Technical Papers
May 26, 2018

Ability of Nanomaterials to Effectively Disperse in Asphalt Binders for Use as a Modifier

Publication: Journal of Materials in Civil Engineering
Volume 30, Issue 8

Abstract

Several studies have investigated the use of nanomaterials to modify asphalt binders and achieve improved properties. It is possible that in some cases nanomaterials do not disperse and agglomerate within the asphalt binder. In such cases, the benefits from the addition of these nanoscale modifiers are limited and are likely driven by mechanisms that can potentially be achieved using larger filler-sized materials. This study investigates the dispersion characteristics of a selected set of nanomaterials in surrogate solvents that represent a physicochemical environment similar to that of asphalt binders. The study also investigates the influence of these nanomaterials on the performance characteristics of asphalt binders. Results show that among the nanomaterials evaluated, those that tend to disperse relatively better in the surrogate environment, i.e., retain their nanoscale identity better relative to others, also tend to show a relatively better performance in terms of rheological properties. This is especially true at low temperatures.

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Acknowledgments

The authors would also like to acknowledge the Texas Department of Transportation for funding this study. The authors would like to acknowledge Dr. Enad Mahmoud for his help with providing nano-glass for this study.

References

Al-Adham, K., and M. Arifuzzaman. 2014. “Moisture damage evaluation in carbon nanotubes reinforced asphalts.” In Sustainability, Eco-efficiency, and Conservation in Transportation Infrastructure Asset Management, 103. Boca Raton, FL: CRC Press.
ASTM. 2015. Standard test method for multiple stress creep and recovery (MSCR) of asphalt binder using a dynamic shear rheometer. ASTM D7405. West Conshohocken, PA: ASTM.
ASTM. 2016a. Standard specification for performance graded asphalt binder. ASTM D6373. West Conshohocken, PA: ASTM.
ASTM. 2016b. Standard test method for determining the flexural creep stiffness of asphalt binder using the bending beam rheometer (BBR). ASTM D6648. West Conshohocken, PA: ASTM.
Boles, M. A., D. Ling, T. Hyeon, and D. V. Talapin. 2016. “The surface science of nanocrystals.” Nat. Mater. 15 (2): 141–153. https://doi.org/10.1038/nmat4526.
Cheng, J., J. Shen, and F. Xiao. 2011. “Moisture susceptibility of warm-mix asphalt mixtures containing nanosized hydrated lime.” J. Mater. Civ. Eng. 23 (11): 1552–1559. https://doi.org/10.1061/(ASCE)MT.1943-5533.0000308.
Diab, A., Z. You, and H. Wang. 2013. “Rheological evaluation of foamed WMA modified with nano hydrated lime.” Procedia-Social Behav. Sci. 96 (Nov): 2858–2866. https://doi.org/10.1016/j.sbspro.2013.08.318.
Filonzi, A., I. V. Sabaraya, R. Hajj, D. Das, N. B. Saleh, A. Bhasin, and E. Mahmoud. 2017. Evaluating the use of nanomaterials to enhance properties of asphalt binders and mixtures. Austin, TX: TX Department of Transportation.
Hansen, C. M. 1967. “The three dimensional solubility parameter-key to paint component affinities. I: Solvents, plasticizers, polymers, and resins.” J. Paint Technol. 39 (505): 104–117.
Hansen, C. M. 2007. Hansen solubility parameters: A user’s handbook. Boca Raton, FL: CRC Press.
Hansen, C. M., and A. Beerbower. 1971. “Solubility parameters.” In Vol. 2 of Kirk-Othmer Encyclopedia of Chemical Technology, 889–910. New York, NY: Wiley.
Huang, Y. Y., and E. M. Terentjev. 2012. “Dispersion of carbon nanotubes: Mixing, sonication, stabilization, and composite properties.” Polymers 4 (1): 275–295. https://doi.org/10.3390/polym4010275.
Jahromi, S. G., and A. Khodaii. 2009. “Effects of nanoclay on rheological properties of bitumen binder.” Constr. Build. Mater. 23 (8): 2894–2904. https://doi.org/10.1016/j.conbuildmat.2009.02.027.
Khattak, M. J., A. Khattab, H. R. Rizvi, and P. Zhang. 2012. “The impact of carbon nano-fiber modification on asphalt binder rheology.” Constr. Build. Mater. 30 (1): 257–264. https://doi.org/10.1016/j.conbuildmat.2011.12.022.
Klaine, S. J., P. J. Alvarez, G. E. Batley, T. F. Fernandes, R. D. Handy, D. Y. Lyon, S. Mahendra, M. J. McLaughlin, and J. R. Lead. 2008. “Nanomaterials in the environment: Behavior, fate, bioavailability, and effects.” Environ. Toxicol. Chem. 27 (9): 1825–1851. https://doi.org/10.1897/08-090.1.
Luo, J. L., Z. D. Duan, T. J. Zhao, and Q. Y. Li. 2011. “Effect of multi-wall carbon nanotube on fracture mechanical property of cement-based composite.” Adv. Mater. Res. 146–147: 581–584. https://doi.org/10.4028/www.scientific.net/AMR.146-147.581.
Min, Y., M. Akbulut, K. Kristiansen, Y. Golan, and J. Israelachvili. 2008. “The role of interparticle and external forces in nanoparticle assembly.” Nat. Mater. 7 (7): 527–538. https://doi.org/10.1038/nmat2206.
Petosa, A. R., D. P. Jaisi, I. R. Quevedo, M. Elimelech, and N. Tufenkji. 2010. “Aggregation and deposition of engineered nanomaterials in aquatic environments: Role of physicochemical interactions.” Environ. Sci. Technol. 44 (17): 6532–6549. https://doi.org/10.1021/es100598h.
Quercia, G., P. Spiesz, G. Husken, and J. Brouwers. 2012. “Effects of amorphous nano-silica additions on mechanical and durability performance of SCC mixtures.” In Proc., Int. Congress on Durability of Concrete. Trondheim, Norway.
Redelius, P. 2000. “Solubility parameters and bitumen.” Fuel 79 (1): 27–35. https://doi.org/10.1016/S0016-2361(99)00103-9.
Redelius, P. 2004. “Bitumen solubility model using Hansen solubility parameter.” Energy Fuels 18 (4): 1087–1092. https://doi.org/10.1021/ef0400058.
Redelius, P., and H. Soenen. 2015. “Relation between bitumen chemistry and performance.” Fuel 140 (Jan): 34–43. https://doi.org/10.1016/j.fuel.2014.09.044.
Sato, T., S. Araki, M. Morimoto, R. Tanaka, and H. Yamamoto. 2014. “Comparison of Hansen solubility parameter of asphaltenes extracted from bitumen produced in different geographical regions.” Energy Fuels 28 (2): 891–897. https://doi.org/10.1021/ef402065j.
Sobolev, K., and M. F. Gutiérrez. 2005. “How nanotechnology can change the concrete world.” Am. Ceram. Soc. Bull. 84 (10): 14.
Xiao, F., A. N. Amirkhanian, and S. N. Amirkhanian. 2011. “Influence of carbon nanoparticles on the rheological characteristics of short-term aged asphalt binders.” J. Mater. Civ. Eng. 23 (4): 423–431. https://doi.org/10.1061/(ASCE)MT.1943-5533.0000184.
Yao, H., Z. You, L. Li, S. W. Goh, C. H. Lee, Y. K. Yap, and X. Shi. 2013. “Rheological properties and chemical analysis of nanoclay and carbon microfiber modified asphalt with Fourier transform infrared spectroscopy.” Constr. Build. Mater. 38 (Jan): 327–337. https://doi.org/10.1016/j.conbuildmat.2012.08.004.
Yao, H., Z. You, L. Li, C. H. Lee, D. Wingard, Y. K. Yap, X. Shi, and S. W. Goh. 2013. “Rheological properties and chemical bonding of asphalt modified with nanosilica.” J. Mater. Civ. Eng. 25 (11): 1619–1630. https://doi.org/10.1061/(ASCE)MT.1943-5533.0000690.
Yao, H., Z. You, L. Li, X. Shi, S. W. Goh, J. Mills-Beale, and D. Wingard. 2012. “Performance of asphalt binder blended with non-modified and polymer-modified nanoclay.” Constr. Build. Mater. 35 (Oct): 159–170. https://doi.org/10.1016/j.conbuildmat.2012.02.056.
You, Z., J. Mills-Beale, J. M. Foley, S. Roy, G. M. Odegard, Q. Dai, and S. W. Goh. 2011. “Nanoclay-modified asphalt materials: Preparation and characterization.” Constr. Build. Mater. 25 (2): 1072–1078. https://doi.org/10.1016/j.conbuildmat.2010.06.070.
Yusoff, N. I. M., A. A. S. Breem, H. N. Alattug, A. Hamim, and J. Ahmad. 2014. “The effects of moisture susceptibility and aging conditions on nano-silica/polymer-modified asphalt mixtures.” Constr. Build. Mater. 72 (Dec): 139–147. https://doi.org/10.1016/j.conbuildmat.2014.09.014.

