Technical Papers
Jan 8, 2016

Protection against Weathering Using Micronized Copper Quat and Heat Treatment Methods on Wood for Construction of Mountain Houses

Publication: Journal of Materials in Civil Engineering
Volume 28, Issue 6

Abstract

During this study, the protective effects of heat treatment and micronized copper quat (MCQ) impregnation on wooden surfaces in outdoor conditions were observed. Within the scope of the study, the 15-month weathering test effects on the Uzungöl and Hıdırnebi plateaus on oriental beech (Fagus orientalis L.) and Scots pine (Pinus sylvestris L.) wooden materials were studied. Changes of color, roughness, and visual-macroscopic values were compared on wooden surfaces that were subjected to weathering tests. Changes in the chemical properties of exposed surfaces were investigated with Fourier transform infrared (FTIR) spectroscopy. The presented data have clearly shown that the MCQ and heat treatment methods increased the stabilization of color and have slowed down the physical and chemical degradation on the wood surface under outdoor conditions. Moreover, the best protection methods against weathering were found to be heat treatment of Scots pine and MCQ impregnation of oriental beech.

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Acknowledgments

The authors would like to thank Karadeniz Technical University, Research Fund (Project No. 2009.113.002.1), for support provided in Turkey.

References

ASTM. (1993). “Standard method for evaluating degree of erosion of exterior paints.”, West Conshohocken, PA.
AWPA (American Wood Protection Association). (2009). “All timber products-preservative treatment by pressure processes.” AWPA U1, Birmingham, AL.
Ayadi, N., Lejeune, F., Charrier, F., Charrier, B., and Merlin, A. (2003). “Color stability of heat-treated wood during artificial weathering.” HolzalsRoh- und Werkstoff, 61(3), 221–226.
CEN (European Committee for Standardization). (2007). “Paints and varnishes-coating materials and coating systems for exterior—Part 3: Natural weathering test.” EN 927–3, Brussels, Belgium.
Colom, X., Carrillo, F., Nogués, F., and Garriga, P. (2003). “Structural analysis of photodegraded wood by means of FTIR spectroscopy.” Polym. Degrad. Stab., 80(3), 543–549.
Deka, M., Humar, M., Rep, G., Kričej, B., Šentjurc, M., and Petrič, M. (2008). “Photo-degradation of water borne acrylic coated modified and non-modified wood during artificial light exposure.” Wood Sci. Technol., 42(1), 5–20.
DIN. (1990). “Determination of values surface roughness parameters Ra, Rb, Rmax using electrical contact (stylus) institute.”, Berlin.
Dubey, M. K., Pang, S., and Walker, J. (2010). “Color and dimensional stability of oil heat-treated pine wood after accelerated UV weathering.” Forest Prod. J., 60(5), 453–459.
Evans, P. D., Wallis, A. F. A., and Owen, N. L. (2000). “Weathering of chemically modified wood surfaces.” Wood Sci. Technol., 34(2), 151–165.
Feist, W. C., and Hon, D. N.-S. (1984). “Chemistry of weathering and protection.” Chapter 11, Chemistry of solid wood, advances in chemistry series 207,, American Chemical Society, Washington, DC.
Gralier, S., Castellan, A., and Kamdem, D. P. (2000). “Photoprotection of copper-amine treated pine.” Wood Fiber Sci., 32(2), 196–202.
Huang, X., Kocaefe, D., Kocaefe, Y., Boluk, Y., and Krause, C. (2013). “Structural analysis of heat-treated birch (Betula papyrifera) surface during artificial weathering.” Appl. Surf. Sci., 264, 117–127.
Humar, M., Pavlič, M., Žlindra, D., Tomažič, M., and Petrič, M. (2011). “Performance of waterborne acrylic surface coatings on wood ımpregnated with Cu-ethanolamine preservatives.” Bull. Mater. Sci., 34(1), 113–119.
ISO (International Organization for Standardization). (1984). “Paints and varnishes—Colorimetry.”, Geneva.
Jin, L., Archer, K., and Preston, A. (1991). “Surface characteristics of wood treated with various AAC, ACQ and CCA formulations after weathering.” Proc., 22 Int. Research Group on Wood Protection, Kyoto, Japan.
Kapaca, E., Cirule, D., Grinins, J., Bikovens, O., and ve Andersons, B. (2011). “Chemical changes of untreated and hydrothermally modified hardwood after artificial weathering.” Proc., 7th Meeting of the Nordic-Baltic Network in Wood Material Science and Engineering (WSE), Oslo, Norway, 37–42.
Kocaefe, D., Poncsak, S., and Boluk, Y. (2008). “Effect of heat treatment on the chemical composition and mechanical properties of birch and aspen.” BioResources, 3(2), 517–537.
Korkut, D. S., Hiziroglu, S., and Aytin, A. (2013). “Effect of heat treatment on surface characteristics of wild cherry wood.” BioResources, 8(2), 1582–1590.
Moore, A. K., and Owen, N. L. (2001). “Infrared spectroscopy studies of solid wood.” Appl. Spectrosc. Rev., 36(1), 65–86.
Nuopponen, M., Wikberg, H., Vuorinen, T., Maunu, S. L., Jämsä, S., and Viitaniemi, P. (2004). “Heat-treated softwood exposed to weathering.” Appl. Poly. Sci., 91(4), 2128–2134.
Ozgenc, O., Hiziroglu, S., and Yıldız, U. C. (2012). “Weathering properties of wood species treated with different coating applications.” BioResources, 7(4), 4875–4888.
