Technical Papers
Jul 29, 2017

Probabilistic and Statistical Modeling of Chloride-Induced Corrosion for Concrete Containing Metakaolin

Publication: Journal of Materials in Civil Engineering
Volume 29, Issue 11

Abstract

This paper presents new models for computing the chloride-induced corrosion period based on combining Monte Carlo simulation and statistical analysis methods. The study is divided into two parts. The first part utilized Monte Carlo simulation to predict the probability of corrosion (1–200 years) for concrete containing metakaolin (MK) with different mixture proportions and concrete covers. Also, the effect of different mixture parameters (percentage of MK, binder content, and water-to-binder ratio) on the probability of corrosion was studied in this part. The second part adopted statistical analysis to develop models predicting the chloride-induced corrosion period (time to reach 10% probability of corrosion initiation) in various MK mixtures and identified the most significant factors affecting this period. Design charts were also developed using statistical analysis to facilitate and simplify the prediction of the chloride-induced corrosion period. The results showed that the probability of corrosion decreased as the percentage of MK increased. Also, using a lower W/B ratio or higher binder content in MK mixtures improved the effectiveness of MK to reduce the probability of corrosion. The results also showed that the most significant factor affecting the chloride-induced corrosion period was found to be MK replacement, W/B ratio, and binder content respectively, in order of significance. The developed models and design charts in this paper will help designers and engineers to better understand the influence and the importance of various mix design parameters of MK mixtures on the chloride-induced corrosion period estimation.

Get full access to this article

View all available purchase options and get full access to this article.

