Technical Papers
May 10, 2017

Steady-State Chloride Diffusion Coefficient and Chloride Migration Coefficient of Cracks in Concrete

Publication: Journal of Materials in Civil Engineering
Volume 29, Issue 9

Abstract

Prediction of chloride ingress is very important for the durability of reinforced concrete structures in chloride-laden environments, especially for concrete with cracks. It is expected that the chloride diffusion coefficient of a crack is much higher than that of the uncracked part in concrete. A single crack in concrete can be a shortcut for chloride ions to pass through. Research on chloride diffusion/migration through cracks in concrete is limited. Therefore, in this paper steady-state chloride diffusion and migration coefficients of cracks in concrete were measured and calculated and the relationship between the two coefficient types was analyzed theoretically and compared with experimental data. The results show that the ratio between the two sets of diffusion/migration coefficients can be related to the ratio between the specimen length and crack length. The measured crack length depends on the resolution of the sampling by microscopy. The optimum unit sampling length for the crack length measurement was found be close to the value of crack width.

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Acknowledgments

The author is grateful for funding from a China CSC scholarship and the support of experimental work during his study in the School of Planning, Architecture and Civil Engineering at Queen’s University Belfast.

References

Akhavan, A., Shafaatian, S., and Rajabipour, F. (2012). “Quantifying the effects of crack width, tortuosity, and roughness on water permeability of cracked mortars.” Cem. Concr. Res., 42(2), 313–320.
Aldea, C. M., Shah, S. P., and Karr, A. (1999). “Effect of cracking on water and chloride permeability of concrete.” J. Mater. Civ. Eng., 181–187.
Andrade, C. (1993). “Calculation of chloride diffusion coefficients in concrete from ionic migration measurements.” Cem. Concr. Res., 23(3), 724–742.
Arya, C., and Xu, Y. (1995). “Effect of cement type on chloride binding and corrosion of steel in concrete.” Cem. Concr. Res., 25(4), 893–902.
Bockris, J. O., and Reddy, A. K. N. (1998). Modern electrochemistry. Vol.1: Ionics, 2nd Ed., Plenum Press, New York.
British Standard Institution. (2009a). “Silica fume for concrete. Part 1: Definitions, requirements and conformity criteria.”, London.
British Standards Institution. (1989). “Testing concrete—Part 125: Methods for mixing and sampling fresh concrete in the laboratory.”, London.
British Standards Institution. (1992). “Specification for ground granulated blastfurnace slag for use with Portland cement.”, London.
British Standards Institution. (2007). “Fly ash for concrete—Part 1: Definition, specifications and conformity criteria.”, London.
British Standards Institution. (2008). “Aggregates for concrete.”, London.
British Standards Institution. (2009b). “Admixtures for concrete, mortar and grout. Part 2: Concrete admixtures—Definitions, requirements, conformity, marking and labelling.”, London.
British Standards Institution. (2011). “Cement. Part 1: Composition, specifications and conformity criteria for common cements.”, London.
Castellote, M., Andrade, C., and Alonso, C. (2001). “Measurement of the steady and non-steady-state chloride diffusion coefficients in a migration test by means of monitoring the conductivity in the anolyte chamber. Comparison with natural diffusion tests.” Cem. Concr. Res., 31(10), 1411–1420.
Djerbi, A., Bonnet, S., Khelidj, A., and Baroghel-Bouny, V. (2008). “Influence of traversing crack on chloride diffusion into concrete.” Cem. Concr. Res., 38(6), 877–883.
Feynman, R. P., Leighton, R. B., and Sands, M. (1964). The Feynman lectures on physics, 1st Ed., California Institute of Technology, Pasadena, CA.
Gerard, B., and Marchand, J. (2000). “Influence of cracking on the diffusion properties of cement-based materials. I: Influence of continuous cracks on the steady-state regime.” Cem. Concr. Res., 30(1), 37–43.
Gowripalan, N., Sirivivatnanon, V., and Lim, C. (2000). “Chloride diffusivity of concrete cracked in flexure.” Cem. Concr. Res., 30(5), 725–730.
Grathwohl, P. (1998). Diffusion in natural porous media: Contaminant transport, sorption/desorption and dissolution kinetics, Kluwer Academic Publishers, Boston.
Ismail, M., Toumi, A., François, R., and Gagné, R. (2008). “Effect of crack opening on the local diffusion of chloride in cracked mortar samples.” Cem. Concr. Res., 38(8–9), 1106–1111.
Jacobsen, S., Marchand, J., and Boisvert, L. (1996). “Effect of cracking and healing on chloride transport in OPC concrete.” Cem. Concr. Res., 26(6), 869–881.
Jang, S. Y., Kim, B. S., and Oh, B. H. (2011). “Effect of crack width on chloride diffusion coefficients of concrete by steady-state migration tests.” Cem. Concr. Res., 41(1), 9–19.
Nordtest. (1997). “Concrete, mortar and cement based repair materials: Chloride diffusion coefficient from migration cell experiments.”, Espoo, Finland.
Nordtest. (1999). “Concrete, mortar and cement-based repair materials: Chloride migration coefficient from non-steady-state migration experiments.”, Espoo, Finland.
Provis, J. L., Myers, R. J., White, C. E., Rose, V., and van Deventer, J. S. J. (2012). “X-ray microtomography shows pore structure and tortuosity in alkali-activated binders.” Cem. Concr. Res., 42(6), 855–864.
Rodriguez, O. G., and Hooton, R. D. (2003). “Influence of cracks on chloride ingress into concrete.” ACI Mater. J., 100(2), 120–126.
Van den Heede, P., Maes, M., and De Belie, N. (2014). “Influence of active crack width control on the chloride penetration resistance and global warming potential of slabs made with fly ash + silica fume concrete.” Constr. Build. Mater., 67(Part A), 74–80.
Wang, J., Basheer, P., Nanukuttan, S., and Bai, Y. (2015). “Influence of cracking caused by structural loading on chloride-induced corrosion process in reinforced concrete elements: A review.” Durability of reinforced concrete from composition to protection, Springer, London, 99–113.
Wang, J., Basheer, P. A. M., Nanukuttana, S. V., Long, A. E., and Bai, Y. (2016). “Influence of service loading and the resulting micro-cracks on chloride resistance of concrete.” Constr. Build. Mater., 108, 56–66.
Wang, K., Jansen, D. C., Shah, S. P., and Karr, A. F. (1997). “Permeability study of cracked concrete.” Cem. Concr. Res., 27(3), 381–393.
Win, P. P., Watanabe, M., and Machida, A. (2004). “Penetration profile of chloride ion in cracked reinforced concrete.” Cem. Concr. Res., 34(7), 1073–1079.

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Go to Journal of Materials in Civil Engineering
Journal of Materials in Civil Engineering
Volume 29Issue 9September 2017

History

Received: Aug 4, 2016
Accepted: Feb 2, 2017
Published online: May 10, 2017
Published in print: Sep 1, 2017
Discussion open until: Oct 10, 2017

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New York Univ. Abu Dhabi, P.O. Box 129188, Abu Dhabi, United Arab Emirates. ORCID: https://orcid.org/0000-0002-1148-777X. E-mail: [email protected]

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