Technical Papers
Dec 3, 2014

Effects of Regular-Sized and Nanosized Hydrated Lime on Binder Rheology and Surface Free Energy of Adhesion of Foamed Warm Mix Asphalt

Publication: Journal of Materials in Civil Engineering
Volume 27, Issue 9

Abstract

Although foamed warm mix asphalt (WMA) offers many potential benefits, there are some performance concerns. Researchers are making efforts to study the usage of different additives as modifiers to meet standard specifications of asphalt mixes for paving applications; however, selection of an appropriate modifier is extremely important to better performing asphalt. In recent years, there has been a dramatic interest in research, technology, and production of nanoparticles (nanomaterials). The current study was conducted with the objective of addressing the potential benefits of using nanosized hydrated lime (NHL) compared with regular-sized hydrated lime (RHL) as a modifier to the WMA produced using an additive. This paper documents the findings of the effect of NHL and RHL on the asphalt binder rheology and provides an insight into their effect on the free energy of adhesion of the asphalt binder–aggregate system. The rheology of asphalt binder was investigated based on the dynamic shear rheometer (DSR) test, whereas the free energy of adhesion was quantified based on the surface free energy (SFE) measurements of the asphalt binders and aggregate. Rheology results showed that the addition of NHL in smaller amounts can provide improved characteristics as compared with RHL. In concurrence with the rheology results, the free energy of adhesion showed that the NHL is more competitive compared with the RHL. Foaming the asphalt binder adversely affects the asphalt binder-to-aggregate adhesion.

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Acknowledgments

This material is based in part on work supported by the National Science Foundation under project 1300286. Any opinions, findings, conclusions, or recommendations expressed in this material are those of the authors and do not necessarily reflect the views of the National Science Foundation. We would also like to acknowledge funding for conducting the USD testing from the University of Oklahoma Research Council and the Oklahoma Department of Transportation. Moreover, we would like to acknowledge funding from State of Michigan—Research Excellence Fund for this study.