References

Al-Alaily, H. S., and Hassan, A. A. A. (2016). “Time-dependence of chloride diffusion for concrete containing metakaolin.” J. Build. Eng., 7, 159–169.
Amleh, L. B. (2000). “Deterioration of reinforcing steel in concrete due to corrosion.” Ph.D. thesis, McGill Univ., Montréal.
Angst, U., Elsener, B., Larsen, C. K., and Vennesland, Ø. (2009). “Critical chloride content in reinforced concrete—A review.” Cem. Concr. Res., 39(12), 1122–1138.
Ann, K. Y., Pack, S. W., Hwang, J.-P., Song, H. W., and Kim, S. H. (2010). “Service life prediction of a concrete bridge structure subjected to carbonation.” Constr. Build. Mater., 24(8), 1494–1501.
Asbridge, A. H., Chadbourn, G. A., and Page, C. L. (2001). “Effects of metakaolin and the interfacial transition zone on the diffusion of chloride ions through cement mortars.” Cem. Concr. Res., 31(11), 1567–1572.
Barnes, P., Bensted, J., and Jones, T. R. (2003). “Metakaolin as pozzolanic addition to concrete.” Structure and performance of cements, CRC Press, London, 372–398.
Bastidas-Arteaga, E., Chateauneuf, A., Sánchez-Silva, M., Bressolette, P., and Schoefs, F. (2011). “A comprehensive probabilistic model of chloride ingress in unsaturated concrete.” Eng. Struct., 33(3), 720–730.
Bayramov, F., Taşdemir, C., and Taşdemir, M. A. (2004). “Optimisation of steel fibre reinforced concretes by means of statistical response surface method.” Cem. Concr. Compos., 26(6), 665–675.
Bentz, E. C. (2003). “Probabilistic modeling of service life for structures subjected to chlorides.” ACI Mater. J., 100(5), 391–397.
Boulfiza, M., Sakai, K., Banthia, N. R., and Yoshida, H. (2003). “Prediction of chloride ions ingress in uncracked and cracked concrete.” ACI Mater. J., 100(1), 38–48.
Cabrera, J. G., Claisse, P. A., and Hunt, D. N. (1995). “A statistical analysis of the factors which contribute to the corrosion of steel in portland cement and silica fume concrete.” Constr. Build. Mater., 9(2), 105–113.
Cady, P. D., and Weyers, R. E. (1983). “Chloride penetration and the deterioration of concrete bridge decks.” Cem. Concr. Aggregates, 5(2), 81–87.
Cassagnabère, F., Escadeillas, G., and Mouret, M. (2009). “Study of the reactivity of cement/metakaolin binders at early age for specific use in steam cured precast concrete.” Constr. Build. Mater., 23(2), 775–784.
Cassagnabère, F., Mouret, M., Escadeillas, G., Broilliard, P., and Bertrand, A. (2010). “Metakaolin, a solution for the precast industry to limit the clinker content in concrete: Mechanical aspects.” Constr. Build. Mater., 24(7), 1109–1118.
Cheewaket, T., Jaturapitakkul, C., and Chalee, W. (2012). “Initial corrosion presented by chloride threshold penetration of concrete up to 10 year-results under marine site.” Constr. Build. Mater., 37, 693–698.
Chen, J., Xu, Q., Li, J., and Fan, S. (2010). “Improved response surface method for anti-slide reliability analysis of gravity dam based on weighted regression.” J. Zhejiang Univ. Sci. A., 11(6), 432–439.
Coleman, J., and Page, C. L. (1997). “Aspects of the pore solution chemistry of hydrated cement pastes containing metakaolin.” Cem. Concr. Res., 27(1), 147–154.
Courard, L., Darimont, A., Schouterden, M., Ferauche, F., Willem, X., and Degeimbre, R. (2003). “Durability of mortars modified with metakaolin.” Cem. Concr. Res., 33(9), 1473–1479.
Crank, J. (1956). Mathematics of diffusion, Clarendon Press, Bristol, U.K.
Cusson, D., and Isgor, B. (2004). “Durability of concrete structures: Prevention, evaluation, inspection, repair and prediction.” Can. Civil Engineer., 21(2), 4–5.
Dıaz, B., Novoa, X. R., and Perez, M. C. (2006). “Study of the chloride diffusion in mortar: A new method of determining diffusion coefficients based on impedance measurements.” Cem. Concr. Compos., 28(3), 237–245.
Ehlen, M. A., Thomas, M. D. A., and Bentz, E. C. (2009). “Life-365 service life prediction ModelTM version 2.0.” Concr. Int., 31(5), 41–46.
Enright, M. P., and Frangopol, D. M. (1998). “Probabilistic analysis of resistance degradation of reinforced concrete bridge beams under corrosion.” Eng. Struct., 20(11), 960–971.
Ferreira, R. M., and Jalali, S. (2006). “Probability-based durability design of concrete structures in marine environment.” Proc., CEC-MAT—Comunicações a Conferências Internacionais, Taylor & Francis, London.
Fluge, F. (2001). “Marine chlorides—A probabilistic approach to derive provisions for EN 206-1.” Proc., Third DuraNet Workshop on Service Life Design of Concrete Structures, from Theory to Standardisation, Tromsø, 10–12.
Ghali, A., Gayed, R. B., and Kroman, J. (2016). “Sustainability of concrete infrastructures.” J. Bridge Eng., 04016033.
Ghezal, A., and Khayat, K. H. (2002). “Optimizing self-consolidating concrete with limestone filler by using statistical factorial design methods.” ACI Mater. J., 99(3), 264–272.
Gjørv, O. E. (2009). Durability design of concrete structures in severe environments, Taylor & Francis, New York.
Gruber, K. A., Ramlochan, T., Boddy, A., Hooton, R. D., and Thomas, M. D. A. (2001). “Increasing concrete durability with high-reactivity metakaolin.” Cem. Concr. Compos., 23(6), 479–484.
Halamickova, P., Detwiler, R. J., Bentz, D. P., and Garboczi, E. J. (1995). “Water permeability and chloride ion diffusion in portland cement mortars: Relationship to sand content and critical pore diameter.” Cem. Concr. Res., 25(4), 790–802.
Hassan, A. A. A., Hossain, K. M. A., and Lachemi, M. (2009). “Corrosion resistance of self-consolidating concrete in full-scale reinforced beams.” Cem. Concr. Compos., 31(1), 29–38.
Hassan, A. A. A., Hossain, K. M. A., and Lachemi, M. (2012). “Effect of metakaolin and silica fume on the durability of self-consolidating concrete.” Cem. Concr. Compos., 34(6), 801–807.
