High- and Intermediate-Temperature Performance of Asphalt Binder Containing Carbon Nanotube Using Different Rheological Approaches
Publication: Journal of Materials in Civil Engineering
Volume 30, Issue 1
Abstract
The present research work was undertaken to evaluate the rutting performance of carbon nanotube (CNT)–modified asphalt binders. Additionally, intermediate-temperature performance, aging resistivity potential, and high-temperature storage stability were also evaluated. Reported literature on rutting performance of CNT-modified asphalt binders is mainly based on the Superpave rutting parameter (), which does not account for the recovery aspect of binder. The paper first highlights the importance of the elastic response of CNT-modified asphalt binders for better understanding about its rutting performance. Further, different approaches such as the evaluation of zero shear viscosity (ZSV), creep test, and multiple stress creep recovery (MSCR) were utilized to reach appropriate conclusions. A recently developed approach, linear amplitude sweep (LAS), was used for evaluating intermediate-temperature performance. The CNT was varied as 0, 0.4, 0.75, 1.5, and 2.25% by the weight of control binder. The value was found to increase until 1.5% CNT content; however, the addition of 2.25% CNT resulted in decreased , indicating reduced rutting performance at higher CNT content. Contrary to the trend, significant improvement in recovery value was observed for all CNT percentages. Further, based on detailed analysis carried out for different rheological parameters such as ZSV value (evaluated using the steady shear approach), deformation resistivity potential from creep test, recovery (R), and nonrecoverable creep compliance () from the MSCR test, CNT addition to the control binder showed significant improvement in rutting resistivity potential for all CNT percentages. Although ZSV value significantly improved with the addition of CNT, the increase in CNT content showed an early transition from Newtonian to non-Newtonian behavior. Further, analysis for stress sensitivity was carried based on the R and values obtained from the MSCR test, which showed an increase in stress sensitivity with the addition of CNT to the control binder. The need for improvement in the current protocol used for evaluating stress sensitivity of asphalt binder (based on the MSCR test) has also been discussed. Improvement in intermediate-temperature performance evaluated through LAS test was also observed. Also, CNT addition to asphalt binder was found to be stable under high-temperature storage conditions. Overall, improvement in high- and intermediate-temperature performance can be expected with the addition of CNT to the control binder.
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References
AASHTO. (2009). “Standard method of test for multiple stress creep recovery (MSCR) test of asphalt binder using a dynamic shear rheometer (DSR).” AASHTO TP70, Washington, DC.
AASHTO. (2010). “Standard specification for performance-graded asphalt binder using multiple stress creep recovery (MSCR) test.” AASHTO MP19, Washington, DC.
AASHTO. (2014). “Standard method of test for estimating damage tolerance of asphalt binders using the linear amplitude sweep.” AASHTO TP101, Washington, DC.
Affdl, J. C., and Kardos, J. L. (1976). “The Halpin-Tsai equations: A review.” Polym. Eng. Sci., 16(5), 344–352.
Airey, G. D. (2011). “Factors affecting the rheology of polymer modified bitumen.” Polymer modified bitumen: Properties and characterization, Woodhead, Oxford, U.K., 238–263.
Ameri, M., Nowbakht, S., Molayem, M., and Aliha, M. R. M. (2016). “Investigation of fatigue and fracture properties of asphalt mixtures modified with carbon nanotubes.” Fatigue Fract. Eng. Mater. Struct., 39(7), 896–906.
Amin, I., El-Badawy, S. M., Breakah, T., and Ibrahim, M. H. (2016). “Laboratory evaluation of asphalt binder modified with carbon nanotubes for Egyptian climate.” Constr. Build. Mater., 121, 361–372.
Amirkhanian, A. N., Xiao, F., and Amirkhanian, S. N. (2010). “Evaluation of high temperature rheological characteristics of asphalt binder with carbon nano particles.” J. Test. Eval., 39(4), 1–9.
Amirkhanian, A. N., Xiao, F. P., and Amirkhanian, S. N. (2011). “Characterization of unaged asphalt binder modified with carbon nano particles.” Int. J. Pavement Res. Technol., 4(5), 281–286.
