Longitudinal Deformation of Mortar Bars Containing Reactive MgO during Carbonation Curing and Sulfate Solution Immersion
Publication: Journal of Materials in Civil Engineering
Volume 31, Issue 11
Abstract
Reactive magnesium oxide (r-MgO) as a replacement of portland cement (PC) not only brings potential to reduce the embodied carbon in construction materials, but also brings uncertainties in the volumetric stability of carbonated r-MgO-PC systems during carbonation curing and sulfate exposure. This study investigates the longitudinal length and mass change of mortar bars with r-MgO replacement levels of 0%, 30%, 50%, and 70% when specimens are subjected to atmospheric drying, accelerated carbonation curing, distilled water immersion, and solution immersion. Experimental results revealed that carbonated mortar bars with a 30% r-MgO replacement level achieve a greater expansion after 24 months of sulfate solution immersion compared with mortar bars made with 100% PC. Formation of gypsum and ettringite are expected to be the main reasons for the expansion. The 50% and 70% r-MgO mortars exhibited volumetric and gravimetric stabilities during accelerated carbonation curing and sulfate solution immersion.
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Data Availability Statement
All data, models, and code generated or used during the study are included in the published paper.
Acknowledgments
The authors acknowledge Ms. Olga Perebatova from the University of Toronto for her input and assistance with the experiments. Prof. Liwu Mo from Nanjing University of Technology is acknowledged for providing materials. The authors are grateful for Professor Panesar’s Early Research Award from the Ministry of Economic Development and Innovation and NSERC.
References
ASTM. 2013. Standard specification for standard sand. ASTM C778. West Conshohocken, PA: ASTM.
ASTM. 2014. Standard practice for mechanical mixing of hydraulic cement pastes and mortars of plastic consistency. ASTM C305. West Conshohocken, PA: ASTM.
ASTM. 2015. Standard test method for length change of hydraulic-cement mortars exposed to a sulfate solution. ASTM C1012/C1012M. West Conshohocken, PA: ASTM.
ASTM. 2016. Standard test method for compressive strength of hydraulic cement mortars (using 2-in. or [50-mm] cube specimens). ASTM C109/C109M. West Conshohocken, PA: ASTM.
ASTM. 2017. Standard test method for measurement of heat of hydration of hydraulic cementitious materials using isothermal conduction calorimetry. ASTM C1702. West Conshohocken, PA: ASTM.
Brečević, L., and D. Kralj. 2007. “On calcium carbonates: From fundamental research to application.” Croat. Chem. Acta 80 (3–4): 467–484.
Brown, P., R. Hooton, and B. Clark. 2004. “Microstructural changes in concretes with sulfate exposure.” Cem. Concr. Compos. 26 (8): 993–999. https://doi.org/10.1016/j.cemconcomp.2004.02.033.
Bullard, J. W., H. M. Jennings, R. A. Livingston, A. Nonat, G. W. Scherer, J. S. Schweitzer, K. L. Scrivener, and J. J. Thomas. 2011. “Mechanisms of cement hydration.” Cem. Concr. Res. 41 (12): 1208–1223. https://doi.org/10.1016/j.cemconres.2010.09.011.
Chatterji, S. 1995. “Mechanism of expansion of concrete due to the presence of dead-burnt CaO and MgO.” Cem. Concr. Res. 25 (1): 51–56. https://doi.org/10.1016/0008-8846(94)00111-B.
Choi, S.-W., B.-S. Jang, J.-H. Kim, and K.-M. Lee. 2014. “Durability characteristics of fly ash concrete containing lightly-burnt MgO.” Constr. Build. Mater. 58 (May): 77–84. https://doi.org/10.1016/j.conbuildmat.2014.01.080.
Cwirzen, A., and K. Habermehl-Cwirzen. 2012. “Effects of reactive magnesia on microstructure and frost durability of portland cement–based binders.” J. Mater. Civ. Eng. 25 (12): 1941–1950. https://doi.org/10.1061/(ASCE)MT.1943-5533.0000768.
Ding, Q., J. Yang, D. Hou, and G. Zhang. 2018. “Insight on the mechanism of sulfate attacking on the cement paste with granulated blast furnace slag: An experimental and molecular dynamics study.” Constr. Build. Mater. 169 (Apr): 601–611. https://doi.org/10.1016/j.conbuildmat.2018.02.148.
Du, C. 2005. “A review of magnesium oxide in concrete.” Concr. Int. 27 (12): 45–50.
Fernández-Díaz, L., Á. Fernández-González, and M. Prieto. 2010. “The role of sulfate groups in controlling CaCO3 polymorphism.” Geochim. Cosmochim. Acta 74 (21): 6064–6076. https://doi.org/10.1016/j.gca.2010.08.010.
Gaines, A. M. 1977. “Protodolomite redefined.” J. Sediment. Res. 47 (2): 543–546.
