Technical Papers
Jul 25, 2014

Technical Characterization of Sintered-Glass Ceramics Derived from Glass Fibers Recovered by Pyrolysis

Publication: Journal of Materials in Civil Engineering
Volume 27, Issue 4

Abstract

Sintered wollastonite-plagioclase glass ceramics were prepared through crystallization of a parent glass generated by vitrification of pyrolysis residual glass fibers that had been pyrolytically recovered from waste composite materials. A vitrifiable mixture consisting of 95% by weight glass fiber and 5% by weight Na2O was melted at 1,450°C to obtain a glass frit. The glass-ceramic materials were produced by a sinter-crystallization process from the powdered glass frit. The effect of firing temperature on the properties of sintered-glass ceramics was investigated. The sintering behavior of glass-ceramic tiles was evaluated by means of water absorption, apparent porosity, and bulk density. In addition, the mineralogical and microstructural characterization of these tiles was carried out using X-ray diffraction (XRD) and scanning electron microscopy (SEM). The results from experiments such as water absorption, bending strength, chemical resistance, and stain resistance have shown that the developed glass-ceramic materials possess technological properties very suitable for architectural applications.

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Acknowledgments

Dr. M. I. Martín thanks the Spanish National Research Council (CSIC), cofinanced by the European Social Fund Operational Programme 2007–2013 Adaptability and Employment Multiregional, for the contract JAE-Doc_08–00032. The authors also thank IRICA from University of Castilla-La Mancha (Spain) for their experimental assistance with XRD.

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Published In

Go to Journal of Materials in Civil Engineering
Journal of Materials in Civil Engineering
Volume 27Issue 4April 2015

History

Received: Sep 6, 2013
Accepted: Mar 26, 2014
Published online: Jul 25, 2014
Discussion open until: Dec 25, 2014
Published in print: Apr 1, 2015

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Authors

Affiliations

M. I. Martín
Postdoctoral Researcher, Dept. of Construction, Group of Glassy and Ceramic Materials, Eduardo Torroja Institute for Construction Science (IETcc), CSIC, Serrano Galvache, 4, 28033 Madrid, Spain.
F. A. López
Research Scientist, Dept. of Primary Metallurgy and Recycling, Recycling Materials Laboratory, National Centre for Metallurgical Research (CENIM), CSIC, Avda. Gregorio del Amo 8, 28040 Madrid, Spain.
F. J. Alguacil
Research Professor, Dept. of Primary Metallurgy and Recycling, Recycling Materials Laboratory, National Centre for Metallurgical Research (CENIM), CSIC, Avda. Gregorio del Amo 8, 28040 Madrid, Spain.
Research Scientist, Dept. of Construction, Group of Glassy and Ceramic Materials, Eduardo Torroja Institute for Construction Science (IETcc), CSIC, Serrano Galvache, 4, 28033 Madrid, Spain (corresponding author). E-mail: [email protected]

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