Abstract

This paper presents investigations on the effects of edge-oxidized graphene oxide (EOGO) on the rheological performance of cement composites. EOGO is produced by a mechanochemical process that can be large production with significantly reduced cost, which enables practical use in infrastructure construction. The work scope is limited to the use of EOGO as an additive in cement paste and cement mortar. This study explored two mix design methods, a dry-mix design and wet-mix design. The dry-mix design method involves the use of EOGO as a dry powder in cement composites, whereas the wet-mix design method means its use as a water-dispersed solution through a sonication process in those cement composites. Varied contents of EOGO ranging from 0.01% through 1.0% were used in both mix design methods. The experimental results show that EOGO-cement composites show higher viscosity than control specimens, which is supported by a microstructure assessment with scanning electron microscopy (SEM) and energy dispersive X-ray spectroscopy (EDS). In addition, it is found that the fluidity of cement composites slightly decreased and apparent viscosity slightly increased with the wet-mix design when compared with the dry-mix design. These results indicate that using the dry-mix design method for EOGO-cement composites is feasible and more practical for field applications.

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Data Availability Statement

Some or all data, models, or code generated or used during the study are available from the corresponding author by request.

Acknowledgments

The authors gratefully acknowledge the Garmor, Inc. for their supply of EOGO to this research. The authors also thank the technical support in petrographic analyses from Mr. Baig Al Muhit.