References

AASHTO. (2011). “Standard method of test for determining the rheological properties of asphalt binder using a dynamic shear rheometer (DSR).”, Washington, DC.
Adamson, A. W., and Gast, A. P. (1997). Physical chemistry of surfaces, 6th Ed., Wiley, New York, 18–40.
Antonietti, M., and Ozin, G. A. (2004). “Promises and problems of mesoscale materials chemistry or why meso?” Chem. Eur. J., 10(1), 28–41.
Barnes, H. A., and Hutton, J. F. (1989). An introduction to rheology, Vol. 3, Elsevier Science Publishers, Amsterdam, Netherlands.
Bhasin, A., Masad, E., Little, D., and Lytton, R. (2006). “Limits of adhesive bond energy for improved resistance to hot mix asphalt to moisture damage.”, Transportation Research Board, Washington, DC, 3–13.
Blazek, J., Sebor, G., Maxa, D., Ajib, M., and Paniagua, H. (2000). “Effect of hydrated lime addition on properties of asphalt.” Pet. Coal, 42(1), 41–45.
Cheng, D. (2002). “Surface free energy of asphalt aggregate system and performance analysis of asphalt concrete based on surface free energy.” Ph.D. thesis, Texas A&M Univ., College Station, TX.
Cheng, D. X., Little, D. N., Lytton, R. L., and Holste, J. C. (2002). “Use of surface free energy properties of the asphalt-aggregate system to predict damage potential.” J. Assoc. Asphalt Paving Technol., 71, 59–88.
Cheng, J., Shen, J., and Xiao, F. (2011). “Moisture susceptibility of warm-mix asphalt mixtures containing nanosized hydrated lime.” J. Mater. Civ. Eng., 1552–1559.
D’Angelo, J., et al. (2008). “Warm mix asphalt: European practice.”, Federal Highway Administration, 68.
Diab, A., and You, Z. (2013). “Rheological properties of short-term aged foamed asphalt modified with nano hydrated lime.” Int. Conf. on Materials Architecture and Engineering Technology (ICMAET), Beijing.
Diab, A., and You, Z. (2014). “Moisture susceptibility of nano-sized hydrated lime modified foamed warm mix asphalt mixes.” Int. Society for Asphalt Pavements (ISAP), CRC Press, Boca Raton, FL, 1735–1745.
Diab, A., You, Z., Othman, A. M., and Ahmed, H. Y. (2012). “Fatigue characteristics of hydrated lime modified HMA.” Int. J. Pavement Res. Technol., 6(1), 31–36.
Diab, A., You, Z., and Wang, H. (2013a). “Rheology of aged foamed warm mix asphalt modified with nano-sized hydrated lime.” 13th COTA Int. Conf. of Transportation Professionals (CICTP 2013), ASCE, Reston, VA.
Diab, A., You, Z., and Wang, H. (2013b). “Using modified creep and recovery tests to evaluate the foam-based warm mix asphalt contained nano hydrated lime.” Adv. Mater. Res., 646, 90–96.
Fromm, H. J. (1974). “The mechanisms of asphalt stripping from aggregates surfaces.” Proc., Association of Asphalt Paving Technologists, Vol. 43, Association of Asphalt Paving Technologists, Lino Lakes, MN, 191–223.
Ghabchi, R., Singh, D., Zaman, M., and Tian, Q. (2013). “Mechanistic evaluation of the effect of WMA additives on wettability and moisture susceptibility properties of asphalt mixes.” J. Test. Eval., 41(6), 933–942.
Goh, S. W., and You, Z. (2008). “Resilient modulus and dynamic modulus of warm mix asphalt.” GeoCongress 2008, Geosustainability and Geohazard Mitigation, ASCE, Reston, VA, 1000–1007.
Goh, S. W., and You, Z. (2012). “Mechanical properties of porous asphalt pavement materials with warm mix asphalt and RAP.” J. Transp. Eng., 90–97.
Good, R. J. (1992). “Contact-angle, wetting, and adhesion: A critical review.” J. Adhes. Sci. Technol., 6(12), 1269–1302.
Hefer, A. W. (2004). “Adhesion in bitumen-aggregate systems and quantification of the effects of water on the adhesive bond.” Ph.D. dissertation, Texas A&M Univ., College Station, TX.
Hielscher, T. (2005). “Ultrasonic production of nano-size dispersions and emulsions.” 1st Workshop on Nanotechnology Transfer ENS, Paris, 14–16.
Hossain, Z., Bhudhala, A., Zaman, M. M., O’Rear, E., Cross, S., and Lewis, S. (2009). “Evaluation of the use of warm mix asphalt as a viable paving material in the United States (Cooperative Agreement: DTFH61-06-H-00044: Task 3).” Federal Highway Administration.
Huang, S. C., and Zeng, M. L. (2007). “Characterization of aging effect on rheological properties of asphalt-filler systems.” Int. J. Pavement Eng., 8(3), 213–223.
Hurley, G. C., et al. (2006). Evaluation of potential processes for use in warm mix asphalt, Association of Asphalt Paving Technologist, White Bear Lake, MN, 41–90.
Ishai, I., and Craus, J. (1977). “Effect of the filler on aggregate-bitumen adhesion properties in bituminous mixtures.” J. Assoc. Asphalt Paving Technol., 43, 228–258.
James, R. (1965). “Metering of steam-water two-phase flow by sharp-edged orifices.” Proc. Inst. Mech. Eng., 549–572.
Jamshidi, A., Hamzah, M. O., and You, Z. (2013). “Performance of warm mix asphalt containing Sasobit®: State-of-the-art.” Constr. Build. Mater., 38, 530–553.
Johansson, L. S. (1998). “Bitumen aging and hydrated lime.”, Royal Institute of Technology, Stockholm, Sweden.
Lai, B., Barros, C., and Yin, H. M. (2009). “Investigation of rheological behavior of asphalt binder modified by the Advera® additive.” 4th Biot Conf. on Poromechanics, New York, 487–492.
Larsen, J. W., Green, T. K., and Kovacn, J. (1985). “The nature of the macromolecular network structure of bituminous coals.” J. Org. Chem., 50(24), 4729–4735.
Lesueur, D., Little, D. N., and Epps, J. A. (1998). “Effect of hydrated lime on the rheology, fracture and aging of bitumen and asphalt mixtures.” Lhoist HMA Symp., Dusseldorf, Germany.
Li, W. (1997). “The measurement of surface free energy for aggregates SHAP RB.”.
Little, D. N., and Epps, J. (2001). “The benefits of hydrated lime in hot mix asphalt.” National Lime Association, Arlington, VA.
Little, D. N., Lytton, R. L., Williams, A. D., and Chen, C. W. (2001). “Microdamage healing in asphalt and asphalt concrete, vol I: Microdamage and microdamage healing.”, Texas Transportation Institution, College Station, TX.
Lytton, R. L., Masad, E. A., Zollinger, C., Bulut, R., and Little, D. (2005). “Measurements of surface energy and its relationship to moisture damage.”, Texas Transportation Institute, College Station, TX.
Miura, K., Mae, K., Li, W., and Kusakaw, T. (2001). “Estimation of hydrogen bond distribution in coal through the analysis of OH stretching bands in diffuse reflectance infrared spectrum measured by in-situ technique.” Energy & Fuels, 15(3), 599–610.
Petersen, J. C. (1967). “An infrared study of hydrogen bonding in asphalt.” Fuel, 46, 295.
Petersen, J. C., Ensley, E. K., and Barbour, F. A. (1974). “Molecular interactions of asphalt in the asphalt-aggregate interface region.”, Transportation Research Board, National Research Council, Washington, DC, 67–78.
Peterson, J. C. (1987). “Lime treatment of asphalt to reduce age hardening and improve flow properties.” Annul Meeting of AAPT, Reno, NV, 23–25.
Saleh, F. M. (2007). “Effect of rheology on the bitumen foam-ability and mechanical properties of foam bitumen stabilised mixes.” Int. J. Pavement Eng., 8(2), 99–110.
Sebaaly, P. E., Hilty, E., and Weizel, D. (2001). “Effectiveness of lime in hot mix asphalt pavement.” Univ. of Nevada, Reno, 〈http://www.wrscunt.edu/WRSCMoisture_files/repor.pdf〉 (Jan. 2014).
Shen, J., Huang, B., Shu, X., and Tang, B. (2010). “Influence of nano-sized hydrated lime (HL) on selected properties of hot-mix asphalt (HMA).” Int. J. Pavement Res. Technol., 4(4), 252–257.
van Oss, C. J., Chaudhury, M. K., and Good, R. J. (1988). “Interfacial lifshitz–van der waals and polar interactions in macroscopic systems.” Chem. Rev., 88(6), 927–941.
Wasiuddin, N. M., Selvamohan, S., Zaman, M. M., and Guegan, M. L. T. A. (2007a). “A comparative laboratory study of Sasobit® and Aspha-min® in warm-mix asphalt.” 86th Annual Meeting Transportation Research Board, Washington, DC.
Wasiuddin, N. M., Zaman, M. M., and O’Rear, E. A. (2007b). “Effect of polymeric aggregate treatment using styrene-butadiene rubber (SBR) for moisture-induced damage potential.” 86th Annual Meeting Transportation Research Board, Washington, DC.
Wasiuddin, N. M., Zaman, M. M., and O’Rear, E. A. (2008). “Effect of sasobit and asphamin on wettability and adhesion between asphalt binders and aggregates.” Transportation Research Board, Washington, DC.
Williams, M. L., Landel, R. F., and Ferry, J. D. (1955). “The temperature dependence of relaxation mechanism in amorphous polymers and other glass forming liquids.” J. ACS, 77(14), 3701–3707.
Zeng, M. L., and Huang, S. C. (2006). “Characterizing the asphalt-aggregate mixtures using rheological properties of asphalt binders.” J. Test. Eval., 34(6), 471–476.

