Effect of Fly Ash on Rheological Properties of Magnesium Oxychloride Cement
Publication: Journal of Materials in Civil Engineering
Volume 31, Issue 3
Abstract
This paper studies the effect of fly ash on rheological properties of magnesium oxychloride cement (MOC) paste. Six different dosages of fly ash (0%, 15%, 20%, 25%, 30%, and 35% by weight of MgO) samples are prepared to investigate the rheological properties of fly ash–magnesium oxychloride cement (FA-MOC) paste. The effects of fly ash on fluidity, setting times and mechanical properties of MOC paste are measured. Phases and microstructures of FA-MOC paste are analyzed by X-ray diffraction (XRD) and scanning electronic microscopy (SEM). An optical microscope is used to evaluate the flocculation of fresh FA-MOC paste. The results reveal that fly ash can improve fluidity and retard the setting time of MOC paste. The water-absorbing ability and the morphology effect of fly ash have combined effects on the rheological properties of FA-MOC paste. At the same time, the results show that fly ash used in MOC paste does not change the phases composition of hardened paste, but increases the amount of (Phase 5). However, fly ash weakens the structure of hydration products and results in poor mechanical properties of MOC paste.
Get full access to this article
View all available purchase options and get full access to this article.
Acknowledgments
The authors acknowledge the support from the Fundamental Research Funds for the National Key R&D Program of China (2017YFB0309903), the Qinghai Provincial Natural Science Foundation (2017-ZJ-764 and 2017-ZJ-763), and the Special Fund for Scientific Research of Central Colleges, Chang’an University (Nos. 310831172201 and 300102318501).
References
AQSIQ (General Administration of Quality Supervision, Inspection and Quarantine of PRC). 1999. Method of testing cements—Determination of strength. GB/T17671-1999. Beijing: AQSIQ.
AQSIQ (General Administration of Quality Supervision, Inspection and Quarantine of PRC). 2000. Methods for testing uniformity of concrete admixture. GB/T8077-2000. Beijing: AQSIQ.
AQSIQ (General Administration of Quality Supervision, Inspection and Quarantine of PRC). 2011. Standard for test method of performance on ordinary fresh concrete. GB/T50080-2011. Beijing: AQSIQ.
Beaudoin, J. J., and V. S. Ramachandran. 1975. “Strength development in magnesium oxychloride and other cements.” Cem. Concr. Res. 5 (6): 617–630. https://doi.org/10.1016/0008-8846(75)90062-9.
Chau, C. K., J. Chan, and Z. Li. 2009. “Influences of fly ash on magnesium oxychloride mortar.” Cem. Concr. Compos. 31 (4): 250–254. https://doi.org/10.1016/j.cemconcomp.2009.02.011.
Demediuk, T., W. F. Cole, and H. V. Hueber. 1955. “Studies on magnesium and calcium oxychlorides.” Aust. J. Chem. 8 (2): 215–233. https://doi.org/10.1071/CH9550215.
Ferron, R. P., A. Gregori, Z. Sun, and S. P. Shah. 2007. “Rheological method to evaluate structural buildup in self-consolidating concrete cement pastes.” ACI Mater. J. 104 (3): 242–250.
Feys, D., J. E. Wallevik, A. Yahia, K. H. Khayat, and O. H. Wallevik. 2013. “Extension of the Reiner–Riwlin equation to determine modified Bingham parameters measured in coaxial cylinders rheometers.” Mater. Struct. 46 (1–2): 289–311. https://doi.org/10.1617/s11527-012-9902-6.
Genovese, D. B. 2012. “Shear rheology of hard-sphere, dispersed, and aggregated suspensions, and filler-matrix composites.” Adv. Colloid Interface Sci. 171–172 (1): 1–16. https://doi.org/10.1016/j.cis.2011.12.005.
Gurney, L. R., D. P. Bentz, T. Sato, and W. J. Weiss. 2018. “Reducing set retardation in high-volume fly ash mixtures with the use of limestone.” Transp. Res. Rec. 2290 (1): 139–146. https://doi.org/10.3141/2290-18.
Hemalatha, T., and A. Ramaswamy. 2017. “A review on fly ash characteristics: Towards promoting high volume utilization in developing sustainable concrete.” Supplement, J. Cleaner Prod. 147 (SC): 546–559. https://doi.org/10.1016/j.jclepro.2017.01.114.
Hou, P., S. Kawashima, K. J. Wang, D. J. Corr, J. S. Qian, and S. P. Shah. 2013. “Effects of colloidal nanosilica on rheological and mechanical properties of fly ash: Cement mortar.” Cem. Concr. Compos. 35 (1): 12–22. https://doi.org/10.1016/j.cemconcomp.2012.08.027.
Hu, C., B. Xu, H. Ma, B. Chen, and Z. Li. 2016. “Micromechanical investigation of magnesium oxychloride cement paste.” Supplement, Constr. Build. Mater. 105 (SC): 496–502. https://doi.org/10.1016/j.conbuildmat.2015.12.182.
Jiang, S., B. Shan, J. Ouyang, W. Zhang, X. Yu, P. Li, and B. Han. 2018. “Rheological properties of cementitious composites with nano/fiber fillers.” Supplement, Constr. Build. Mater. 158 (SC): 786–800. https://doi.org/10.1016/j.conbuildmat.2017.10.072.
Jiao, D., C. Shi, Q. Yuan, X. An, Y. Liu, and H. Li. 2017. “Effect of constituents on rheological properties of fresh concrete—A review.” Supplement, Cem. Concr. Compos. 83 (SC): 146–159. https://doi.org/10.1016/j.cemconcomp.2017.07.016.
Li, Z., and C. K. Chau. 2007. “Influence of molar ratios on properties of magnesium oxychloride cement.” Cem. Concr. Res. 37 (6): 866–870. https://doi.org/10.1016/j.cemconres.2007.03.015.
