Technical Papers
Dec 22, 2015

Sorption and Photocatalytic Degradation of Trichlorfon by Foam Concrete Blended with Nitrogen-Doped Titanium Dioxide

Publication: Journal of Materials in Civil Engineering
Volume 28, Issue 5

Abstract

Foam concrete incorporated with nitrogen-doped TiO2 (N-TiO2/FC) was fabricated, characterized, and tested for the sorption and degradation of trichlorfon. The removal performance of trichlorfon under visible-light irradiation by using this concrete was compared with that using pure foam concrete (FC) and foam concrete incorporated with TiO2 (TiO2/FC). Factors including the amount of photocatalysts and curing age were investigated. The N-TiO2/FC exhibited a higher removal efficiency of trichlorfon but a lower sorption than FC and TiO2/FC. The sorption and photocatalytic activity decreased with curing age and the amount of incorporated nanoparticles. Seventy-five percent of 20mg/L trichlorfon was absorbed by N-TiO2/FC (6% incorporation and 1-day curing) in 540 min, and 19% of the sorbed trichlorfon was degraded in 180 min with a compressive strength of 4.9 MPa. The FC could absorb nearly 83% of trichlorfon in 540 min but degrade less than 1% in 180 min. Moreover, 6% N-TiO2/FC exhibited the best performance (removed almost 100% of trichlorfon in 2 weeks) in pilot-scale experiments, indicating its potential use in nonpoint pollution control.

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Acknowledgments

The study was financially supported by the National Natural Science Foundation of China (No. 51322901) and the Fundamental Research Funds for the Central Universities (No. 2014B02914). The research fund was provided by the National Basic Research Program of China (973 Program, No. 2010CB429006).

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Go to Journal of Materials in Civil Engineering
Journal of Materials in Civil Engineering
Volume 28Issue 5May 2016

History

Received: Sep 2, 2014
Accepted: Oct 14, 2015
Published online: Dec 22, 2015
Published in print: May 1, 2016
Discussion open until: May 22, 2016

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Professor, College of Environment, Hohai Univ., 1 Xikang Rd., Nanjing 210098, P.R. China. E-mail: [email protected]
Graduate Research Assistant, College of Environment, Hohai Univ., 1 Xikang Rd., Nanjing 210098, P.R. China. E-mail: [email protected]
Graduate Research Assistant, College of Environment, Hohai Univ., 1 Xikang Rd., Nanjing 210098, P.R. China. E-mail: [email protected]
Dawei Wang, Ph.D. [email protected]
Director, College of Environment, Hohai Univ., 1 Xikang Rd., Nanjing 210098, P.R. China (corresponding author). E-mail: [email protected]
Wenlong Zhang, Ph.D. [email protected]
Professor, College of Environment, Hohai Univ., 1 Xikang Rd., Nanjing 210098, P.R. China. E-mail: [email protected]
Qing Wang, Ph.D. [email protected]
Professor, College of Environment, Hohai Univ., 1 Xikang Rd., Nanjing 210098, P.R. China. E-mail: [email protected]

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