Andrews, R., Jacques, D., Minot, M., and Rantell, T. (2002). “Fabrication of carbon multiwall nanotube/polymer composites by shear mixing.” Macromol. Mater. Eng., 287(6), 395–403.
Arabani, M., and Faramarzi, M. (2015). “Characterization of CNTs-modified HMA’s mechanical properties.” Constr. Build. Mater., 83, 207–215.
Arash, B., Wang, Q., and Varadan, V. K. (2014). “Mechanical properties of carbon nanotube/polymer composites.” Sci. Rep., 4(1), 6479.
Ashish, P. K., Singh, D., and Bohm, S. (2016a). “A study on the rheological performance of a nanoclay-modified asphalt binder using the Brookfield viscometer and dynamic shear rheometer.” Fourth Int. Conf. on Geo-China, ASCE, Reston, VA, 9–15.
Ashish, P. K., Singh, D., and Bohm, S. (2016b). “Evaluation of rutting, fatigue and moisture damage performance of nanoclay modified asphalt binder.” Constr. Build. Mater., 113, 341–350.
Ashish, P. K., Singh, D., and Bohm, S. (2017). “Investigation on influence of nanoclay addition on rheological performance of asphalt binder.” Road Mater. Pavement Des., 18(5), 1007–1026.
ASTM. (2007). “Standard test method for ductility of bituminous materials.” ASTM D113, West Conshohocken, PA.
ASTM. (2010a). “Standard test method for flash and fire points by Cleveland open cup tester.” ASTM D92, West Conshohocken, PA.
ASTM. (2010b). “Standard test method for kinematic viscosity of asphalts (bitumens).” ASTM D2170, West Conshohocken, PA.
ASTM. (2013). “Standard test method for penetration of bituminous materials.” ASTM D5, West Conshohocken, PA.
ASTM. (2014a). “Standard practice for determining the separation tendency of polymer from polymer modified asphalt.” ASTM D7173, West Conshohocken, PA.
ASTM. (2014b). “Standard test method for effects of heat and air on asphaltic materials (thin-film oven test).” ASTM D1754, West Conshohocken, PA.
ASTM. (2014c). “Standard test method for softening point of bitumen (ring-and-ball apparatus).” ASTM D36, West Conshohocken, PA.
ASTM. (2015a). “Standard test method for determining the rheological properties of asphalt binder using a dynamic shear rheometer.” ASTM D7175, West Conshohocken, PA.
ASTM. (2015b). “Standard test method for viscosity determination of asphalt at elevated temperatures using a rotational viscometer.” ASTM D4402, West Conshohocken, PA.
Bahia, H. U., Zeng, M., Zhai, H., and Khatri, A. (1999). “Superpave protocols for modified asphalt binders.”, National Cooperative Highway Research Program, Washington, DC, 9–10.
Barber, A. H., Cohen, S. R., and Wagner, H. D. (2003). “Measurement of carbon nanotube-polymer interfacial strength.” Appl. Phys. Lett., 82(23), 4140–4142.
Binard, C., Anderson, D., Lapalu, L., and Planche, J. P. (2004). “Zero shear viscosity of modified and unmodified binders.” Proc., 3rd Eurasphalt and Eurobitume Congress, Vol. 2, Foundation Eurasphalt, Breukelen, Netherlands.
Biro, S., Gandhi, T., and Amirkhanian, S. (2009). “Determination of zero shear viscosity of warm asphalt binders.” Constr. Build. Mater., 23(5), 2080–2086.
Breuer, O., and Sundararaj, U. (2004). “Big returns from small fibers: A review of polymer/carbon nanotube composites.” Polym. Compos., 25(6), 630–645.
Cheng, J., Shen, J., and Xiao, F. (2011). “Moisture susceptibility of warm-mix asphalt mixtures containing nanosized hydrated lime.” J. Mater. Civ. Eng., 1552–1559.
Coleman, J. N., Khan, U., Blau, W. J., and Gun’ko, Y. K. (2006). “Small but strong: A review of the mechanical properties of carbon nanotube-polymer composites.” Carbon, 44(9), 1624–1652.
