Technical Papers
Oct 15, 2014

Chloride Penetration Prediction in Concrete through an Empirical Model Based on Constant Flux Diffusion

Publication: Journal of Materials in Civil Engineering
Volume 27, Issue 8

Abstract

An empirical model based on constant flux is presented for chloride transport through concrete in atmospherical exposure conditions. A continuous supply of chlorides is assumed as a constant mass flux at the exposed concrete surface. The model is applied to experimental chloride profiles obtained from a real marine structure, and results are compared with the classical error-function model. The proposed model shows some advantages. It yields a better predictive capacity than the classical error-function model. The previously observed chloride surface concentration increases are compatible with the proposed model. Nevertheless, the predictive capacity of the model can fail if the concrete microstructure changes with time. The model seems to be appropriate for well-maturated concretes exposed to a marine environment in atmospherical conditions.

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Acknowledgments

We dedicate this work to the memory of our late colleague and friend Dr. Estanislao (Tanis) Viqueira, who passed away a few days after the acceptance of this article for publication. The authors thank the Ministerio de Economía y Competitividad of Spain and Fondo Europeo de Desarrollo Regional (FEDER) for the funding received for this research through project BIA2010-20548. M. P. López is grateful for a fellowship with the Formación Personal Investigador (FPI) program (reference BES-2011-046401).

