Technical Papers
Nov 6, 2015

Effectiveness of Products in Managing Metallic Corrosion Induced by Cyclic Deicer Exposure: Laboratory Study Using Multielectrode Array Sensors, Electrochemical Impedance, and Laser Profilometer

Publication: Journal of Materials in Civil Engineering
Volume 28, Issue 5

Abstract

A total of 12 multielectrode array sensors were utilized to assess the individual effectiveness of two corrosion inhibitors and one coating under cyclic deicer exposure conditions. There were four sensor groups, and each group consisted of nine-pin probes that were fabricated from 1008 carbon steel, 304 stainless steel, and 1100 aluminum, respectively. A total of two environmental exposure tests were conducted, in which 2.3% NaCl and 3.0% MgCl2 solutions were used as salt, respectively. The two tests each included eight environmental cycles and with 24 h per cycle. For all the exposed sensors, the most severe corrosion occurred at the beginning of the humidity stage. For sensors in the control group, MgCl2 exhibited a corrosion attack throughout the exposure period, whereas NaCl only exhibited an apparent corrosion attack during the humidity stage. Both the sensor corrosion rates and mass loss results indicate that the inhibitors had a much greater effect for MgCl2 than for NaCl. Although the coating showed significant benefits in protecting the metallic substrates, the cyclic exposure to MgCl2 led to greater coating deterioration than did NaCl. For validation, impedance measurements were conducted on carbon steel panels subjected to similar exposures, and three-dimensional laser profilometer scans were performed to characterize their surface morphology after the exposures.

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Acknowledgments

The research reported herein was financially supported by the Washington Department of Transportation (WSDOT) as well as the Research & Innovative Technology Administration (RITA) at the U.S. Department of Transportation (USDOT) through the Alaska University Transportation Center (AUTC) and Western Transportation Institute. The authors thank all the professionals who provided products for testing and Yan Zhang for his assistance in the laboratory testing. The authors also acknowledge the funding support by the ChuTian Scholar Visiting Professorship Fund provided by the Hubei Department of Education to Wuhan Polytechnic University. The authors neither declare any conflict of interest nor endorse any product or test protocol. The brand names were mentioned for the convenience of the reader only, and the findings are constrained to the investigated conditions and should not be generalized.

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Go to Journal of Materials in Civil Engineering
Journal of Materials in Civil Engineering
Volume 28Issue 5May 2016

History

Received: Dec 22, 2014
Accepted: Aug 11, 2015
Published online: Nov 6, 2015
Discussion open until: Apr 6, 2016
Published in print: May 1, 2016

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Authors

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Associate Professor, Wuhan Polytechnic Univ., School of Civil Engineering and Architecture, Wuhan, Hubei 430023, China. E-mail: [email protected]
Hui Yu, Ph.D. [email protected]
Research Engineer, Wood Group Mustang, Inc., 16001 Park 10 Place, Houston, TX 77084. E-mail: [email protected]
Xianming Shi, Ph.D., M.ASCE [email protected]
P.E.
Associate Professor, Laboratory of Advanced and Sustainable Cementitious Materials, Dept. of Civil and Environmental Engineering, Washington State Univ., Sloan 101, P.O. Box 642910, Pullman, WA 99164-2910 (corresponding author). E-mail: [email protected]

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