D’Angelo, J., Kluttz, R., Dongre, R. N., Stephens, K., and Zanzotto, L. (2007). “Revision of the Superpave high temperature binder specification: The multiple stress creep recovery test (with discussion).” 2007 Journal of the Association of Asphalt Paving Technologists: From the Proc., Technical Sessions, Association of Asphalt Paving Technologists, Lino Lakes, MN.
De Visscher, J., Soenen, H., Vanelstraete, A., and Redelius, P. (2004). “A comparison of the zero shear viscosity from oscillation tests and the repeated creep test.” Proc., 3rd Eurasphalt and Eurobitume Congress, Vol. 2, Foundation Eurasphalt, Breukelen, Netherlands.
Diab, A., and You, Z. (2014). “Evaluation of foam-based warm mix asphalt modified with nano-sized hydrated lime using multiple creep and recovery tests.” Second Transportation and Development Congress, ASCE, Reston, VA, 230–238.
Dongré, R., and D’Angelo, J. (2003). “Refinement of Superpave high-temperature binder specification based on pavement performance in the accelerated loading facility.” Transp. Res. Rec., 1829, 39–46.
Du, J. H., Bai, J., and Cheng, H. M. (2007). “The present status and key problems of carbon nanotube based polymer composites.” Express Polym. Lett., 1(5), 253–273.
Elbirli, B., and Shaw, M. T. (1978). “Time constants from shear viscosity data.” J. Rheol., 22(5), 561–570.
Elseifi, M. A., Alvergue, A., Mohammad, L. N., Salari, S., Aguiar-Moya, J. P., and Cooper, S. B., Jr. (2015). “Rutting and fatigue behaviors of shingle-modified asphalt binders.” J. Mater. Civ. Eng., 04015113.
Faramarzi, M., Arabani, M., Haghi, A. K., and Mottaghitalab, V. (2015). “Carbon nanotubes-modified asphalt binder: Preparation and characterization.” Int. J. Pavement Res. Technol., 8(1), 29–37.
Giuliani, F., Merusi, F., and Antunes, I. (2006). “Creep flow behavior of asphalt rubber binder—The zero shear viscosity analysis.” Proc., Asphalt Rubber, Palm Springs, CA, 1–16.
Goli, A., Ziari, H., and Amini, A. (2017). “Influence of carbon nanotubes on performance properties and storage stability of SBS modified asphalt binders.” J. Mater. Civ. Eng., 04017070.
Hasan, Z., Kamran, R. O., Mohammad, F., Ahmad, G., and Hosein, F. (2012). “Evaluation of different conditions on the mixing bitumen and carbon nanotubes.” Int. J. Civ. Environ. Eng., 12(6), 12–53.
Hassan, M., Mohammad, L., Cooper, S., III, and Dylla, H. (2011). “Evaluation of nano-titanium dioxide additive on asphalt binder aging properties.” Transp. Res. Rec., 2207, 11–15.
Jahromi, S. G., Andalibizade, B., and Khodaii, A. (2010). “Mechanical behavior of nanoclay modified asphalt mixtures.” J. Test. Eval., 38(5), 1–9.
Kim, H. S., Lee, S. J., and Amirkhanian, S. (2010). “Rheology investigation of crumb rubber modified asphalt binders.” KSCE J. Civ. Eng., 14(6), 839–843.
Li, Y. L., Shen, M. Y., Su, H. S., Chiang, C. L., and Yip, M. C. (2012). “A study on mechanical properties of CNT-reinforced carbon/carbon composites.” J. Nanomater., 2012, 262694.
Ma, P. C., Kim, J. K., and Tang, B. Z. (2007). “Effects of silane functionalization on the properties of carbon nanotube/epoxy nanocomposites.” Compos. Sci. Technol., 67(14), 2965–2972.
Ma, P. C., Siddiqui, N. A., Marom, G., and Kim, J. K. (2010). “Dispersion and functionalization of carbon nanotubes for polymer-based nanocomposites: A review.” Appl. Sci. Manuf., 41(10), 1345–1367.
