Technical Papers
Oct 27, 2016

Mesoscopic Predictions of Cement Mortar Diffusivity by Analytical and Numerical Methods

Publication: Journal of Materials in Civil Engineering
Volume 29, Issue 4

Abstract

The purpose of this paper is to develop mesoscale models for predicting the diffusivity of cement mortar by numerical and analytical methods. The interfacial transition zone (ITZ) volume fraction was calculated by a three-dimensional geometric model with randomly distributed aggregates. The decrease in the water–cement ratio of the bulk cement paste due to the presence of ITZ was also considered. The results showed that the bulk paste porosity decreased significantly at a larger aggregate fraction. The mortar diffusivity was predicted by analytical and numerical methods. The predicted mortar diffusivity was in conformance with the measured diffusivity. It also indicated that the decreasing rate of the diffusivity as the increasing fraction of aggregate was dependent on the ITZ contents. The predicted results for the cement mortar with oblate or prolate aggregates showed that the diffusivity was larger as the shapes of the aggregates were more spherical than oblate or prolate.

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Acknowledgments

This research project was financially supported by the National Natural Science Foundation of China (Grant No. 51320105013) and the National Basic Research Program of China (973 program) (Grant No. 2015CB655100).

References

Abyaneh, S. D., Wong, H. S., and Buenfeld, N. R. (2013). “Modelling the diffusivity of mortar and concrete using a three-dimensional mesostructure with several aggregate shapes.” Comput. Mater. Sci., 78, 63–73.
Bary, B., and Bejaoui, S. (2006). “Assessment of diffusive and mechanical properties of hardened cement pastes using a multi-coated sphere assemblage model.” Cem. Concr. Res., 36(2), 245–258.
Caré, S., and Hervé, E. (2004). “Application of a n-phase model to the diffusion coefficient of chloride in mortar.” Transp. Porous Media, 56(2), 119–135.
Delagrave, A., Bigas, J. P., Ollivier, J. P., Marchand, J., and Pigeon, M. (1997). “Influence of the interfacial zone on the chloride diffusivity of mortars.” Adv. Cem. Based Mater., 5(3–4), 86–92.
Duan, H. L., and Karihaloo, B. L. (2007). “Effective thermal conductivities of heterogeneous media containing multiple imperfectly bonded inclusions.” Phys. Rev. B, 75(6).
Duan, H. L., Karihaloo, B. L., Wang, J., and Yi, X. (2006). “Effective conductivities of heterogeneous media containing multiple inclusions with various spatial distributions.” Phys. Rev. B, 73(17).
Garboczi, E. J., and Bentz, D. P. (1998). “Multiscale analytical/numerical theory of the diffusivity of concrete.” Adv. Cem. Based Mater., 8(2), 77–88.
Jiang, Z., Huang, Q., Xi, Y., Gu, X., and Zhang, W. (2016). “Experimental study of diffusivity of the interfacial transition zone between cement paste and aggregate.” J. Mater. Civ. Eng., .
Larrard, T., Bary, B., Adam, E., and Kloss, F. (2013). “Influence of aggregate shapes on drying and carbonation phenomena in 3D concrete numerical samples.” Comp. Mater. Sci., 72, 1–14.
Nielsen, E. P., and Geiker, M. R. (2003). “Chloride diffusion in partially saturated cementitious material.” Cem. Concr. Res., 33(1), 133–138.
Oh, B. H., and Jang, S. Y. (2004). “Prediction of diffusivity of concrete based on simple analytic equitions.” Cem. Concr. Res., 34(3), 463–480.
Pivonka, P., Hellmich, C., and Smith, D. (2004). “Microscopic effects on chloride diffusivity of cement pastes—A scale-transition analysis.” Cem. Concr. Res., 34(12), 2251–2260.
Promentilla, M. A. B., Sugiyama, T., Hitomi, T., and Takeda, N. (2009). “Quantification of tortuosity in hardened cement pastes using synchrotron-based X-ray computed microtomography.” Cem. Concr. Res., 39(6), 548–557.
Scrivener, K. L., and Nemati, K. M. (1996). “The percolation of pore space in the cement paste aggregate interfacial zone of concrete.” Cem. Concr. Res., 26(1), 35–40.
Wong, H. S., Zobel, M., Buenfeld, N. R., and Zimmerman, R. W. (2009). “Influence of the interfacial transition zone and microcracking on the diffusivity, permeability and sorptivity of cement-based materials after drying.” Mag. Concr. Res., 61(8), 571–589.
Xi, Y., and Bazant, Z. P. (1999). “Modeling chloride penetration in saturated concrete.” J. Mater. Civ. Eng., 58–65.
Xi, Y., and Nakhi, A. (2005). “Composite damage models for diffusivity of distressed materials.” J. Mater. Civ. Eng., 286–295.
Yang, C. C., and Su, J. K. (2002). “Approximate migration coefficient of interfacial transition zone and the effect of aggregate content on the migration coefficient of mortar.” Cem. Concr. Res., 32(10), 1559–1565.
Zheng, J. (2012). “Effective medium approach for evaluating the oxygen diffusivity of concrete.” J. Mater. Civ. Eng., 711–717.
Zheng, J. J., and Zhou, X. Z. (2007). “Percolation of ITZs in concrete and effects of attributing factors.” J. Mater. Civ. Eng., 784–790.

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Published In

Go to Journal of Materials in Civil Engineering
Journal of Materials in Civil Engineering
Volume 29Issue 4April 2017

History

Received: Oct 15, 2015
Accepted: Sep 1, 2016
Published online: Oct 27, 2016
Discussion open until: Mar 27, 2017
Published in print: Apr 1, 2017

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Authors

Affiliations

Zhilu Jiang [email protected]
Ph.D. Candidate, Dept. of Structural Engineering, Tongji Univ., 1239 Siping Rd., Shanghai 200092, P.R. China. E-mail: [email protected]
Professor, Dept. of Civil, Architectural, and Environmental Engineering, Univ. of Colorado, Boulder, CO 80309. E-mail: [email protected]
Xianglin Gu [email protected]
Professor, Dept. of Structural Engineering, Tongji Univ., 1239 Siping Rd., Shanghai 200092, P.R. China (corresponding author). E-mail: [email protected]
Qinghua Huang [email protected]
Assistant Professor, Dept. of Structural Engineering, Tongji Univ., 1239 Siping Rd., Shanghai 200092, P.R. China. E-mail: [email protected]
Weiping Zhang [email protected]
Professor, Dept. of Structural Engineering, Tongji Univ., 1239 Siping Rd., Shanghai 200092, P.R. China. E-mail: [email protected]

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