Technical Papers
Oct 30, 2013

Research Progresses in Magnesium Phosphate Cement–Based Materials

Publication: Journal of Materials in Civil Engineering
Volume 26, Issue 10

Abstract

This paper reviews recent studies on preparation, hydration, and properties of magnesium phosphate cement (MPC). MPC is the phosphate-bonded inorganic material derived from reactions between phosphate and magnesium oxide. The hydration reaction in the MgO-NH4H2PO4 system is strongly exothermic, and the main product is struvite (NH4MgPO4·6H2O). The setting time and mechanical properties depend on the proportion and characteristics of raw materials, water to binder ratio, the addition of retarders, and admixtures. Moreover, the MPC demonstrates favorable durability performance compared with Portland cement. Additionally, recommendations for future research are proposed.

Get full access to this article

View all available purchase options and get full access to this article.

References

Abdelrazig, B., and Sharp, J. (1985). “A discussion of the papers on magnesia-phosphate cements by T. Sugama and L. E. Kukacka.” Cement Concr. Res., 15(5), 921–922.
Abdelrazig, B., Sharp, J., and El-Jazairi, B. (1988). “The chemical composition of mortars made from magnesia-phosphate cement.” Cement Concr. Res., 18(3), 415–425.
Abdelrazig, B., Sharp, J., and El-Jazairi, B. (1989). “The microstructure and mechanical properties of mortars made from magnesia-phosphate cement.” Cement Concr. Res., 19(2), 247–258.
Allan, F. C., and Asgar, K. (1980). “Reaction of cobalt-chromium casting alloys with investments.” J. Dental Res., 59(9), 1478–1485.
Ando, J., Shinada, T., and Hiraoka, G. (1974). “Reaction of monoaluminum phosphate with alumina and magnesia.” J. Ceram. Soc. Japan, 82, 644–649.
Andrade, A., and Schuiling, R. D. (2001). “The chemistry of struvite crystallization.” Miner. J., 23(5–6), 37–46.
Awada, T. (1974). “On setting mechanism and hygroscopic expansion of phosphate-bonded investment mixed with colloïdal silica solution.” J. Japan Dental Res. Soc., 32(6).
Chang, Y., Shi, C., Yang, N., and Yang, J. (2013). “Effect of fineness of magnesium oxide on properties of magnesium potassium phosphate cement.” J. Chinese Ceram. Soc., 41(4), 492–499.
Ding, Z. (2005). “Research of magnesium phosphosilicate cement.” Doctor, Hong Kong Univ. of Science and Technology, Hong Kong.
Ding, Z., Dong, B., Xing, F., Han, N., and Li, Z. (2012). “Cementing mechanism of potassium phosphate based magnesium phosphate cement.” Ceram. Int., 38(8), 6281–6288.
Ding, Z., and Li, Z. (2005). “Effect of aggregates and water contents on the properties of magnesium phospho-silicate cement.” Cement Concr. Compos., 27(1), 11–18.
Ding, Z., Lin, W., and Feng, X. (2010). “Property study of high early strength magnesium phosphosilicate cement (in Chinese).” Proc., 7th Council Meeting of the Chinese Ceramic Society, Chinese Ceramic Society.
Finch, T., and Sharp, J. (1989). “Chemical reactions between magnesia and aluminium orthophosphate to form magnesia-phosphate cements.” J. Mater. Sci., 24(12), 4379–4386.
Gilham-Dayton, P. A. (1963). “The phosphate bonding of refractory materials.” Trans. Br. Ceram. Soc., 62(1), 895–904.
Hall, D. A., Stevens, R., and El-Jazairi, B. (2001). “The effect of retarders on the microstructure and mechanical properties of magnesia–phosphate cement mortar.” Cement Concr. Res., 31(3), 455–465.
Hall, D. A., Stevens, R., and Jazairi, B. E. (1998). “Effect of water content on the structure and mechanical properties of magnesia-phosphate cement mortar.” J. Am. Ceram. Soc., 81(6), 1550–1556.
Huang, Y. (1989). Metal corrosion and protection principles, Shanghai Jiaotong Univ. Press, Shanghai.