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Go to Journal of Materials in Civil Engineering
Journal of Materials in Civil Engineering
Volume 30Issue 8August 2018

History

Received: Jun 4, 2017
Accepted: Dec 22, 2017
Published online: May 26, 2018
Published in print: Aug 1, 2018
Discussion open until: Oct 26, 2018

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Authors

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Indu Venu Sabaraya
Dept. of Civil, Architectural and Environmental Engineering, Univ. of Texas at Austin, 301 E Dean Keeton St., Austin, TX 78712.
Angelo Filonzi
Dept. of Civil, Architectural and Environmental Engineering, Univ. of Texas at Austin, 301 E Dean Keeton St., Austin, TX 78712.
Ramez Hajj
Dept. of Civil, Architectural and Environmental Engineering, Univ. of Texas at Austin, 301 E Dean Keeton St., Austin, TX 78712.
Dipesh Das, Ph.D.
Dept. of Civil, Architectural and Environmental Engineering, Univ. of Texas at Austin, 301 E Dean Keeton St., Austin, TX 78712.
Navid B. Saleh, Ph.D., M.ASCE
Associate Professor, Dept. of Civil, Architectural and Environmental Engineering, Univ. of Texas at Austin, 301 E Dean Keeton St., Austin, TX 78712.
Amit Bhasin, Ph.D., P.E., A.M.ASCE [email protected]
Director, Center for Transportation Research, Associate Professor, Dept. of Civil, Architectural and Environmental Engineering, Univ. of Texas at Austin, 301 E Dean Keeton St., Austin, TX 78712 (corresponding author). Email: [email protected]

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