Technical Notes
May 26, 2012

Determination of Apparent Activation Energy of Concrete by TMC and Mathematical Means

Publication: Journal of Materials in Civil Engineering
Volume 25, Issue 2

Abstract

This paper presents a novel procedure to determine the apparent activation energy (Ea) of concrete by temperature-matched curing (TMC) and a mathematical approach in which a TMC system is designed and finite-element software is used. The mathematical approach is adopted to analyze Ea energy by minimizing the difference between the predicted values and measured data from testing samples cured under TMC conditions. Two methods are proposed to select the best-fit value of Ea (Ea1 for specified age i and Ea2 for testing ages ranging from the first testing age to age i). The results show that the value of Ea is strongly age-dependent and nonlinear. Ea1 decreases remarkably after a critical age, whereas Ea2 varies smoothly with age. The value of Ea is related to the temperature history. The procedure to determine Ea presented in this paper fully takes into account the temperature effects on cementitious materials, and practicality and accuracy are greatly improved.

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Acknowledgments

The work presented in this paper was funded by Project 863 “Super High-Rise Building Construction Condition Monitoring and Reliability Control Technology” (2009AA04Z420).

References

Alexander, K. M., and Taplin, J. H. (1962). “Concrete strength, bond strength, cement hydration and the maturity rule.” Aust. J. Appl. Sci., 13(4), 277–284.
ASTM. (2004a). “Standard practice for estimating concrete strength by the maturity method.” ASTM C1074, West Conshohocken, PA.
ASTM. (2004b). “Standard test method for obtaining and testing drilled cores and sawed beams of concrete.” ASTM C 42/C 42M, West Conshohocken, PA.
Broda, M., Wirquin, E., and Duthoit, B. (2002). “Conception of an isothermal calorimeter for concrete-determination of the apparent activation energy.” Mater. Struct., 35(7), 389–394.
CEB-FIP. (1993). CEB-FIP model code 1990: Design code, Thomas Telford, London.
Chanvillard, G., and D’Aloia, L. (1997). “Concrete strength estimation at early ages: Modification of the method of equivalent age.” ACI Mater. J., 94(6), 520–530.
Han, S. H., Kim, J. K., and Park, Y. D. (2003). “Prediction of compressive strength of fly ash concrete by new apparent activation energy function.” Cem. Concr. Res., 33(7), 965–971.
Hansen, P. F., and Pedersen, E. J. (1977). “Maturity computer for controlled curing and hardening of concrete.” Nordisk Betong, 19(1), 21–25.
Kada-Benameur, H., Wirquin, E., and Duthoit, B. (2000). “Determination of apparent activation energy of concrete by isothermal calorimetry.” Cem. Concr. Res., 30(2), 301–305.
Kim, J. K., Han, S. H., and Lee, K. M. (2001). “Estimation of compressive strength by a new apparent activation energy function.” Cem. Concr. Res., 31(2), 217–225.
Li, M. J., Shao Q. (2010). “Analysis of hydration heat in 3.8-meter-wide artificial dug-hole pile of Guangzhou New TV Tower.” Guangzhou Architect., 38(4), 37–40.
Liu, G., Xu, Y. L., and Yu, C. H. (2007). “Experimental study on the solid strength of mass concrete.” Concrete, 9, 102–104.
Mak, S. L., and Torii, K. (1995). “Strength development of high strength concretes with and without silica fume under the influence of high hydration temperatures.” Cem. Concr. Res., 25(8), 1791–1802.
Mani, A. C., Tam, C. T., and Lee, S. L. (1990). “Influence of high early temperatures on properties of PFA concrete.” Cem. Concr. Compos., 12(2), 109–115.
McIntosh, J. D. (1956). “The effects of low-temperature curing on the compressive strength of concrete.” Proc., RILEM Symp. on Winter Concreting, Session BII, Danish Institute for Building Research, Copenhagen.
Saul, A. G. A. (1951). “Principles underlying the steam curing of concrete at atmospheric pressure.” Mag. Concr. Res., 2(6), 127–140.
Wang, J. C, Yan, P. Y, and Yu, H. F (2007). “Apparent activation energy of concrete in early age determined by adiabatic test.” J. Wuhan Univ. Technol. Mater. Sci. Ed., 22(3), 537–541.
Wang, X. Y., Cho, H. K., and Lee, H. S. (2011). “Prediction of temperature distribution in concrete incorporating fly ash or slag using a hydration model.” Composites Part B, 42(1), 27–40.
Wirquin, E., Broda M., and Duthoit B. (2002). “Determination of the apparent activation energy of concrete by calorimetric and mechanical means: Influence of a superplasticizer.” Cem. Concr. Res., 32(8), 1207–1213.
Yan, P. Y., and Qin, X. (2001). “The effect of expansive agent and possibility of delayed ettringite formation in shrinkage-compensating massive concrete.” Cem. Concr. Res., 31(2), 335–337.
Zhang, J. Y., Cusson, D., Monteiro, P., and Harvey, J. (2008). “New perspectives on maturity method and approach for high performance concrete applications.” Cem. Concr. Res., 38(12), 1438–1446.

Information & Authors

Information

Published In

Go to Journal of Materials in Civil Engineering
Journal of Materials in Civil Engineering
Volume 25Issue 2February 2013
Pages: 289 - 295

History

Received: Feb 18, 2011
Accepted: May 23, 2012
Published online: May 26, 2012
Published in print: Feb 1, 2013

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Authors

Affiliations

School of Materials Science and Engineering, Tongji Univ., Shanghai 200092, China; Technical Centre of Shanghai Construction (Group) General Co., Shanghai 200083, China (corresponding author). E-mail: [email protected]
Xiong Zhang
School of Materials Science and Engineering, Tongji Univ., Shanghai 200092, China.
Xiaomin Liao
Technical Centre of Shanghai Construction (Group) General Co., Shanghai 200083, China.
Yun Zhou
Technical Centre of Shanghai Construction (Group) General Co., Shanghai 200083, China.

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