Technical Papers
Jun 23, 2016

Compressive Strength and Microstructural Properties of Fly Ash–Based Geopolymer Concrete

Publication: Journal of Materials in Civil Engineering
Volume 28, Issue 12

Abstract

This study examines the role of alkali hydroxide and its concentration on the microstructure and compression strength of fly ash–based geopolymer concrete. Geopolymer is an innovative ceramic material, composed of long chains and networks of inorganic molecules, that is used as an alternative to conventional portland cement for civil infrastructure applications. Some of the advantages of geopolymer concrete are its fast setting time, rapid strength development, and its significantly reduced carbon footprint. In this study, aluminosilicate geopolymers with different alkaline solutions [NaOH, KOH, Ba (OH)2, and LiOH] were prepared by mixing Class C (9.42% CaO) and Class F-fly ash (1.29% CaO). The samples were cured under different experimental conditions and then tested for compressive strength. X-ray diffraction (XRD) and scanning electron microscopy/energy dispersive spectroscopy (SEM/EDS) have been used to identify the new phases formed in the geopolymeric matrix. The results revealed that microstructural properties of fly ash particles and calcium content have a significant effect on the setting time and the compressive strength of geopolymer concrete, and the structure of the formed geopolymer is typically glasslike. The early polymerization of geopolymer concrete is dependent on the concentration of the sodium hydroxide solution (NaOH). The exclusive use of NaOH showed the highest compressive strength when compared with other combinations of alkali hydroxides.