Li, D., Li, P., and Feng, C. (2009). “Research on water resistance of magnesium phosphate cement (in Chinese).” J. Build. Mater., 12(005), 505–510.
Li, X., Du, L., and Li, D. (2008). “The preparation and study on the new high early strength magnesium phosphate cement.” Bull. Chinese Ceram. Soc., 27(1), 20–25.
Li, Y., and Chen, B. (2013). “Factors that affect the properties of magnesium phosphate cement.” Constr. Build. Mater., 47, 977–983.
Li, Z., Ding, Z., and Zhang, Y. (2004). “Development of sustainable cementitious materials.” Proc., Int. Workshop on Sustainable Development and Concrete Technology, Iowa State Univ., Ames, IA, 55–76.
Lin, W., Wei, S., and Li, Z. (2011). “Study on the drying shrinkage of magnesium phosphate cement mortar.” Ind. Constr., 41(4), 75–78.
Mabie, C. P. (1973). “Petrographic study of the refractory performance of high-fusing dental alloy investments: I. High-fired, phosphate-bonded investments.” J. Dental Res., 52(1), 96–110.
Mala, K., Mullick, A. K., Jain, K. K., and Singh, P. K. (2013). “Effect of relative levels of mineral admixtures on corrosion resistance of cracked ternary cement blend concrete.” J. Sustainable Cem. Based Mater., 3(1), 24–46.
Min, M., Zhi, W., Qing-Zhen, W., Qian-Wen, H., and Chao, Y. (2011). “Influencing factors on water resistance of magnesium phosphate cement and its improving measures.” Fly Ash Compr. Utilization, 6, 15–18.
Neiman, R., and Sarma, A. C. (1980). “Setting and thermal reactions of phosphate investments.” J. Dental Res., 59(9), 1478–1485.
Popovics, S., and Rajendran, N. (1987). “Early age properties of magnesium phosphate-based cements under various temperature conditions.” Transportation Research Board Business Office, Washington, DC.
Popovics, S., Rajendran, N., and Penko, M. (1987). “Rapid hardening cements for repair of concrete.” ACI Mater. J., 84(1).
Qian, C., and Yang, J. M. (2011). “Effect of disodium hydrogen phosphate on hydration and hardening of magnesium potassium phosphate cement.” J. Mater. Civ. Eng., 1405–1411.
Qiao, F., Chau, C., and Li, Z. (2010). “Property evaluation of magnesium phosphate cement mortar as patch repair material.” Constr. Build. Mater., 24(5), 695–700.
Roy, D. (1989). “Recent advances in phosphate chemically bonded ceramics.” MRS Intl. Mtg. Adv. Mater., 13(2), 213–227.
Sarkar, A. K. (1990). “Phosphate cement-based fast-setting binders.” Am. Ceram. Soc. Bull., 69(2), 234–238.
Sarkar, A. K. (1991). “Hydration/dehydration characteristics of struvite and dittmarite pertaining to magnesium ammonium phosphate cement systems.” J. Mater. Sci., 26(9), 2514–2518.
Sarkar, A. K. (1993). “Investigation of reaction/bonding mechanisms in regular and retarded magnesium ammonium phosphate cement systems.” Ceram. Trans., 40, 281–288.
Seehra, S., Gupta, S., and Kumar, S. (1993). “Rapid setting magnesium phosphate cement for quick repair of concrete pavements—characterisation and durability aspects.” Cement Concr. Res., 23(2), 254–266.
Sengupta, P., Swihart, G., Dimitrijevic, R., and Hossain, M. (1991). “The crystal structure of lunebergite.” Am. Mineral., 76, 1400–1407.
Shi, C., Yang, J., Yang, N., and Chang, Y. (2014). “Effect of waterglass on water stability of potassium magnesium phosphate cement paste.” Cement Concr. Compos., in press.
Soudée, E., and Péra, J. (2000). “Mechanism of setting reaction in magnesia-phosphate cements.” Cement Concr. Res., 30(2), 315–321.
Soudée, E., and Péra, J. (2002). “Influence of magnesia surface on the setting time of magnesia-phosphate cement.” Cement Concr. Res., 32(1), 153–157.
Stratful, I., Scrimshaw, M., and Lester, J. (2001). “Conditions influencing the precipitation of magnesium ammonium phosphate.” Water Res., 35(17), 4191–4199.
