Laboratory Investigation of Washing Practices and Bio-Based Additive for Mitigating Metallic Corrosion by Magnesium Chloride Deicer
Publication: Journal of Materials in Civil Engineering
Volume 29, Issue 1
Abstract
This work evaluates best practices for managing the corrosive effect of magnesium-chloride-based deicers on the metallic components of equipment fleets. The first part of this study evaluates the effectiveness of salt remover for washing bare metals. A dip-dry test was employed to simulate the field conditions. Carbon steel (C1010), aluminum alloy (Al1100), and stainless steel (SS304L) were used in the test program to evaluate the use of water, soapy water, and a commercial salt remover in washing practices. The corrosion behavior of metals was studied using linear polarization and electrochemical impedance spectroscopy measurements. Digital photos and scanning electron microscopy revealed the surface morphology of corrosion coupons. The salt remover could significantly enhance the corrosion resistance of carbon steel and stainless steel in a 30%-by-weight solution, but not that of the aluminum alloy. Further investigation focused on the evaluation of an innovative sugar beet by-product for use as a deicer additive. A modified dip-dry test was employed to simulate the field conditions. Bare and coated C1010 samples were used to evaluate the potential anticorrosion benefits of this green deicer additive. The corrosion behavior of the samples was characterized using electrochemical impedance spectroscopy. The use of sugar beet by-product can enhance the corrosion resistance of carbon steel and the mechanism of protection is the formation of a temporary protective layer on the metallic surface.
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Acknowledgments
The authors acknowledge the financial support provided by the Washington Department of Transportation (WSDOT) as well as the Alaska UTC under the USDOT Research & Innovative Technology Administration (RITA). The authors also acknowledge financial support by the ChuTian Scholar Visiting Professorship Fund provided by the Hubei Department of Education, China, as well as financial support by the National Science Foundation of China (No. 51278390). The authors are indebted to the AUTC project manager Billy Connor, WSDOT project manager Monty Mills, and other technical panel members for their continued support throughout this project. The authors also would like to acknowledge the Laboratory for Cellular Metabolism and Engineering (LCME) at Washington State University for running mass spectroscopy analyses. The contents of this work reflect the views of the authors, who are responsible for the facts and the accuracy of the data presented herein. The authors declare no conflict of interest. The mentioning of trademarks is for reader’s convenience only and does not imply any endorsement.
References
Albright, M. (2005). “Changes in water quality in an urban stream following the use of organically derived deicing products.” Lake Reserv. Manage., 21(1), 119–124.
Alsabagh, A. M., Migahed, M. A., and Awad, H. S. (2006). “Reactivity of polyester aliphatic amine surfactants as corrosion inhibitors for carbon steel in formation water (deep well water).” Corros. Sci., 48(4), 813–828.
Autolab. (2015). “Electrochemical impedance spectroscopy of three coated aluminum samples.” 〈http://www.ecochemie.nl/download/Applicationnotes/Autolab_Application_Note_COR09.pdf〉 (Aug. 1, 2015).
Baskar, R., Kesavan, D., Gopiraman, M., and Subramanian, K. (2014). “Corrosion inhibition of mild steel in 1.0 M hydrochloric acid medium by new photo-cross-linkable polymers.” Prog.Org. Coat., 77(4), 836–844.
Carugo, O. (2014). “Buried chloride stereochemistry in the protein data bank.” BMC Struct. Biol., 14(1), 19.
Chakib, I., et al. (2016). “Relationship between structure and inhibition behaviour of (E)-4-(2, 3-Dihydro-1, 3-benzothiazol-2-ylidene)-3-methyl-1-phenyl-1 H-pyrazol-5(4 H)-one (P1) for mild steel corrosion: Experimental and theoretical approach.” Pharma Chem., 2(8), 380–391.
Cheng, K. C., and Guthrie, T. F. (1998). “Liquid road deicing environment impact (498-0670).” Insurance Corporation of British Columbia, Richmond, BC, Canada.
Dariva, C. G., and Galio, A. F. (2014). “Corrosion inhibitors—Principles, mechanisms and applications.” Developments in corrosion protection, M. Aliofkhazraei, ed., InTech, Rijeka, Croatia.
Elachouri, M., Hajji, M. S., Kertit, S., Essassi, E. M., Salem, M., and Coudert, R. (1995). “Some surfactants in the series of 2-(alkyldimethylammonio) alkanol bromides as inhibitors of the corrosion of iron in acid chloride solution.” Corros. Sci., 37(3), 381–389.
Finšgar, M., and Jackson, J. (2014). “Application of corrosion inhibitors for steels in acidic media for the oil and gas industry: A review.” Corros. Sci., 86, 17–41.
Fischel, M. (2001). “Evaluation of selected deicers based on a review of the literature.”, Colorado Dept. of Transportation, Denver.