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References

ASTM. (2012). “Standard practice for capping cylindrical concrete specimens.” ASTM C617, West Conshohocken, PA.
ASTM. (2015). “Standard test method for compressive strength of cylindrical concrete specimens.” ASTM C39, West Conshohocken, PA.
Davidovits, J. (1991). “Geopolymers: Inorganic polymeric new materials.” J. Therm. Anal., 37(8), 1633–1656.
Davidovits, J. (1994). “Properties of geopolymer cements.” 1st Int. Conf. on Alkaline Cements and Concretes, Vol. 1, Geopolymer Institute, Saint Quentin, France, 131–149.
Davidovits, J. (1999). “Chemistry of geopolymeric systems, terminology.” Proc., 2nd Int. Conf. on Geopolymer’99, Geopolymer Institute, Saint Quentin, France, 9–22.
De Silva, P., and Sagoe-Crenstil, K. (2008). “Medium-term phase stability of Na2OAl2O3SiO2H2O geopolymer systems.” Cem. Concr. Res., 38(6), 870–876.
Diaz-Loya, E., Allouche, E. N., and Eklund, S. (2010). “Factors affecting the suitability of fly ash as source material for geopolymers.” Fuel, 89(5), 992–996.
Diaz-Loya, E., Allouche, E. N., and Vaidya, S. (2011). “Mechanical properties of fly-ash-based geopolymer concrete.” ACI Mater. J., 108(3), 300–306.
Duxson, P., Provis, J. L., Lukey, G. C., Mallicoat, S. W., Kriven, W. M., and Van Deventer, J. S. (2005). “Understanding the relationship between geopolymer composition, microstructure and mechanical properties.” Colloids Surf. A, 269(1), 47–58.
Fernandez-Jimenez, A., and Palomo, A. (2003). “Characterization of fly ashes: Potential reactivity as alkaline cements.” Fuel, 82(18), 2259–2265.
Fernandez-Jimenez, A. M., Palomo, A., and Lopez-Hombrados, C. (2006). “Engineering properties of alkali-activated fly ash concrete.” ACI Mater. J., 103(2), 106–112.
Hardjito, D., and Rangan, B. V. (2005). “Development and properties of low-calcium fly ash-based geopolymer concrete.”, Curtin Univ. of Technology, Perth, Australia.
Hardjito, D., Wallah, S. E., Sumajouw, D. M., and Rangan, B. V. (2004). “Factors influencing the compressive strength of fly ash-based geopolymer concrete.” Civ. Eng. Dimension, 6(2), 88–93.
Lee, W. K. W., and Van Deventer, J. S. J. (2002). “Structural reorganization of class F fly ash in alkaline silicate solutions.” Colloids and Surf. A, 211(1), 49–66.
Malhotra, V. M. (2002). “Introduction: Sustainable development and concrete technology.” ACI Concr. Int., 24(7), 22.
McCaffrey, R. (2002). “Climate change and the cement industry.” Global cement and lime magazine (environmental special issue), Global Cement, 15–19.
Naik, V., Mauzerall, D., Horowitz, L., Schwarzkopf, M. D., Ramaswamy, V., and Oppenheimer, M. (2005). “Net radiative forcing due to changes in regional emissions of tropospheric ozone precursors.” J. Geophys. Res., 110(D24).
Palacios, M., and Puertas, F. (2007). “Effect of shrinkage-reducing admixtures on the properties of alkali-activated slag mortars and pastes.” Cem. Concr. Res., 37(5), 691–702.
Palomo, A., Grutzeck, M. W., and Blanco, M. T. (1999). “Alkali-activated fly ashes a cement for the future.” Cem. Concr. Res., 29(8), 1323–1329.
Provis, J. L., Duxson, P., and van Deventer, J. S. J. (2010). “The role of particle technology in developing sustainable construction materials.” Adv. Powder Technol., 21(1), 2–7.
Provis, J. L., Duxson, P., Van Deventer, J. S. J., and Lukey, G. C. (2005). “The role of mathematical modeling and gel chemistry in advancing geopolymer technology.” Chem. Eng. Res. Des., 83(7), 853–860.
Provis, J. L., and van Deventer, J. S. J. (2007). “Geopolymerization kinetics in situ energy dispersive X-ray diffractometry.” Chem. Eng. Sci., 62(9), 2309–2317.
Sofi, M., Van Deventer, J. S. J., Mendis, P. A., and Lukey, G. C. (2007). “Engineering properties of inorganic polymer concretes (IPCs).” Cem. Concr. Res., 37(2), 251–257.
Torres-Carrasco, M., and Puertas, F. (2015). “Waste glass in the geopolymer preparation: Mechanical and microstructural characterization.” J. Cleaner Prod., 90, 397–408.
Van Jaarsveld, J. G. S., Van Deventer, J. S. J., and Lukey, G. C. (2002). “The effect of composition and temperature on the properties of fly ash- and kaolinite-based geopolymers.” Chem. Eng. J., 89(1), 63–73.
Van Jaarsveld, J. G. S., Van Deventer, J. S. J., and Lukey, G. C. (2003). “The characterization of source materials in fly ash-based geopolymers.” Mater. Lett., 57(7), 1272–1280.
Vijai, K., Kumutha, R., and Vishnuram, B. G. (2012). “Properties of glass fibre reinforced geopolymer concrete composites.” Asian J. Civ. Eng. (Build Hous), 13(4), 511–520.
Weil, M., Jeske, U., Dombrowski, K., and Buchwald, A. (2007). “Sustainable design of geopolymers-evaluation of raw materials by the integration of economic and environmental aspects in the early phases of material development.” Advances in life cycle engineering for sustainable manufacturing businesses, Springer, London, 279–283.

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Information

Published In

Go to Journal of Materials in Civil Engineering
Journal of Materials in Civil Engineering
Volume 28Issue 12December 2016

History

Received: Dec 10, 2015
Accepted: Mar 30, 2016
Published online: Jun 23, 2016
Discussion open until: Nov 23, 2016
Published in print: Dec 1, 2016

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Authors

Affiliations

Gaurav Nagalia [email protected]
Research Assistant, Dept. of Material Science and Engineering, Univ. of Texas at Arlington, Nedderman Hall 417, 416 Yates St., Arlington, TX 76019. E-mail: [email protected]
Yeonho Park, Ph.D., M.ASCE [email protected]
Postdoctoral Researcher, Dept. of Civil Engineering, Univ. of Texas at Arlington, Nedderman Hall 417, 416 Yates St., Arlington, TX 76019. E-mail: [email protected]
Ali Abolmaali, Ph.D., M.ASCE [email protected]
Professor, Dept. of Civil Engineering, Univ. of Texas at Arlington, Nedderman Hall 417, 416 Yates St., Arlington, TX 76019. E-mail: [email protected]
Pranesh Aswath, Ph.D. [email protected]
Professor, Dept. of Material Science and Engineering, Univ. of Texas at Arlington, Nedderman Hall 417, 416 Yates St., Arlington, TX 76019 (corresponding author). E-mail: [email protected]

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