References

ACI Committee 365. (2000). “Service-life prediction: State-of-the-art report.” American Concrete Institute, Farmington Hills, MI.
ACI Committee 365. (2009). “Life-365 service life prediction model and computer program for predicting the service life and life-cycle cost of reinforced concrete exposed to chlorides, version 2.0.1.” American Concrete Institute, Farmington Hills, MI.
Andrade, C., Tavares, F., Castellote, M., Petre-Lazar, I., Climent, M. A., and de Vera, G. (2006). “Comparison of chloride models: The importance of surface concentration.” Proc., 2nd Int. Symp. on “Advances in Concrete through Science and Engineering.” Quebec City Canada, J. Marchand, B. Bissonnette, R. Gagné, M. Jolin, and F. Paradis, eds., RILEM Publications pro051, Bagneux, France, 227–242.
Ann, K. Y., Ahn, J. H., and Ryou, J. S. (2009). “The importance of chloride content at the concrete surface in assessing the time to corrosion of steel in concrete structures.” Constr. Build. Mater., 23(1), 239–245.
ASTM. (1994). “Standard test method for specific gravity, absorption, and voids in hardened concrete.”, West Conshohocken, PA.
ASTM. (1996). “Standard test method for determining atmospheric chloride deposition rate by wet candle method.”, West Conshohocken, PA.
Bamforth, P. B. (1999). “The derivation of input data for modelling chloride ingress from eight-year UK coastal exposure trials.” Mag. Concr. Res., 51(2), 87–96.
Baroghel-Bouny, V., Thiéry, M., and Wang, X. (2011). “Modelling of isothermal coupled moisture-ion transport in cementitious materials.” Cem. Concr. Res., 41(8), 828–841.
Cheung, M., Zhao, J., and Chan, Y. (2009). “Service life prediction of RC bridge structures exposed to chloride environments.” J. Bridge Eng., 164–178.
Chinchón, S., García, J., López Atalaya, M., Linares, A., and Vera, R. (2004). “Cement paste colouring in concretes.” Cem. Concr. Res., 34(11), 1987–1991.
Climent, M. A., de Vera, G., López, J. F., Viqueira, E., and Andrade, C. (2002). “A test method for measuring chloride diffusion coefficients through nonsaturated concrete. Part I: The instantaneous plane source diffusion case.” Cem. Concr. Res., 32(7), 1113–1123.
Climent, M. A., de Vera, G., Viqueira, E., and López, M. M. (2004). “Generalization of the possibility of eliminating the filtration step in the determination of acid-soluble chloride content in cement and concrete by potentiometric titration.” Cem. Concr. Res., 34(12), 2291–2295.
Climent, M. A., Viqueira, E., de Vera, G., and López Atalaya, M. M. (1999). “Analysis of acid-soluble chloride in cement, mortar and concrete by potentiometric titration without filtration steps.” Cem. Concr. Res., 29(6), 893–898.
Costa, A., and Appleton, J. (1999a). “Chloride penetration into concrete in marine environment. Part I: Main parameters affecting chloride penetration.” Mater. Struct., 32(4), 252–259.
Costa, A., and Appleton, J. (1999b). “Chloride penetration into concrete in marine environment. Part II: Prediction of long term chloride penetration.” Mater. Struct., 32(5), 354–359.
de Vera, G., Climent, M. A., Viqueira, E., Antón, C., and Andrade, C. (2007). “A test method for measuring chloride diffusion coefficients through partially saturated concrete. Part II: The instantaneous plane source diffusion case with chloride binding consideration.” Cem. Concr. Res., 37(5), 714–724.
Guzmán, S., Gálvez, J. C., and Sancho, J. M. (2011). “Cover cracking of reinforced concrete due to rebar corrosion induced by chloride penetration.” Cem. Concr. Res., 41(8), 893–902.
Kropp, J. (1995). “Chlorides in concrete.” Performance criteria for concrete durability, J. Kropp and H. K. Hilsdorf, eds., E & FN Spon, London, 138–164.
Lee, J. S., and Moon, H. Y. (2006). “Salinity distribution of seashore concrete structures in Korea.” Build. Environ., 41(10), 1447–1453.
Marchand, J. (2001). “Modeling the behavior of unsaturated cement systems exposed to aggressive chemical environments.” Mater. Struct., 34(4), 195–200.
Martín-Pérez, B., Pantazapoulou, S. J., and Thomas, M. D. A. (2001). “Numerical solution of mass transport equations in concrete structures.” Comput. Struct., 79(13), 1251–1264.
MATLAB 6.1 [Computer software]. Natick, MA, Mathworks.
Meijers, S. J. H., Bijen, J. M. J. M., de Borst, R., and Fraaij, A. L. A. (2005). “Computational results of a model for chloride ingress in concrete including convection, drying-wetting cycles and carbonation.” Mater. Struct., 38(2), 145–154.
Meira, G. R., Andrade, C., Padaratz, I. J., Alonso, C., and Borba, J. C., Jr. (2007). “Chloride penetration into concrete structures in the marine atmosphere zone—Relationship between deposition of chlorides on the wet candle and chlorides accumulated into concrete.” Cem. Concr. Compos., 29(9), 667–676.
Ministry of Development. (2008). “Structural concrete code EHE-08.” Madrid, Spain (in Spanish).
MOPU. (1975). “Royal Decree 1964/1975: Specification of general technique requirements for the reception of cement (RC-75).” State Official Bulletin (BOE), Ministry of Construction and Urban Development, Madrid, Spain (in Spanish).
MOPU. (1982). “Royal Decree 2252/1982: Instruction for the design and execution of works of mass or reinforced concrete (EH-82).” State Official Bulletin (BOE), Ministry of Construction and Urban Development, Madrid, Spain (in Spanish).
Nguyen, T. Q., Petković, J., Dangla, P., and Baroghel-Bouny, V. (2008). “Modelling of coupled ion and moisture transport in porous building materials.” Constr. Build. Mater., 22(11), 2185–2195.
Saetta, A. V., Scotta, R. V., and Vitaliani, R. V. (1993). “Analysis of chloride diffusion into partially saturated concrete.” ACI Mater. J., 90(5), 441–451.
Samson, E., Marchand, J., Snyder, K. A., and Beaudoin, J. J. (2005). “Modeling ion and fluid transport in unsaturated cement systems in isothermal conditions.” Cem. Concr. Res., 35(1), 141–153.
Sandberg, P., Tang, L., and Andersen, A. (1998). “Recurrent studies of chloride ingress in uncracked marine concrete at various exposure times and elevations.” Cem. Concr. Res., 28(10), 1489–1503.
Song, H. W., Lee, C. H., and Ann, K. Y. (2008). “Factors influencing chloride transport in concrete structures exposed to marine environments.” Cem. Concr. Compos., 30(2), 113–121.
Thomas, M. D. A., and Bamforth, P. B. (1999). “Modelling chloride diffusion in concrete. Effect of fly ash and slag.” Cem. Concr. Res., 29(4), 487–495.
Uji, K., Matsuoka, Y., and Maruya, T. (1990). “Formulation of an equation for surface chloride content of concrete due to permeation of chloride.” Proc., 3rd Int. Symp. on Corrosion of Reinforcement in Concrete, C. L. Page, K. W. J. Treadaway, and P. B. Bamforth, eds., Society for the Chemical Industry, Warwickshire, U.K.
Vennesland, Ø., Climent, M. A., and Andrade, C. (2013). “Recommendation of RILEM TC 178-TMC: Testing and modeling chloride penetration in concrete. methods for obtaining dust samples by means of grinding concrete in order to determine the chloride concentration profile.” Mater. Struct., 46(3), 337–344.
Viqueira, E. (2009). “Concrete contamination by chlorides due to interaction with PVC combustion products and due to marine atmospherical exposure.” Ph.D. thesis, Universitat d’Alacant, Alacant, Spain (in Spanish).
Yuan, Q., Shi, C., De Schutter, G., Audenaert, K., and Deng, D. (2009). “Chloride binding of cement-based materials subjected to external chloride environment—A review.” Constr. Build. Mater., 23(1), 1–13.

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Go to Journal of Materials in Civil Engineering
Journal of Materials in Civil Engineering
Volume 27Issue 8August 2015

History

Received: Apr 29, 2014
Accepted: Aug 5, 2014
Published online: Oct 15, 2014
Discussion open until: Mar 15, 2015
Published in print: Aug 1, 2015

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Authors

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Professor, Departament d’Enginyeria Civil, Universitat d’Alacant, Ap. 99, 03080 Alacant, Spain (corresponding author). E-mail: [email protected]
M. A. Climent
Full Professor, Departament d’Enginyeria Civil, Universitat d’Alacant, Ap. 99, 03080 Alacant, Spain.
E. Viqueira
Deceased; formerly, Associate Professor, Departament d’Enginyeria Civil, Universitat d’Alacant, Ap. 99, 03080 Alacant, Spain.
C. Antón
Researcher, Departament d’Enginyeria Civil, Universitat d’Alacant, Ap. 99, 03080 Alacant, Spain.
M. P. López
Ph.D. Candidate, Departament d’Enginyeria Civil, Universitat d’Alacant, Ap. 99, 03080 Alacant, Spain.

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