Ozgenc, O., Okan, O. T., Yıldız, U. C., and Deniz, I. (2013). “Wood surface protection against artificial weathering with vegetable seed oils.” BioResources, 8(4), 6242–6262.
Ozgenc, O., and Yildiz, U. C. (2014). “Surface characteristics of wood treated with new generation preservatives after artificial weathering.” Wood Res., 59(4), 605–616.
Özgenç, Ö. (2014). “Increasing resistance of wooden materials used in mountain houses of eastern Black Sea region to weather conditions.” Ph.D. thesis, Karadeniz Technical Univ., Trabzon, Turkey.
Pandey, K. K., and Pitman, A. J. (2003). “FTIR studies of the changes in wood chemistry following decay by brown-rot and white-rot fungi.” Int. Biodeteroir. Biodegrad., 52(3), 151–160.
Rüther, P. (2011). “Wood weathering from a service life perspective.” Ph.D. thesis, Norwegian Univ. of Science and Technology, Trondheim, Norway.
Saha, S., Kocaefe, D., Boluk, Y., and Pichette, A. (2013). “Surface degradation of CeO2 stabilized acrylic polyurethane coated heatly treated Jack pine during accelerated weathering.” Appl. Surf. Sci., 276, 86–94.
Schnabel, T., Zimmer, B., and Petutschnig, A. J. (2009). “On the modelling of colour changes of wood surfaces.” Eur. J. Wood Prod., 67(2), 141–149.
Teacă, C.-A., Roşu, D., Bodîrlău, R., and Roşu, L. (2012). “Structural changes in wood under artificial UV light irradiation determined by FTIR spectroscopy and color measurements—A brief review.” BioResources, 8(1), 1478–1507.
Temiz, A., Eikenes, M., Yıldız, Ü. C., Evans, F. G., and Jacobsen, B. (2003). “Accelerated weathering test for the evaluation of wood preservative efficacy.” Proc., 34 Int. Research Group on Wood Protection, Brisbane, Australia.
Temiz, A., Terziev, N., Eikenes, M., and Hafren, J. (2007). “Effect of accelerated weathering on surface chemistry of modified wood.” Appl. Surf. Sci., 253(12), 5355–5362.
Temiz, A., Terziev, N., Jacobsen, B., and ve Eikenes, M. (2006). “Weathering, water absorption, and durability of silicon, acetylated, and heat-treated wood.” Appl. Poly. Sci., 102(5), 4506–4513.
Temiz, A., Yıldız, U. C., Aydin, I., Eikenes, M., Alfredsen, G., and Çolakoğlu, G. (2005). “Surface roughness and color characteristics of wood treated with preservatives after accelerated weathering test.” Appl. Surf. Sci., 250(1–4), 35–42.
Tuong, V. M., and ve Li, J. (2010). “Effect of heat treatment on the change in color and dimensional stability of acacia hybrid wood.” BioResources, 5(2), 1257–1267.
Volkmer, T., Arietan, L., Plummer, C., Strautmann, J., and Noël, M. (2013). “Loss of tensile strength in cellulose tissue on the surface of spruce (Picea abies) cuased by natural photodegradation and delignification.” Polym. Degrad. Stab., 98(6), 1118–1125.
Williams, R. S. (2005). “Weathering of wood.” Chapter 7, Handbook of wood chemistry and wood composites, Taylor & Francis, New York.
Williams, R. S., Knaebe, P., Sotos, P. G., and Feist, W. C. (2001a). “Erosion rates of wood during natural weathering. Part I. Effects of grain angle and surface texture.” Wood Fiber Sci., 33(1), 31–42.
Williams, R. S., Knaebe, P., Sotos, P. G., and Feist, W. C. (2001b). “Erosion rates of wood during natural weathering. Part II. Earlywood and latewood erosion rates.” Wood Fiber Sci., 33(1), 43–49.
Yalınkılıç, M. K., Imamura, Y., Takahashi, M., Demirci, Z., Yalınkılıç, A. C., and Peker, H. (1999). “FTIR studies of the effects of outdoor exposure on varnish-coated wood pretreated with CCB or water repellents.” J. Wood Sci., 45(6), 502–514.
Yıldız, S., and Gümüşkaya, E. (2007). “The effects of heat modification on crystalline structure of cellulose in soft and hardwood.” Build. Environ., 42(1), 62–67.
Yıldız, S., Tomak, E. D., Yıldız, U. C., and Ustaömer, D. (2013). “Effect of artificial weathering on the properties of heat treated wood.” Polym. Degrad. Stab., 98(8), 1419–1427.
Yıldız, S., Yıldız, U. C., and Tomak, E. D. (2011). “The effects of natural weathering on the properties of heat-treated alder wood.” BioResources, 6(3), 2501–2504.
Zhang, J., Kamdem, D. P., and Temiz, A. (2009). “Weathering of copper-amine treated wood.” Appl. Surf. Sci., 256(3), 842–846.

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Go to Journal of Materials in Civil Engineering
Journal of Materials in Civil Engineering
Volume 28Issue 6June 2016

History

Received: Mar 10, 2015
Accepted: Oct 13, 2015
Published online: Jan 8, 2016
Published in print: Jun 1, 2016
Discussion open until: Jun 8, 2016

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Authors

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Ozlem Ozgenc [email protected]
Assistant Professor, Dept. of Forest Industry Engineering, Faculty of Forestry, Karadeniz Technical Univ., Trabzon 61080, Turkey (corresponding author). E-mail: [email protected]
Umit C. Yildiz [email protected]
Professor, Dept. of Forest Industry Engineering, Faculty of Forestry, Karadeniz Technical Univ., Trabzon 61080, Turkey. E-mail: [email protected]

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