Liu, Z., S. Wang, J. Huang, Z. Wei, B. Guan, and J. Fang. 2015. “Experimental investigation on the properties and microstructure of magnesium oxychloride cement prepared with caustic magnesite and dolomite.” Constr. Build. Mater. 85 (15): 247–255. https://doi.org/10.1016/j.conbuildmat.2015.01.056.
Lu, Z., X. Kong, C. Zhang, F. Xing, and Y. Zhang. 2017. “Effect of colloidal polymers with different surface properties on the rheological property of fresh cement pastes.” Supplement, Colloids Surf., A 520 (SC): 154–165. https://doi.org/10.1016/j.colsurfa.2017.01.067.
Naik, T. R., and S. S. Singh. 1997. “Influence of fly ash on setting and hardening characteristics of concrete systems.” ACI Mater. J. 94 (5): 355–360.
Qian, Y., and S. Kawashima. 2018. “Distinguishing dynamic and static yield stress of fresh cement mortars through thixotropy.” Cem. Concr. Compos. 86: 288–296. https://doi.org/10.1016/j.cemconcomp.2017.11.019.
Sabet, F. A., N. A. Libre, and M. Shekarchi. 2013. “Mechanical and durability properties of self consolidating high performance concrete incorporating natural zeolite, silica fume and fly ash.” Supplement, Constr. Build. Mater. 44 (SC): 175–184. https://doi.org/10.1016/j.conbuildmat.2013.02.069.
Shang, Y., D. Zhang, C. Yang, Y. Liu, and Y. Liu. 2015. “Effect of graphene oxide on the rheological properties of cement pastes.” Constr. Build. Mater. 96: 20–28. https://doi.org/10.1016/j.conbuildmat.2015.07.181.
Tan, Y., Y. Liu, and L. Grover. 2014. “Effect of phosphoric acid on the properties of magnesium oxychloride cement as a biomaterial.” Cem. Concr. Res. 56: 69–74. https://doi.org/10.1016/j.cemconres.2013.11.001.
Tan, Y., Y. Liu, Z. Zhao, J. Z. Paxton, and L. M. Grover. 2015. “Synthesis and in vitro degradation of a novel magnesium oxychloride cement.” J. Biomed. Mater. Res. Part A 103 (1): 194–202. https://doi.org/10.1002/jbm.a.35166.
Vance, K., A. Arora, G. Sant, and N. Neithalath. 2015. “Rheological evaluations of interground and blended cement–limestone suspensions.” Constr. Build. Mater. 79: 65–72. https://doi.org/10.1016/j.conbuildmat.2014.12.054.
Wallevik, J. E. 2005. “Thixotropic investigation on cement paste: Experimental and numerical approach.” J. Non-Newtonian Fluid Mech. 132 (1): 86–99. https://doi.org/10.1016/j.jnnfm.2005.10.007.
Wallevik, O. H., D. Feys, J. E. Wallevik, and K. H. Khayat. 2015. “Avoiding inaccurate interpretations of rheological measurements for cement-based materials.” Cem. Concr. Res. 78: 100–109.
Wang, Q., X. Cui, J. Wang, S. Li, C. Lv, and Y. Dong. 2017. “Effect of fly ash on rheological properties of graphene oxide cement paste.” Constr. Build. Mater. 138: 35–44. https://doi.org/10.1016/j.conbuildmat.2017.01.126.
Wu, C., W. Chen, H. Zhang, H. Yu, W. Zhang, N. Jiang, and L. Liu. 2017. “The hydration mechanism and performance of modified magnesium oxysulfate cement by tartaric acid.” Constr. Build. Mater. 144: 516–524. https://doi.org/10.1016/j.conbuildmat.2017.03.222.
Xu, B., H. Ma, H. Shao, Z. Li, and B. Lothenbach. 2017. “Influence of fly ash on compressive strength and micro-characteristics of magnesium potassium phosphate cement mortars.” Cem. Concr. Res. 99: 86–94. https://doi.org/10.1016/j.cemconres.2017.05.008.
Yu, J., C. Lu, C. K. Leung, and G. Li. 2017. “Mechanical properties of green structural concrete with ultrahigh-volume fly ash.” Supplement, Constr. Build. Mater. 147 (SC): 510–518. https://doi.org/10.1016/j.conbuildmat.2017.04.188.
Zhang, X., S. Ge, H. Wang, and R. Chen. 2017. “Effect of 5-phase seed crystal on the mechanical properties and microstructure of magnesium oxychloride cement.” Supplement, Constr. Build. Mater. 150 (SC): 409–417. https://doi.org/10.1016/j.conbuildmat.2017.05.211.
Zheng, D., D. M. Wang, C. F. Ren, and W. C. Tang. 2017. “Study of high volume circulating fluidized bed fly ash on rheological properties of the resulting cement paste.” Supplement, Constr. Build. Mater. 135 (SC): 86–93. https://doi.org/10.1016/j.conbuildmat.2016.12.127.
Zhou, Z., H. Chen, Z. Li, and H. Li. 2015. “Simulation of the properties of system by thermodynamic method.” Cem. Concr. Res. 68: 105–111. https://doi.org/10.1016/j.cemconres.2014.11.006.
Information & Authors
Information
Published In
Copyright
©2018 American Society of Civil Engineers.
History
Received: Mar 30, 2018
Accepted: Aug 7, 2018
Published online: Dec 31, 2018
Published in print: Mar 1, 2019
Discussion open until: May 31, 2019
Authors
Metrics & Citations
Metrics
Citations
Download citation
If you have the appropriate software installed, you can download article citation data to the citation manager of your choice. Simply select your manager software from the list below and click Download.