Ma, P. C., Tang, B. Z., and Kim, J. K. (2008). “Effect of CNT decoration with silver nanoparticles on electrical conductivity of CNT-polymer composites.” Carbon, 46(11), 1497–1505.
Manchado, M. L., Valentini, L., Biagiotti, J., and Kenny, J. M. (2005). “Thermal and mechanical properties of single-walled carbon nanotubes-polypropylene composites prepared by melt processing.” Carbon, 43(7), 1499–1505.
McNally, T., et al. (2005). “Polyethylene multiwalled carbon nanotube composites.” Polymer, 46(19), 8222–8232.
Morea, F., Agnusdei, J. O., and Zerbino, R. (2010). “Comparison of methods for measuring zero shear viscosity in asphalts.” Mater. Struct., 43(4), 499–507.
Ouyang, C., Wang, S., Zhang, Y., and Zhang, Y. (2006). “Low-density polyethylene/silica compound modified asphalts with high-temperature storage stability.” J. Appl. Polym. Sci., 101(1), 472–479.
Park, S. H., and Bandaru, P. R. (2010). “Improved mechanical properties of carbon nanotube/polymer composites through the use of carboxyl-epoxide functional group linkages.” Polymer, 51(22), 5071–5077.
Parvez, M. A., Wahhab, H. I. A. A., Shawabkeh, R. A., and Hussein, I. A. (2014). “Asphalt modification using acid treated waste oil fly ash.” Constr. Build. Mater., 70, 201–209.
Peigney, A., Laurent, C., Flahaut, E., Bacsa, R. R., and Rousset, A. (2001). “Specific surface area of carbon nanotubes and bundles of carbon nanotubes.” Carbon, 39(4), 507–514.
Polacco, G., Stastna, J., Biondi, D., and Zanzotto, L. (2006). “Relation between polymer architecture and nonlinear viscoelastic behavior of modified asphalts.” Curr. Opin. Colloid Interface Sci., 11(4), 230–245.
Rowe, G. M., D’Angelo, J. A., and Sharrock, M. J. (2002). “Use of the zero shear viscosity as a parameter for the high temperature binder specification parameter.” 3rd Int. Symp. on Binder Rheology and Pavement Performance, Abatech Consulting Engineer, Blooming Glen, PA.
Saboo, N., and Kumar, P. (2016). “Analysis of different test methods for quantifying rutting susceptibility of asphalt binders.” J. Mater. Civ. Eng., 04016024.
Salvetat, J. P., et al. (1999). “Elastic and shear moduli of single-walled carbon nanotube ropes.” Phys. Rev. Lett., 82(5), 944–947.
Santagata, E., Baglieri, O., Tsantilis, L., and Chiappinelli, G. (2015a). “Fatigue and healing properties of nano-reinforced bituminous binders.” Int. J. Fatigue, 80, 30–39.
Santagata, E., Baglieri, O., Tsantilis, L., and Chiappinelli, G. (2015b). “Fatigue properties of bituminous binders reinforced with carbon nanotubes.” Int. J. Pavement Eng., 16(1), 80–90.
Santagata, E., Baglieri, O., Tsantilis, L., Chiappinelli, G., and Aimonetto, I. B. (2015c). “Effect of sonication on high temperature properties of bituminous binders reinforced with nano-additives.” Constr. Build. Mater., 75, 395–403.
Santagata, E., Baglieri, O., Tsantilis, L., and Dalmazzo, D. (2012). “Rheological characterization of bituminous binders modified with carbon nanotubes.” Procedia-Social Behav. Sci., 53, 546–555.
Seo, M. K., and Park, S. J. (2004). “Electrical resistivity and rheological behaviors of carbon nanotubes-filled polypropylene composites.” Chem. Phys. Lett., 395(1), 44–48.
Shafabakhsh, G., Mirabdolazimi, S. M., and Sadeghnejad, M. (2014). “Evaluation the effect of nano-TiO2 on the rutting and fatigue behavior of asphalt mixtures.” Constr. Build. Mater., 54, 566–571.
Shen, J. N., Xie, Z. X., Xiao, F. P., and Fan, W. Z. (2012). “Evaluations of nano-sized hydrated lime on the moisture susceptibility of hot mix asphalt mixtures.” Appl. Mech. Mater., 174, 82–90.