References

ASTM. 2014a. Standard practice for mechanical mixing of hydraulic cement pastes and mortars of plastic consistency. ASTM C305. West Conshohocken, PA: ASTM.
ASTM. 2014b. Standard specification for flow table for use in tests of hydraulic cement. ASTM C230. West Conshohocken, PA: ASTM.
ASTM. 2015. Standard test method for flow of hydraulic cement mortar. ASTM C1437. West Conshohocken, PA: ASTM.
ASTM. 2016. Standard test method for compressive strength of hydraulic cement mortars. ASTM C109. West Conshohocken, PA: ASTM.
ASTM. 2018a. Standard specification for concrete aggregates. ASTM C33. West Conshohocken, PA: ASTM.
ASTM. 2018b. Standard specification for portland cement. ASTM C150. West Conshohocken, PA: ASTM.
Chuah, S., Z. Pan, J. G. Sanjayan, C. M. Wang, and W. H. Duan. 2014. “Nano reinforced cement and concrete composites and new perspective from graphene oxide.” Constr. Build. Mater. 73 (Dec): 113–124. https://doi.org/10.1016/j.conbuildmat.2014.09.040.
Cwirzen, A., K. Habermehl-Cwirzen, and V. Penttala. 2008. “Surface decoration of carbon nanotubes and mechanical properties of cement/carbon nanotube composites.” Adv. Cem. Res. 20 (2): 65–73. https://doi.org/10.1680/adcr.2008.20.2.65.
Dreyer, D. R., S. Park, C. W. Bielawski, and R. S. Ruoff. 2010. “The chemistry of graphene oxide.” Chem. Soc. Rev. 39 (1): 228–240. https://doi.org/10.1039/B917103G.
e Silva, R. A., P. de Castro Guetti, M. S. da Luz, F. Rouxinol, and R. V. Gelamo. 2017. “Enhanced properties of cement mortars with multilayer graphene nanoparticles.” Constr. Build. Mater. 149 (Sep): 378–385. https://doi.org/10.1016/j.conbuildmat.2017.05.146.
Ferraris, C. F., K. H. Obla, and R. Hill. 2001. “The influence of mineral admixtures on the rheology of cement paste and concrete.” Cem. Concr. Res. 31 (2): 245–255. https://doi.org/10.1016/S0008-8846(00)00454-3.
Gagg, C. R. 2014. “Cement and concrete as an engineering material: An historic appraisal and case study analysis.” Eng. Fail. Anal. 40 (May): 114–140. https://doi.org/10.1016/j.engfailanal.2014.02.004.
Gao, Y., X. Ren, X. Tan, T. Hayat, A. Alsaedi, and C. Chen. 2017. “Insights into key factors controlling GO stability in natural surface waters.” J. Hazard. Mater. 335 (Aug): 56–65. https://doi.org/10.1016/j.jhazmat.2017.04.027.
Garmor. 2015. “Garmor edge functionalized graphene features.” Accessed March 03, 2019. http://www.garmortech.com/technology.htm.
Gong, K., Z. Pan, A. H. Korayem, L. Qiu, D. Li, F. Collins, C. M. Wang, and W. H. Duan. 2014. “Reinforcing effects of graphene oxide on portland cement paste.” J. Mater. Civ. Eng. 27 (2): A4014010. https://doi.org/10.1061/(ASCE)MT.1943-5533.0001125.
Gong, K., T. Tan, M. Dowman, L. Qiu, D. Li, F. G. Collins, and W. Duan. 2012. “Rheological behaviours of graphene oxide reinforced cement composite.” In Proc., Int. Composites Conf., 95–99. Clayton, Australia: Monash University Publishing.
Horszczaruk, E., E. Mijowska, R. J. Kalenczuk, M. Aleksandrzak, and S. Mijowska. 2015. “Nanocomposite of cement/graphene oxide–Impact on hydration kinetics and Young’s modulus.” Constr. Build. Mater. 78 (Mar): 234–242. https://doi.org/10.1016/j.conbuildmat.2014.12.009.
Hummers, W. S., Jr, and R. E. Offeman. 1958. “Preparation of graphitic oxide.” J. Am. Chem. Soc. 80 (6): 1339. https://doi.org/10.1021/ja01539a017.
Konsta-Gdoutos, M. S., Z. S. Metaxa, and S. P. Shah. 2010. “Highly dispersed carbon nanotube reinforced cement based materials.” Cem. Concr. Res. 40 (7): 1052–1059. https://doi.org/10.1016/j.cemconres.2010.02.015.
Li, G. Y., P. M. Wang, and X. Zhao. 2007. “Pressure-sensitive properties and microstructure of carbon nanotube reinforced cement composites.” Cem. Concr. Compos. 29 (5): 377–382. https://doi.org/10.1016/j.cemconcomp.2006.12.011.
Li, H., H.-G. Xiao, J. Yuan, and J. Ou. 2004. “Microstructure of cement mortar with nano-particles.” Composites Part B 35 (2): 185–189. https://doi.org/10.1016/S1359-8368(03)00052-0.
Li, X., A. H. Korayem, C. Li, Y. Liu, H. He, J. G. Sanjayan, and W. H. Duan. 2016. “Incorporation of graphene oxide and silica fume into cement paste: A study of dispersion and compressive strength.” Constr. Build. Mater. 123 (Oct): 327–335. https://doi.org/10.1016/j.conbuildmat.2016.07.022.
Li, X., Y. M. Liu, W. G. Li, C. Y. Li, J. G. Sanjayan, W. H. Duan, and Z. Li. 2017. “Effects of graphene oxide agglomerates on workability, hydration, microstructure and compressive strength of cement paste.” Constr. Build. Mater. 145 (Aug): 402–410. https://doi.org/10.1016/j.conbuildmat.2017.04.058.
Long, W.-J., J.-J. Wei, H. Ma, and F. Xing. 2017. “Dynamic mechanical properties and microstructure of graphene oxide nanosheets reinforced cement composites.” Nanomaterials 7 (12): 407. https://doi.org/10.3390/nano7120407.
Lu, Z., A. Hanif, C. Ning, H. Shao, R. Yin, and Z. Li. 2017. “Steric stabilization of graphene oxide in alkaline cementitious solutions: Mechanical enhancement of cement composite.” Mater. Des. 127 (Aug): 154–161. https://doi.org/10.1016/j.matdes.2017.04.083.
Lv, S., J. Liu, T. Sun, Y. Ma, and Q. Zhou. 2014a. “Effect of GO nanosheets on shapes of cement hydration crystals and their formation process.” Constr. Build. Mater. 64 (Aug): 231–239. https://doi.org/10.1016/j.conbuildmat.2014.04.061.
Lv, S., Y. Ma, C. Qiu, T. Sun, J. Liu, and Q. Zhou. 2013. “Effect of graphene oxide nanosheets of microstructure and mechanical properties of cement composites.” Constr. Build. Mater. 49 (Dec): 121–127. https://doi.org/10.1016/j.conbuildmat.2013.08.022.
Lv, S., S. Ting, J. Liu, and Q. Zhou. 2014b. “Use of graphene oxide nanosheets to regulate the microstructure of hardened cement paste to increase its strength and toughness.” CrystEngComm 16 (36): 8508–8516. https://doi.org/10.1039/C4CE00684D.
Mohammed, A., J. G. Sanjayan, W. Duan, and A. Nazari. 2015. “Incorporating graphene oxide in cement composites: A study of transport properties.” Constr. Build. Mater. 84 (Jun): 341–347. https://doi.org/10.1016/j.conbuildmat.2015.01.083.
Musso, S., J.-M. Tulliani, G. Ferro, and A. Tagliaferro. 2009. “Influence of carbon nanotubes structure on the mechanical behavior of cement composites.” Compos. Sci. Technol. 69 (11–12): 1985–1990. https://doi.org/10.1016/j.compscitech.2009.05.002.
Pan, Z., L. He, L. Qiu, A. H. Korayem, G. Li, J. W. Zhu, F. Collins, D. Li, W. H. Duan, and M. C. Wang. 2015. “Mechanical properties and microstructure of a graphene oxide–cement composite.” Cem. Concr. Compos. 58 (Apr): 140–147. https://doi.org/10.1016/j.cemconcomp.2015.02.001.
Parveen, S., S. Rana, R. Fangueiro, and M. C. Paiva. 2015. “Microstructure and mechanical properties of carbon nanotube reinforced cementitious composites developed using a novel dispersion technique.” Cem. Concr. Res. 73 (Jul): 215–227. https://doi.org/10.1016/j.cemconres.2015.03.006.
Raki, L., J. Beaudoin, R. Alizadeh, J. Makar, and T. Sato. 2010. “Cement and concrete nanoscience and nanotechnology.” Materials 3 (2): 918–942. https://doi.org/10.3390/ma3020918.
Russ, J. C. 2016. The image processing handbook. Boca Raton, FL: CRC Press.
Shang, Y., D. Zhang, C. Yang, Y. Liu, and Y. Liu. 2015. “Effect of graphene oxide on the rheological properties of cement pastes.” Constr. Build. Mater. 96 (Oct): 20–28. https://doi.org/10.1016/j.conbuildmat.2015.07.181.
Silvestre, J., N. Silvestre, and J. De Brito. 2016. “Review on concrete nanotechnology.” Eur. J. Environ. Civ. Eng. 20 (4): 455–485. https://doi.org/10.1080/19648189.2015.1042070.
Sobolkina, A., V. Mechtcherine, V. Khavrus, D. Maier, M. Mende, M. Ritschel, and A. Leonhardt. 2012. “Dispersion of carbon nanotubes and its influence on the mechanical properties of the cement matrix.” Cem. Concr. Compos. 34 (10): 1104–1113. https://doi.org/10.1016/j.cemconcomp.2012.07.008.
Tong, T., Z. Fan, Q. Liu, S. Wang, S. Tan, and Q. Yu. 2016. “Investigation of the effects of graphene and graphene oxide nanoplatelets on the micro-and macro-properties of cementitious materials.” Constr. Build. Mater. 106 (Mar): 102–114. https://doi.org/10.1016/j.conbuildmat.2015.12.092.
Wang, Q., X. Cui, J. Wang, S. Li, C. Lv, and Y. Dong. 2017. “Effect of fly ash on rheological properties of graphene oxide cement paste.” Constr. Build. Mater. 138 (May): 35–44. https://doi.org/10.1016/j.conbuildmat.2017.01.126.
Wang, Q., J. Wang, C.-X. Lu, B.-W. Liu, K. Zhang, and C.-Z. Li. 2015. “Influence of graphene oxide additions on the microstructure and mechanical strength of cement.” New Carbon Mater. 30 (4): 349–356. https://doi.org/10.1016/S1872-5805(15)60194-9.
Wang, Q., J. Wang, C.-X. Lv, X.-Y. Cui, S.-Y. Li, and X. Wang. 2016. “Rheological behavior of fresh cement pastes with a graphene oxide additive.” New Carbon Mater. 31 (6): 574–584. https://doi.org/10.1016/S1872-5805(16)60033-1.
Zhao, L., X. Guo, Y. Liu, C. Ge, Z. Chen, L. Guo, X. Shu, and J. Liu. 2018. “Investigation of dispersion behavior of GO modified by different water reducing agents in cement pore solution.” Carbon 127 (Feb): 255–269. https://doi.org/10.1016/j.carbon.2017.11.016.

