Technical Papers
Aug 11, 2014

Use of Secondary Slags in Completely Recyclable Concrete

Publication: Journal of Materials in Civil Engineering
Volume 27, Issue 5

Abstract

A completely recyclable concrete (CRC) is designed to have a chemical composition equivalent to the one of general raw materials for cement production. By doing so, this CRC can be used at the end of its service life in the cement clinkering process without need for ingredient adjustments, and with improvement of the resource efficiency of cement and concrete production. Copper slag is interesting as an iron source for the production of such a CRC and can be added to concrete, either as alternative binder or as aggregate. By isothermal calorimetry and compressive strength tests it was found that the addition of copper slag as cement replacement is of minor interest. But a study toward the compressive strength and durability of concrete with copper slag as aggregate replacement had promising results. The performance of these concretes was comparable with or even better than the reference concrete, regarding strength and most durability aspects such as porosity and permeability, and resistance against carbonation and chloride ingress. Only the resistance to freeze-thaw attack with deicing agents was inferior.

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Acknowledgments

Financial support from the Institute for the Promotion of Innovation through Science and Technology in Flanders (IWT-Vlaanderen) and the Research Foundation Flanders (FWO) (Grant no. G087510 N) for this study is gratefully acknowledged.

References

ACI. (2008). “Guide to durable concrete.”, ACI, Farmington Hills, MI.
Al-Jabri, K. S., Al-Saidy, A. H., and Taha, R. (2011). “Effect of copper slag as a fine aggregate on the properties of cement mortars and concrete.” Constr. Build. Mater., 25(2), 933–938.
Al-Jabri, K. S., Hisada, M., Al-Oraimi, S. K., and Al-Saidy, A. H. (2009a). “Copper slag as sand replacement for high performance concrete.” Cem. Concr. Compos., 31(7), 483–488.
Al-Jabri, K. S., Hisada, M., Al-Saidy, A. H., and Al-Oraimi, S. K. (2009b). “Performance of high strength concrete made with copper slag as a fine aggregate.” Constr. Build. Mater., 23(6), 2132–2140.
Al-Jabri, K. S., Taha, R. A., Al-Hashmi, A., and Al-Harthy, A. S. (2006). “Effect of copper slag and cement by-pass dust addition on mechanical properties of concrete.” Constr. Build. Mater., 20(5), 322–331.
Arab, H. B. (2006). “Aggregates from construction & demolition waste in Europe.” State of play—Providing essential materials for Europe, European Aggregates Association, Brussels, Belgium.
Baert, G. (2009). “Physico-chemical interactions in Portland cement—(high volume) fly ash binders.” Ph.D. thesis, Ghent Univ., Ghent.
De Belie, N., and Robeyst, N. (2007). “Recycling of construction materials.” Environment-conscious construction materials and systems, State of the art report of TC 192-ECM, RILEM Rep. No. 37, N. Kashino, D. Van Gemert and K. Imamoto, eds., RILEM Publications S.A.R.L., Bagneux, 11–23.
De Schepper, M., De Buysser, K., Van Driessche, I., and De Belie, N. (2013). “The regeneration of cement out of completely recyclable concrete: Clinker production evaluation.” Constr. Build. Mater., 38, 1001–1009.
De Schepper, M., Snellings, R., De Buysser, K., Van Driessche, I., and De Belie, N. (2014). “The hydration of cement regenerated from completely recyclable concrete.” Constr. Build. Mater., 60(0), 33–41.
De Schutter, G. (1999). “Hydration and temperature development of concrete made with blast-furnace slag cement.” Cem. Concr. Res., 29(1), 143–149.
Goñi, S., Lorenzo, M. P., and Sagrera, J. L. (1994). “Durability of hydrated Portland cement with copper slag addition in NaCl+Na2SO4 medium.” Cem. Concr. Res., 24(8), 1403–1412.
Gorai, B., and Jana, R. K. (2003). “Characteristics and utilisation of copper slag—A review.” Resour. Conserv. Recycl., 39(4), 299–313.
Kaid, N., Cyr, M., Julien, S., and Khelafi, H. (2009). “Durability of concrete containing a natural pozzolan as defined by a performance-based approach.” Constr. Build. Mater., 23(12), 3457–3467.
Khanzadi, M., and Behnood, A. (2009). “Mechanical properties of high-strength concrete incorporating copper slag as coarse aggregate.” Constr. Build. Mater., 23(6), 2183–2188.
Kogel, J. E., Trivedi, N. C., and Barker, J. M. (2006). Industrial minerals and rocks, 7th Ed., Society for Mining, Metallurgy and Exploration, Englewood, CO.
Langer, W. H., Drew, L. J., and Sachs, J. S. (2004). “Aggregate and the environment: Production, construction, reclamation.” American Geological Institute, Alexandria.