Gregg, J. M., D. L. Bish, S. E. Kaczmarek, and H. G. Machel. 2015. “Mineralogy, nucleation and growth of dolomite in the laboratory and sedimentary environment: A review.” Sedimentology 62 (6): 1749–1769. https://doi.org/10.1111/sed.12202.
Hall, C., P. Barnes, A. D. Billimore, A. C. Jupe, and X. Turrillas. 1996. “Thermal decomposition of ettringite Ca6[Al(OH)6]2(SO4)3 26H2O.” J. Chem. Soc. Faraday Trans. 92 (12): 2125–2129. https://doi.org/10.1039/FT9969202125.
Howson, M. R., A. D. Pethybridge, and W. A. House. 1987. “Synthesis and distribution coefficient of low-magnesium calcites.” Chem. Geol. 64 (1–2): 79–87. https://doi.org/10.1016/0009-2541(87)90153-7.
Irassar, E. F., V. L. Bonavetti, and M. González. 2003. “Microstructural study of sulfate attack on ordinary and limestone portland cements at ambient temperature.” Cem. Concr. Res. 33 (1): 31–41. https://doi.org/10.1016/S0008-8846(02)00914-6.
Kralj, D., J. Kontrec, L. Brečević, G. Falini, and V. Nöthig-Laslo. 2004. “Effect of inorganic anions on the morphology and structure of magnesium calcite.” Chem. Eur. J. 10 (7): 1647–1656. https://doi.org/10.1002/chem.200305313.
Kunther, W., B. Lothenbach, and J. Skibsted. 2015. “Influence of the Ca/Si ratio of the C–S–H phase on the interaction with sulfate ions and its impact on the ettringite crystallization pressure.” Cem. Concr. Res. 69 (Mar): 37–49. https://doi.org/10.1016/j.cemconres.2014.12.002.
Liu, K., D. Sun, A. Wang, G. Zhang, and J. Tang. 2018. “Long-term performance of blended cement paste containing fly ash against sodium sulfate attack.” J. Mater. Civ. Eng. 30 (12): 04018309. https://doi.org/10.1061/(ASCE)MT.1943-5533.0002516.
Liu, Z., X. Cui, and M. Tang. 1991. “MgO-type delayed expansive cement.” Cem. Concr. Res. 21 (6): 1049–1057. https://doi.org/10.1016/0008-8846(91)90065-P.
Mo, L., M. Deng, and M. Tang. 2010. “Effects of calcination condition on expansion property of MgO-type expansive agent used in cement-based materials.” Cem. Concr. Res. 40 (3): 437–446. https://doi.org/10.1016/j.cemconres.2009.09.025.
Mo, L., M. Deng, M. Tang, and A. Al-Tabbaa. 2014. “MgO expansive cement and concrete in China: Past, present and future.” Cem. Concr. Res. 57 (Mar): 1–12. https://doi.org/10.1016/j.cemconres.2013.12.007.
Mo, L., M. Deng, and A. Wang. 2012. “Effects of MgO-based expansive additive on compensating the shrinkage of cement paste under non-wet curing conditions.” Cem. Concr. Compos. 34 (3): 377–383. https://doi.org/10.1016/j.cemconcomp.2011.11.018.
Mo, L., M. Liu, A. Al-Tabbaa, and M. Deng. 2015a. “Deformation and mechanical properties of the expansive cements produced by inter-grinding cement clinker and MgOs with various reactivities.” Constr. Build. Mater. 80 (Apr): 1–8. https://doi.org/10.1016/j.conbuildmat.2015.01.066.
Mo, L., M. Liu, A. Al-Tabbaa, M. Deng, and W. Y. Lau. 2015b. “Deformation and mechanical properties of quaternary blended cements containing ground granulated blast furnace slag, fly ash and magnesia.” Cem. Concr. Res. 71 (May): 7–13. https://doi.org/10.1016/j.cemconres.2015.01.018.
Mo, L., and D. K. Panesar. 2012. “Effects of accelerated carbonation on the microstructure of portland cement pastes containing reactive MgO.” Cem. Concr. Res. 42 (6): 769–777. https://doi.org/10.1016/j.cemconres.2012.02.017.
Mo, L., and D. K. Panesar. 2013. “Accelerated carbonation: A potential approach to sequester in cement paste containing slag and reactive MgO.” Cem. Concr. Compos. 43 (Oct): 69–77. https://doi.org/10.1016/j.cemconcomp.2013.07.001.
Mo, L., and D. K. Panesar. 2014. “Microstructure of reactive magnesia cement pastes subjected to high carbon dioxide concentration.” J. Chin. Ceram. Soc. 42 (2): 142–149.
Monkman, S., and Y. Shao. 2006. “Assessing the carbonation behavior of cementitious materials.” J. Mater. Civ. Eng. 18 (6): 768–776. https://doi.org/10.1061/(ASCE)0899-1561(2006)18:6(768).
