Abstract

Application of power ultrasound to enhance dispersion of commercial densified silica fume leads to increased compressive strengths and refinement of the pore structure in mortars, compared with those that are untreated. This was attributed to the enhanced pozzolanic reactivity achieved by particle dispersion through sonication, leading to higher consumption of portlandite during curing, and formation of a calcium silicate hydrate gel with a higher degree of cross-linking than is identified in specimens with densified silica fume. This suggests that with the use of sonicated silica fume, it is possible to reduce the required quantity of admixture in blended cements to achieve specified performance, with the additional advantage of the formation of a highly densified structure and refined pore network, contributing to potential improvements in durability.

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Acknowledgements

This study was sponsored by the Ministerio de Ciencia e Innovación of Spain (Project SILISONIC BIA-2007-63252 and research scholarships BES-2008-002440 and EEBB-2011-43847), the European regional development fund (FEDER), and the Universitat Politècnica de València (Spain). Participation of SAB and JLP was funded by the Australian Research Council (ARC), including partial funding through the Particulate Fluids Processing Centre, a Special Research Centre of the ARC. The authors thank Dr. John Gehman for support in conducting the NMR experiments at the Bio21 Institute, University of Melbourne, Australia.

References

Al-Amoudi, O. S. B. (2002). “Durability of plain and blended cements in marine environments.” Adv. Cement Res., 14(3), 89–100.
Andersen, M. D., Jakobsen, H. J., and Skibsted, J. (2003). “Incorporation of aluminum in the calcium silicate hydrate (C-S-H) of hydrated portland cements: A high-field Al27 and Si29 MAS NMR investigation.” Inorg. Chem., 42(7), 2280–2287.
Andersen, M. D., Jakobsen, H. J., and Skibsted, J. (2004). “Characterization of white portland cement hydration and the C-S-H structure in the presence of sodium aluminate by Al27 and Si29 MAS NMR spectroscopy.” Cement Concrete Res., 34(5), 857–868.
Andersen, M. D., Jakobsen, H. J., and Skibsted, J. (2006). “A new aluminium-hydrate species in hydrated portland cements characterized by Al27 and Si29 MAS NMR spectroscopy.” Cement Concrete Res., 36(1), 3–17.
ASTM. (2011). “Standard specification for silica fume used in cementitious mixtures.” C1240-11, West Conshohocken, PA.
Bar-Nes, G., Katz, A., Peled, Y., and Zeiri, Y. (2008). “The mechanism of cesium immobilization in densified silica-fume blended cement pastes.” Cement Concrete Res., 38(5), 667–674.
Barnes, J. R. et al. (1985). “Hydration of portland cement followed by Si29 solid-state NMR spectroscopy.” J. Mater. Sci. Lett., 4(10), 1293–1295.
Bentz, D. P., and Stutzman, P. E. (1994). “Evolution of porosity and calcium hydroxide in laboratory concretes containing silica fume.” Cement Concrete Res., 24(6), 1044–1050.
Bonen, D., and Diamond, S. (1992). “Occurrence of large silica fume-derived paticles in hydrated cement paste.” Cement Concrete Res., 22(6), 1059–1066.
Bye, G. C. (1999). Portland cement, Thomas Telford, London.
Chung, D. D. L. (2002). “Review: Improving cement-based materials by using silica fume.” J. Mater. Sci., 37(4), 673–682.
Diamond, S. (2000). “Mercury porosimetry: An inappropriate method for the measurement of pore size distributions in cement-based materials.” Cement Concrete Res., 30(10), 1517–1525.
Diamond, S., Sahu, S., and Thaulow, N. (2004). “Reaction products of densified silica fume agglomerates in concrete.” Cement Concrete Res., 34(9), 1625–1632.
European Committee for Standardization (CEN). (2000). “Cement—Part 1: Composition, specifications and conformity criteria for common cements.” EN 197-1:2000, Brussels, Belgium.
European Committee for Standardization (CEN). (2005). “Certification of silica fume for concrete.” EN 13263-1:2005, Brussels, Belgium.
Faucon, P., Delagrave, A., Richet, C., Marchand, J. M., and Zanni, H. (1999). “Aluminum incorporation in calcium silicate hydrates (C-S-H) depending on their Ca/Si ratio.” J. Phys. Chem. B, 103(37), 7796–7802.
Frías, M., Ramírez, M., Vigil de la Villa, R., Garcia, R., Rodríguez, O., and Sánchez Rojas, M. I. (2011). “Formation of hydrotalcite in activated paper sludge waste/Ca(OH)2 system.” Proc., 13th Int. Congress on the Chemistry of Cement, CSIC-Instituto Eduardo Torroja, Madrid, Spain.