McDonough, W., and Braungart, M. (2002). Cradle to cradle: Remaking the way we make things, 1st Ed., North Point Press, New York.
Mills, R. H. (1966). “Factors influencing cessation of hydration in water-cured cement pastes.” Symp. on the Structure of Portland Cement Paste and Concrete, Highway Research Board Special Rep. 90, Highway Research Board, Washington, DC, 406–424.
Najimi, M., Sobhani, J., and Pourkhorshidi, A. R. (2011). “Durability of copper slag contained concrete exposed to sulfate attack.” Constr. Build. Mater., 25(4), 1895–1905.
NBN. (1976). “Testing of building materials: Resistance to freezing: Water absorption by capillarity.” B 05-201, NBN, Brussels, Belgium.
NBN. (2001a). “Testing hardened concrete—Part 1: Shape, dimensions and other requirements for specimens and moulds.” EN 12390-1, NBN, Brussels, Belgium.
NBN. (2001b). “Concrete—Part 1: Specification, performance, production and conformity.” EN 206-1, NBN, Brussels, Belgium.
NBN. (2003). “Concrete paving flags—Requirements and test methods.” EN 1339, NBN, Brussels, Belgium.
NBN. (2004). “Supplement to NBN EN 206-1—concrete—specification, performance, production and confirmity.” B 15-001, NBN, Brussels, Belgium.
NBN. (2005). “Methods of testing cement—Part 1: Determination of strength.” EN 196-1, NBN, Brussels, Belgium.
NT Build 492. (1999). Concrete, mortar and cement-based repair materials: Chloride migration coefficient from non-steady state migration experiments.
RILEM TC 116-PCD. (1999). “Permeability of concrete as a criterion of its durability.” Final report: Concrete durability—An approach towards performance testing Vol. 32, RILEM Publications SARL, Bagneux, France, 163–173.
Shi, C., Meyer, C., and Behnood, A. (2008). “Utilization of copper slag in cement and concrete.” Resour. Conserv. Recycl., 52(10), 1115–1120.
Taha, R., Al-Rawas, A., Al-Jabri, K., Al-Harthy, A., Hassan, H., and Al-Oraimi, S. (2004). “An overview of waste materials recycling in the Sultanate of Oman.” Resour. Conserv. Recycl., 41(4), 293–306.
Taha, R. A., Alnuaimi, A. S., Al-Jabri, K. S., and Al-Harthy, A. S. (2007). “Evaluation of controlled low strength materials containing industrial by-products.” Build. Environ., 42(9), 3366–3372.
Tamura, M., Noguchi, T., and Tomosawa, F. (2004). “Cementitious waste-free-type completely recyclable concrete.” Proc., RILEM Int. Symp. on Environment-Conscious Materials and Systems for Sustainable Development, N. Kashino and Y. Ohama, eds., RILEM Publications SARL, Bagneux, France, 61–71.
Thomas, B. S., Anoop, S., and Kumar, V. S. (2012). “Utilization of solid waste particles as aggregates in concrete.” Procedia Eng., 38, 3789–3796.
Tixier, R., Devaguptapu, R., and Mobasher, B. (1997). “The effect of copper slag on the hydration and mechanical properties of cementitious mixtures.” Cem. Concr. Res., 27(10), 1569–1580.
Wu, W., Zhang, W., and Ma, G. (2010a). “Mechanical properties of copper slag reinforced concrete under dynamic compression.” Constr. Build. Mater., 24(6), 910–917.
Wu, W., Zhang, W., and Ma, G. (2010b). “Optimum content of copper slag as a fine aggregate in high strength concrete.” Mater. Des., 31(6), 2878–2883.
Zain, M. F. M., Islam, M. N., Radin, S. S., and Yap, S. G. (2004). “Cement-based solidification for the safe disposal of blasted copper slag.” Cem. Concr. Compos., 26(7), 845–851.

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Go to Journal of Materials in Civil Engineering
Journal of Materials in Civil Engineering
Volume 27Issue 5May 2015

History

Received: Jan 27, 2014
Accepted: May 21, 2014
Published online: Aug 11, 2014
Discussion open until: Jan 11, 2015
Published in print: May 1, 2015

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Authors

Affiliations

Mieke De Schepper [email protected]
Ph.D. Candidate, Magnel Laboratory for Concrete Research, Ghent Univ., Technologiepark Zwijnaarde 904, 9052 Ghent, Belgium (corresponding author). E-mail: [email protected]
Pieter Verlé
Engineer, Master of Science in Civil Engineering, Magnel Laboratory for Concrete Research, Ghent Univ., Technologiepark Zwijnaarde 904, 9052 Ghent, Belgium.
Isabel Van Driessche
Professor, Sol-gel Centre for Research on Inorganic Powders and Thin films Synthesis (SCRiPTS), Ghent Univ., Krijgslaan 281- S3, 9000 Ghent, Belgium.
Nele De Belie [email protected]
Professor, Magnel Laboratory for Concrete Research, Ghent Univ., Technologiepark Zwijnaarde 904, 9052 Ghent, Belgium. E-mail: [email protected]

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