Shenoy, A. (2002). “Model-fitting the master curves of the dynamic shear rheometer data to extract a rut-controlling term for asphalt pavements.” J. Test. Eval., 30(2), 95–102.
Shirodkar, P., Mehta, Y., Nolan, A., Dahm, K., Dusseau, R., and McCarthy, L. (2012). “Characterization of creep and recovery curve of polymer modified binder.” Constr. Build. Mater., 34, 504–511.
Steyn, W. J. (2009). “Potential applications of nanotechnology in pavement engineering.” J. Transp. Eng., 764–772.
Steyn, W. J., Bosman, T. E., Galle, S., and van Heerden, J. (2013). “Evaluating the properties of bitumen stabilized with carbon nanotubes.” Adv. Mater. Res., 723, 312–319.
Teizer, J., Venugopal, M., Teizer, W., and Felkl, J. (2011). “Nanotechnology and its impact on construction: Bridging the gap between researchers and industry professionals.” J. Constr. Eng. Manage., 594–604.
Vlachovicova, Z., Wekumbura, C., Stastna, J., and Zanzotto, L. (2007). “Creep characteristics of asphalt modified by radial styrene-butadiene–styrene copolymer.” Constr. Build. Mater., 21(3), 567–577.
Wang, P., Dong, Z. J., Tan, Y. Q., and Liu, Z. Y. (2016). “Anti-ageing properties of styrene-butadiene–styrene copolymer-modified asphalt combined with multi-walled carbon nanotubes.” Road Mater. Pavement Des., 18(3), 533–549.
Wang, X., et al. (2009). “Fabrication of ultralong and electrically uniform single-walled carbon nanotubes on clean substrates.” Nano Lett., 9(9), 3137–3141.
Xiao, F., Amirkhanian, A. N., and Amirkhanian, S. N. (2010). “Influence of carbon nanoparticles on the rheological characteristics of short-term aged asphalt binders.” J. Mater. Civ. Eng., 423–431.
Xiao, F., Amirkhanian, A. N., and Amirkhanian, S. N. (2011). “Long-term ageing influence on rheological characteristics of asphalt binders containing carbon nanoparticles.” Int. J. Pavement Eng., 12(6), 533–541.
Yang, X., and You, Z. (2015). “High temperature performance evaluation of bio-oil modified asphalt binders using the DSR and MSCR tests.” Constr. Build. Mater., 76, 380–387.
Yao, H., et al. (2012). “Rheological properties and chemical bonding of asphalt modified with nanosilica.” J. Mater. Civ. Eng., 1619–1630.
Yu, J. Y., Feng, P. C., Zhang, H. L., and Wu, S. P. (2009). “Effect of organo-montmorillonite on aging properties of asphalt.” Constr. Build. Mater., 23(7), 2636–2640.
Yusoff, N. I. M., Breem, A. A. S., Alattug, H. N., Hamim, A., and Ahmad, J. (2014). “The effects of moisture susceptibility and ageing conditions on nano-silica/polymer-modified asphalt mixtures.” Constr. Build. Mater., 72, 139–147.
Zhang, H., Zhu, C., and Kuang, D. (2015a). “Physical, rheological, and aging properties of bitumen containing organic expanded vermiculite and nano-zinc oxide.” J. Mater. Civ. Eng., 04015203.
Zhang, H., Zhu, C., Yu, J., Shi, C., and Zhang, D. (2015b). “Influence of surface modification on physical and ultraviolet aging resistance of bitumen containing inorganic nanoparticles.” Constr. Build. Mater., 98, 735–740.
Zoorob, S. E., Castro-Gomes, J. P., Oliveira, L. P., and O’Connell, J. (2012). “Investigating the multiple stress creep recovery bitumen characterisation test.” Constr. Build. Mater., 30, 734–745.
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©2017 American Society of Civil Engineers.
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Received: Jan 9, 2017
Accepted: Jun 9, 2017
Published online: Oct 26, 2017
Published in print: Jan 1, 2018
Discussion open until: Mar 26, 2018
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