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Go to Journal of Materials in Civil Engineering
Journal of Materials in Civil Engineering
Volume 27Issue 9September 2015

History

Received: May 9, 2014
Accepted: Oct 20, 2014
Published online: Dec 3, 2014
Discussion open until: May 3, 2015
Published in print: Sep 1, 2015

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Authors

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Aboelkasim Diab, Ph.D.
Assistant Professor, Dept. of Civil Engineering, Aswan Univ., 81542, Egypt; formerly, Research Assistant, Civil and Environmental Engineering, Michigan Technological Univ., 1400 Townsend Dr., Houghton, MI 49931.
Zhanping You, Ph.D., P.E., M.ASCE [email protected]
Professor, Dept. of Civil and Environmental Engineering, Michigan Technological Univ., 1400 Townsend Dr., Houghton, MI 49931-1295 (corresponding author). E-mail: [email protected]
Rouzbeh Ghabchi, Ph.D.
Research Fellow, School of Civil Engineering and Environmental Science, Univ. of Oklahoma, 202 West Boyd St., Room 334, Norman, OK 73019.
Musharraf Zaman, Ph.D., P.E., F.ASCE
Professor, School of Civil Engineering and Environmental Science, Univ. of Oklahoma, 202 West Boyd St., Room 334, Norman, OK 73019.

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