Hallberg, S.-E., Gustafsson, A., Johansson, A., and Thunqvist, E.-L. (2007). “Anti-skid treatment tests with glucose, fructose, and unrefined sugar.” 86th Annual Meeting of the Transportation Research Board, Transportation Research Board, Washington, DC.
He, X., and Shi, X. (2009). “Self-repairing coating for corrosion protection of aluminum alloys.” Prog. Org. Coat., 65(1), 37–43.
Honarvar Nazari, M., Bergner, D., and Shi, X. (2015). “Managing metallic corrosion on winter maintenance equipment assets.” Environmental sustainability in transportation infrastructure, ASCE, Reston, VA, 61–76.
Johnson, J. R. (2008). “Removing soluble salts.” Coat. Pro. Mag., 7, 2–5.
Kahl, S. C. (2002). “Agricultural by-products for anti-icing and deicing use in Michigan.”, Michigan Dept. of Transportation, Lansing, MI.
Keddam, M. (2006). “W.R. Whitney award lecture: Application of advanced electrochemical techniques and concepts to corrosion phenomena.” Corrosion, 62(12), 1056–1066.
Li, Y., Fang, Y., Seeley, N., Jungwirth, S., Jackson, E., and Shi, X. (2013). “Corrosion by chloride deicers on highway maintenance equipment: Renewed perspective and laboratory investigation.” Transp. Res. Rec., 2361, 106–113.
Li, Y., Kumar, P., Shi, X., Nguyen, T. A., Xio, Z., and Wu, J. (2012). “Electroless synthesis of Ni-P and Ni-P-Zn alloy coatings for protecting steel rebar from chloride-induced corrosion.” Int. J. Electrochem. Sci., 7, 8151–8169.
Marlier, E. E., Tereniak, S. J., Ding, K., Mulliken, J. E., and Lu, C. C. (2011). “First-row transition-metal chloride complexes of the wide bite-angle diphosphine iPrDPDBFphos and reactivity studies of monovalent nickel—Inorganic chemistry.” Inorg. Chem., 50(19), 9290–9299.
Nazari, M. H., and Allahkaram, S. R. (2010). “The effect of acetic acid on the CO2 corrosion of Grade X70 steel.” Mater. Des., 31(9), 4290–4295.
Nixon, W. A., and Williams, A. D. (2001). “A guide for selecting anti-icing chemicals, version 1.0.”, Univ. of Iowa, Iowa City, IA.
Pilgrim, K. M. (2013). “Determining the aquatic toxicity of deicing materials.”, Minnesota Dept. of Transportation, St. Paul, MN.
Reboul, M. C., and Baroux, B. (2011). “Metallurgical aspects of corrosion resistance of aluminium alloys.” Mater. Corros., 62(3), 215–233.
Shi, X., Li, Y., Jungwirth, S., Fang, Y., Seeley, N., and Jackson, E. (2013a). “Identification and laboratory assessment of best practices to protect DOT equipment from the corrosive effect of chemical deicers.”, Washington State Dept. of Transportation, Olympia, WA.
Shi, X., Veneziano, D., Xie, N., and Gong, J. (2013b). “Use of chloride-based ice control products for sustainable winter maintenance: A balanced perspective.” Cold Reg. Sci. Technol., 86, 104–112.
Solmaz, R. (2014). “Investigation of corrosion inhibition mechanism and stability of Vitamin B1 on mild steel in 0.5 M HCl solution.” Corros. Sci., 81, 75–84.
Stephens, E. V., Wilson, D. F., Eberhardt, J. J., and Sklad, P. S. (2005). “Effects of highway ice-clearing treatments on corrosion of heavy vehicle materials and components.”, U.S. Dept. of Energy, Richland, WA.
Taylor, P., Verkade, J., Gopalakrishnan, K., Wadhwa, K., and Kim, S. (2010). “Development of an improved agricultural-based deicing product.”, Institute for Transportation, Iowa State Univ., Ames, IA.
Ye, Z., Veneziano, D., and Shi, X. (2013). “Estimating statewide benefits of winter maintenance operations.” Transp. Res. Rec., 2329, 17–23.
Zhang, J., Klasky, M., and Letellier, B. C. (2009). “The aluminum chemistry and corrosion in alkaline solutions.” J. Nucl. Mater., 384(2), 175–189.
Zhao, G., Lu, X., Xiang, J., and Han, Y. (2009). “Formation characteristic of CO2 corrosion product layer of P110 steel investigated by SEM and electrochemical techniques.” J. Iron Steel Res. Int., 16(4), 89–94.
Zhao, G. X., Zheng, M., Lv, X. H., Dong, X. H., and Li, H. L. (2005). “Effect of temperature on anodic behavior of 13Cr martensitic steel in CO2 environment.” Met. Mater. Int., 11(2), 135–140.
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© 2016 American Society of Civil Engineers.
History
Received: Jan 30, 2016
Accepted: Jun 22, 2016
Published online: Aug 8, 2016
Published in print: Jan 1, 2017
Discussion open until: Jan 8, 2017
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