Sugama, T., and Kukacka, L. (1983a). “Characteristics of magnesium polyphosphate cements derived from ammonium polyphosphate solutions.” Cement Concr. Res., 13(4), 499–506.
Sugama, T., and Kukacka, L. (1983b). “Magnesium monophosphate cements derived from diammonium phosphate solutions.” Cement Concr. Res., 13(3), 407–416.
Wagh, A. S. (2004). Chemically bonded phosphate ceramics, Elsevier, Bridgewater, NJ, 102.
Wagh, A. S., and Jeong, S. Y. (2003). “Chemically bonded phosphate ceramics. I: A dissolution model of formation.” J. Am. Ceram. Soc., 86(11), 1838–1844.
Wang, H. (2006). “Study on the high performance magnesium phosphate cement based materials (in Chinese).” Chongqing Univ., Chongqing, China.
Wilson, W. A., and Nicholson, J. W. (1993). Acid-base cement (their biomedical and industrial applications), Cambridge University Press, Cambridge, U.K.
Yang, J., and Qian, C. (2010). “Effect of borax on hydration and hardening properties of magnesium and potassium phosphate cement pastes.” J. Wuhan Univ. Technol. Mater. Sci. Ed., 25(4), 613–618.
Yang, J., Shi, C., Chang, Y., and Yang, N. (2013). “Hydration and hardening characteristics of magnesium potassium phosphate cement paste containing composite retarders.” J. Build. Mater., 16(1), 43–49.
Yang, Q., and Wu, X. (1999). “Factors influencing properties of phosphate cement-based binder for rapid repair of concrete.” Cement Concr. Res., 29(3), 389–396.
Yang, Q., Zhang, S., and Wu, X. (2002). “Deicer-scaling resistance of phosphate cement-based binder for rapid repair of concrete.” Cement Concr. Res., 32(1), 165–168.
Yang, Q., Zhu, B., and Wu, X. (2000). “Characteristics and durability test of magnesium phosphate cement-based material for rapid repair of concrete.” Mater. Struct., 33(4), 229–234.
Yao, Y., Wang, Z., and Wang, L. (2012). “Durability of concrete under combined mechanical load and environmental actions: A review.” J. Sustainable Cem. Based Mater., 1(1–2), 2–15.
Yoshizaki, Y., Ikeda, K., Yoshida, S., and Yoshizumi, A. (1989). “Physicochemical study of magnesium-phosphate cement.” MRS Intl. Mtg. Adv., 13, 27–38.
Zhang, T., Vandeperre, L. J., and Cheeseman, C. R. (2012). “Magnesium-silicate-hydrate cements for encapsulating problematic aluminium containing wastes.” J. Sustainable Cem. Based Mater., 1(1–2), 34–45.
Zhou, X., Yang, J., and Jin, W. (2012). “Microstructure evolution of magnesium-potassium phosphate cement paste.” Bull. Chinese Ceram. Soc., 31(6), 1438–1444.

Information & Authors

Information

Published In

Go to Journal of Materials in Civil Engineering
Journal of Materials in Civil Engineering
Volume 26Issue 10October 2014

History

Received: Jul 22, 2013
Accepted: Oct 28, 2013
Published online: Oct 30, 2013
Published in print: Oct 1, 2014
Discussion open until: Oct 22, 2014

Permissions

Request permissions for this article.

Authors

Affiliations

Nan Yang
Graduate Student, College of Civil Engineering, Hunan Univ., Changsha 410082, China.
Professor, College of Civil Engineering, Hunan Univ., Changsha 410082, China (corresponding author). E-mail: [email protected]
Jianming Yang
Professor, College of Civil Engineering, Yancheng Institute of Technology, Yancheng 224051, China.
Yuan Chang
Graduate Student, College of Civil Engineering, Hunan Univ., Changsha 410082, China.

Metrics & Citations

Metrics

Citations

Download citation

If you have the appropriate software installed, you can download article citation data to the citation manager of your choice. Simply select your manager software from the list below and click Download.

Cited by

View Options

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Media

Figures

Other

Tables

Share

Share

Copy the content Link

Share with email

Email a colleague

Share