Neville, A. 2004. “The confused world of sulfate attack on concrete.” Cem. Concr. Res. 34 (8): 1275–1296. https://doi.org/10.1016/j.cemconres.2004.04.004.
Panesar, D. K., and Y. Bilan. 2017. “Carbonation curing of concrete containing reactive MgO: A study of the material properties and economic feasibility.” In Proc., 11th High Performance Concrete and 2nd Cement Innovations in Concrete Conf. Tromsø, Norway: Norwegian Concrete Association/Tekna.
Pokrovsky, O. 1998. “Precipitation of calcium and magnesium carbonates from homogeneous supersaturated solutions.” J. Cryst. Growth 186 (1–2): 233–239. https://doi.org/10.1016/S0022-0248(97)00462-4.
Pu, L., and C. Unluer. 2016. “Investigation of carbonation depth and its influence on the performance and microstructure of MgO cement and PC mixes.” Constr. Build. Mater. 120 (Sep): 349–363. https://doi.org/10.1016/j.conbuildmat.2016.05.067.
Qing, Y., C. Huxing, W. Yuqing, W. Shangxian, and L. Zonghan. 2004. “Effect of MgO and gypsum content on long-term expansion of low heat portland slag cement with slight expansion.” Cem. Concr. Compos. 26 (4): 331–337. https://doi.org/10.1016/S0958-9465(02)00145-2.
Ruiz-Agudo, E. N., K. Kudłacz, C. V. Putnis, A. Putnis, and C. Rodriguez-Navarro. 2013. “Dissolution and carbonation of portlandite [Ca(OH)2] single crystals.” Environ. Sci. Technol. 47 (19): 11342–11349. https://doi.org/10.1021/es402061c.
Santhanam, M., M. D. Cohen, and J. Olek. 2001. “Sulfate attack research—Whither now?” Cem. Concr. Res. 31 (6): 845–851. https://doi.org/10.1016/S0008-8846(01)00510-5.
Santhanam, M., M. D. Cohen, and J. Olek. 2003. “Effects of gypsum formation on the performance of cement mortars during external sulfate attack.” Cem. Concr. Res. 33 (3): 325–332. https://doi.org/10.1016/S0008-8846(02)00955-9.
Shand, M. A. 2006. The chemistry and technology of magnesia. New York: Wiley.
Sherir, M. A., K. M. Hossain, and M. Lachemi. 2018. “Permeation and transport properties of self-healed cementitious composite produced with MgO expansive agent.” J. Mater. Civ. Eng. 30 (11): 04018291. https://doi.org/10.1061/(ASCE)MT.1943-5533.0002466.
Vandeperre, L. J., and A. Al-Tabbaa. 2007. “Accelerated carbonation of reactive MgO cements.” Adv. Cem. Res. 19 (2): 67–79. https://doi.org/10.1680/adcr.2007.19.2.67.
Wada, N., K. Yamashita, and T. Umegaki. 1995. “Effects of divalent cations upon nucleation, growth and transformation of calcium carbonate polymorphs under conditions of double diffusion.” J. Cryst. Growth 148 (3): 297–304. https://doi.org/10.1016/0022-0248(94)00880-9.
Ye, Q., K. Yu, and Z. Zhang. 2015. “Expansion of ordinary portland cement paste varied with nano-MgO.” Constr. Build. Mater. 78 (Mar): 189–193. https://doi.org/10.1016/j.conbuildmat.2014.12.113.
Zhang, R., N. Bassim, and D. K. Panesar. 2018. “Characterization of Mg components in the reactive MgO and portland cement system during hydration and carbonation.” J. CO2 Util. 27: 518–527. https://doi.org/10.1016/j.jcou.2018.08.025.
Zhang, R., and D. K. Panesar. 2017a. “Investigation on Mg content in calcite when magnesium calcite and nesquehonite co-precipitate in hardened paste.” Thermochim. Acta 654 (Aug): 203–215. https://doi.org/10.1016/j.tca.2017.04.005.
Zhang, R., and D. K. Panesar. 2017b. “New approach to calculate water film thickness and its correlation to the rheology of mortar and concrete containing reactive MgO.” Constr. Build. Mater. 150 (Sep): 892–902. https://doi.org/10.1016/j.conbuildmat.2017.05.218.
Zhang, R., and D. K. Panesar. 2018a. “Mechanical properties and rapid chloride permeability of carbonated concrete containing reactive MgO.” Constr. Build. Mater. 172 (May): 77–85. https://doi.org/10.1016/j.conbuildmat.2018.03.223.
Zhang, R., and D. K. Panesar. 2018b. “Water absorption of carbonated reactive MgO concrete and its correlation with the pore structure.” J. CO2 Util. 24 (Mar): 350–360. https://doi.org/10.1016/j.jcou.2018.01.026.
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©2019 American Society of Civil Engineers.
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Received: Nov 21, 2018
Accepted: Jun 4, 2019
Published online: Aug 29, 2019
Published in print: Nov 1, 2019
Discussion open until: Jan 29, 2020
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