Hooton, R. D., Geiker, M. R., and Bentz, E. C. (2002). “Effects of curing on chloride ingress and implications on service life.” Mater. J., 99(2), 201–206.
Kang, S. C., Koh, H. M., and Choo, J. F. (2010). “An efficient response surface method using moving least squares approximation for structural reliability analysis.” Probab. Eng. Mech., 25(4), 365–371.
Kato, Y., and Uomoto, T. (2005). “Modeling of effective diffusion coefficient of substances in concrete considering spatial properties of composite materials.” Adv. Concr. Technol., 3(2), 241–251.
Kirkpatrick, T. J., Weyers, R. E., Anderson-Cook, C. M., and Sprinkel, M. M. (2002). “Probabilistic model for the chloride-induced corrosion service life of bridge decks.” Cem. Concr. Res., 32(12), 1943–1960.
Liang, M., Lin, L., and Liang, C. (2002). “Service life prediction of existing reinforced concrete bridges exposed to chloride environment.” J. Infrastruct. Syst., 76–85.
Lizarazo-Marriaga, J., and Claisse, P. (2009). “Determination of the concrete chloride diffusion coefficient based on an electrochemical test and an optimization model.” Mater. Chem. Phys., 117(2–3), 536–543.
Malhotra, V. M. (2000). “Role of supplementary cementing materials in reducing greenhouse gas emissions.” Concrete technology for a sustainable development in the 21st century, O. E. Gjorn and K. Sakai, eds., E&FN Spon, London.
Mangat, P. S., and Molloy, B. T. (1994). “Prediction of long term chloride concentration in concrete.” Mater. Struct., 27(6), 338–346.
Marek, P., and Brozzetti, J. (2001). Probabilistic assessment of structures using Monte Carlo simulation, basics, exercises, software, ITAM Academy of Sciences Czech Republic, Brno, Czech Republic.
Marek, P., Guštar, M., and Tikalsky, P. J. (1993). “Monte Carlo simulation—Tool for better understanding of LRFD.” J. Struct. Eng., 1586–1599.
Marikunte, S., Aldea, C., and Shah, S. P. (1997). “Durability of glass fiber reinforced cement composites: Effect of silica fume and metakaolin.” Adv. Cem. Based Mater., 5(3–4), 100–108.
Marsh, P. S., and Frangopol, D. M. (2008). “Reinforced concrete bridge deck reliability model incorporating temporal and spatial variations of probabilistic corrosion rate sensor data.” Reliab. Eng. Syst. Saf., 93(3), 394–409.
McNally, C., and Sheils, E. (2012). “Probability-based assessment of the durability characteristics of concretes manufactured using CEM II and GGBS binders.” Constr. Build. Mater., 30, 22–29.
McPolin, D. O., Basheer, P. A., and Long, A. E. (2009). “Carbonation and pH in mortars manufactured with supplementary cementitious materials.” J. Mater. Civil Eng., 217–225.
Mehta, P. K., and Monteiro, P. J. M. (1993). Concrete: Structure, properties and materials, Prentice Hall, Upper Saddle River, NJ.
Newman, J. B., and Choo, B. S. (2003). Advanced concrete technology: Concrete properties, Butterworth-Heinemann, San Diego.
Nieves-Mendoza, D., et al. (2012). “Statistical analysis of factors influencing corrosion in concrete structures.” Int. J. Electrochem. Sci., 7(6), 5495–5509.
Nowak, A. S., and Collins, K. R. (2000). Reliability of structures, McGraw Hill, New York.
Poon, C. S., Lam, L., Kou, S. C., Wong, Y. L., and Wong, R. (2001). “Rate of pozzolanic reaction of metakaolin in high-performance cement pastes.” Cem. Concr. Res., 31(9), 1301–1306.
Quanwang, L., Kefei, L., Xingang, Z., Qinming, Z., and Zhihong, F. (2015). “Model-based durability design of concrete structures in Hong Kong–Zhuhai–Macau sea link project.” Struct. Saf., 53, 1–12.
Ramezanianpour, A. A., Kazemian, A., Moghaddam, M. A., Moodi, F., and Ramezanianpour, A. M. (2016). “Studying effects of low-reactivity GGBFS on chloride resistance of conventional and high strength concretes.” Mater. Struct., 49(7), 1–13.
Ramlochan, T., Thomas, M., and Gruber, K. A. (2000). “The effect of metakaolin on alkali-silica reaction in concrete.” Cem. Concr. Res., 30(3), 339–344.
Shamsad, A., Abul Kalam, A., and Kevin, F. L. (2012). “Effect of the key mixture parameters on tortuosity and permeability of concrete.” J. Adv. Concr. Technol., 10(3), 86–94.
Sudret, B. (2008). “Probabilistic models for the extent of damage in degrading reinforced concrete structures.” Reliab. Eng. Syst. Saf., 93(3), 410–422.
Takewaka, K., and Matsumoto, S. (1988). “Quality and cover thickness of concrete based on the estimation of chloride penetration in marine environments.” Proc., 2nd Int. Conf. of Concrete in Marine Environment, ACI, Farmington Hills, MI, 381–400.
Tang, L., and Nilsson, L. (1992). “Chloride diffusivity in high strength concrete at different ages.” Nordic Concr. Res., 11(1), 162–171.
Thomas, M. D. A., and Bamforth, P. B. (1999). “Modelling chloride diffusion in concrete: Effect of fly ash and slag.” Cem. Concr. Res., 29(4), 487–495.
Tuutti, K. (1982). “Corrosion of steel in concrete.”, Swedish Cement and Concrete Research Institute, Stockholm, Sweden.
Vedalakshmi, R., Devi, R., Emmanuel, B., and Palaniswamy, N. (2008). “Determination of diffusion coefficient of chloride in concrete: An electrochemical impedance spectroscopic approach.” Mater. Struct., 41(7), 1315–1326.
Wild, S., Khatib, J. M., and Jones, A. (1996). “Relative strength, pozzolanic activity and cement hydration in superplasticised metakaolin concrete.” Cem. Concr. Res., 26(10), 1537–1544.
Wong, S. M., Hobbs, R. E., and Onof, C. (2005). “An adaptive response surface method for reliability analysis of structures with multiple loading sequences.” Struct. Saf., 27(4), 287–308.
Xuemei, L., Hongjian, D., and Min-Hong, Z. (2015). “A model to estimate the durability performance of both normal and light-weight concrete.” Constr. Build. Mater., 80(1), 255–261.
Young, J. F. (1988). “Review of the pore structure of cement paste and concrete and its influence on permeability.” ACI J., 108, 1–18.

