Engineering
Volume 32Issue 7July 2020

History

Received: May 13, 2019
Accepted: Nov 25, 2019
Published online: May 4, 2020
Published in print: Jul 1, 2020
Discussion open until: Oct 4, 2020

Permissions

Request permissions for this article.

Authors

Affiliations

Lin-yong Cui [email protected]
Ph.D. Student, Dept. of Geotechnical Engineering, College of Civil Engineering, Tongji Univ., Shanghai 200092, China. Email: [email protected]
Professor, Dept. of Geotechnical Engineering, College of Civil Engineering, Tongji Univ., Shanghai 200092, China; Professor, Key Laboratory of Geotechnical and Underground Engineering of Ministry of Education, Tongji Univ., Shanghai 200092, China (corresponding author). Email: [email protected]
Professor, Dept. of Geotechnical Engineering, College of Civil Engineering, Tongji Univ., Shanghai 200092, China. Email: [email protected]
Yong-Gui Chen [email protected]
Professor, Dept. of Geotechnical Engineering, College of Civil Engineering, Tongji Univ., Shanghai 200092, China. Email: [email protected]
Associate Professor, Dept. of Geotechnical Engineering, College of Civil Engineering, Tongji Univ., Shanghai 200092, China. Email: [email protected]
Professor, Dept. of Geotechnical Engineering, College of Civil Engineering, Tongji Univ., Shanghai 200092, China; Professor, Laboratoire Navier, Ecole des Ponts ParisTech, 6 et 8 Ave. Blaise Pascal, Cité Descartes, Champs-sur-Marne 77455 Marne-la-Vallée cedex 2, France. Email: [email protected]

Metrics & Citations

Metrics

Citations

Download citation

If you have the appropriate software installed, you can download article citation data to the citation manager of your choice. Simply select your manager software from the list below and click Download.

Cited by

View Options

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Media

Figures

Other

Tables

Share

Share

Copy the content Link

Share with email

Email a colleague

Share