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Go to Journal of Materials in Civil Engineering
Journal of Materials in Civil Engineering
Volume 32Issue 6June 2020

History

Received: Dec 10, 2018
Accepted: Oct 25, 2019
Published online: Mar 26, 2020
Published in print: Jun 1, 2020
Discussion open until: Aug 26, 2020

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Yousef Alharbi, Ph.D. [email protected]
Assistant Professor, Dept. of Civil Engineering, King Saud Univ., P.O. Box 800, Riyadh 11421, Saudi Arabia. Email: [email protected]
Postdoctoral Researcher, Dept. of Civil, Environmental and Construction Engineering, Univ. of Central Florida, 4000 Central Florida Blvd., Bldg. 91, Suite 211, Orlando, FL 32816 (corresponding author). ORCID: https://orcid.org/0000-0001-8897-7120. Email: [email protected]
Jinwoo An, Ph.D. [email protected]
Assistant Professor, Dept. of Engineering, Univ. of Mount Union, 1972 Clark Ave., Alliance, OH 44601. Email: [email protected]
Boo Hyun Nam, Ph.D., M.ASCE [email protected]
Associate Professor, Dept. of Civil, Environmental and Construction Engineering, Univ. of Central Florida, 4000 Central Florida Blvd., Bldg. 91, Suite 211, Orlando, FL 32816. Email: [email protected]

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