Information & Authors

Information

Published In

Go to Journal of Materials in Civil Engineering
Journal of Materials in Civil Engineering
Volume 29Issue 11November 2017

History

Received: Oct 30, 2016
Accepted: May 2, 2017
Published online: Jul 29, 2017
Published in print: Nov 1, 2017
Discussion open until: Dec 29, 2017

Permissions

Request permissions for this article.

Authors

Affiliations

Hossam S. Al-alaily
Graduate Student and Faculty of Engineering and Applied Science, Dept. of Civil Engineering, Memorial Univ. of Newfoundland, St. John’s, NL, Canada A1B 3X5.
Assem A. A. Hassan, Ph.D. [email protected]
P.Eng.
Associate Professor and Faculty of Engineering and Applied Science, Dept. of Civil Engineering, Memorial Univ. of Newfoundland, St. John’s, NL, Canada A1B 3X5 (corresponding author). E-mail: [email protected]
Amgad A. Hussein, Ph.D.
P.Eng.
Associate Professor, Chair and Faculty of Engineering and Applied Science, Dept. of Civil Engineering, Memorial Univ. of Newfoundland, St. John’s, NL, Canada A1B 3X5.

Metrics & Citations

Metrics

Citations

Download citation

If you have the appropriate software installed, you can download article citation data to the citation manager of your choice. Simply select your manager software from the list below and click Download.

Cited by

View Options

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Media

Figures

Other

Tables

Share

Share

Copy the content Link

Share with email

Email a colleague

Share