German Institute for Standardization (DIN). (2005). “Methods of testing cement—Part 1: Determination of strength.” DIN-EN 196-1:2005, Berlin (in German).
Goldman, A., and Bentur, A. (1993). “The influence of microfillers on enhancement of concrete strength.” Cement Concrete Res., 23(4), 962–972.
Groves, G. W., and Rodger, S. A. (1989). “The hydration of C3S and ordinary portland cement with relatively large additions of microsilica.” Adv. Cement Res., 2(8), 135–140.
Holland, T. C. (2005). Silica fume user’s manual, Silica Fume Association, Lovettsville, VA.
Hooton, R. D. (1993). “Influence of silica fume replacement of cement on physical properties and resistance to sulfate attack, freezing and thawing, and alkali–silica reactivity.” ACI Mater. J., 90(2), 143–151.
Ivorra, S., Garcés, P., Catalá, G., Andión, L. G., and Zornoza, E. (2010). “Effect of silica fume particle size on mechanical properties of short carbon fiber reinforced concrete.” Mater. Design, 31(3), 1553–1558.
Komarneni, S. et al. (1985). “Al27 and Si29 magic angle spinning nuclear magnetic resonance spectroscopy of Al-substituted tobermorites.” J. Mater. Sci., 20(11), 4209–4214.
Lagerblad, B., and Utkin, P. (1995). “Undispersed granulated silica fume in concrete: Chemical system and durability problems.” MRS Proc., 370, 89–98.
Leemann, A., Münch, B., Gasser, P., and Holzer, L. (2006). “Influence of compaction on the interfacial transition zone and the permeability of concrete.” Cement Concrete Res., 36(8), 1425–1433.
Li, H., Xiao, H-G., Yuan, J., and Ou, J. (2004). “Microstructure of cement mortar with nano-particles.” Compos. Part B-Eng., 35(2), 185–189.
Li, S., Roy, D. M., and Kumar, A. (1985). “Quantatative determination of pozzolanas in hydrated systems of cement or Ca(OH)2 with fly ash or silica fume.” Cement Concrete Res., 15(6), 1079–1086.
Maas, A. J., Ideker, J. H., and Juenger, M. C. G. (2007). “Alkali silica reactivity of agglomerated silica fume.” Cement Concrete Res., 37(2), 166–174.
Martínez, D., Payá, J., Monzó, J. M., and Borrachero, M. V. (2008). “Granulometric activation of densified silica fume (CSF) by sonication.” Adv. Cement Res., 20(3), 129–135.
Martínez, D., Payá, J., Monzó, J. M., and Borrachero, M. V. (2011). “Effect of sonication on the reactivity of silica fume in portland cement mortars.” Adv. Cement Res., 23(1), 23–31.
Marusin, S. L., and Bradford, S. L. (2000). “Alkali-silica reaction in concrete caused by densified silica fume lumps: A case study.” Cement Concrete Aggr., 22(2), 90.
Mitchell, D. R. G., Hinczak, I., and Day, R. A. (1998). “Interaction of silica fume with calcium hydroxide solutions and hydrated cement pastes.” Cement Concrete Res., 28(11), 1571–1584.
Olek, J., and Rangaraju, P. R. (2000). “Evaluation of the potential of densified silica fume to cause alkali-silica reaction in cementitious matrices using a modified ASTM C 1260 test procedure.” Cement Concrete Aggr., 22(2), 150–159.
Papadakis, V. G. (2000). “Effect of supplementary cementing materials on concrete resistance against carbonation and chloride ingress.” Cement Concrete Res., 30(2), 291–299.
Payá, J., Monzó, J. M., Borrachero, M. V., and Velázquez, S. (2003). “Evaluation of the pozzolanic activity of fluid catalytic cracking catalyst residue (FC3R). Thermogravimetric analysis studies on FC3R-Portland cement pastes.” Cement Concrete Res., 33(4), 603–609.
Poon, C. S., Azhar, S., Anson, M., and Wong, Y.-L. (2001). “Comparison of the strength and durability performance of normal and high-strength pozzolanic concretes at elevated temperatures.” Cement Concrete Res., 31(9), 1291–1300.
Porteneuve, C., Korb, J-P., Petit, D., and Zanni, H. (2002). “Structure-texture correlation in ultra-high-performance concrete: A nuclear magnetic resonance study.” Cement Concrete Res., 32(1), 97–101.
Poulsen, S., Jakobsen, H. J., and Skibsted, J. (2009). “Methodologies for measuring the degree of reaction in portland cement blends with supplementary cementitious materials by Al27 and Si29 MAS NMR spectroscopy.” Proc., 7th Int. Conf. on Building Materials, Bauhaus-Universitat Weimar, Weimar, Germany, 177–188.
Ramachandran, V. S., Paroli, R. M., Beaudoin, J. J., and Delgado, A. H. (2002). Handbook of thermal analysis of construction materials, Noyes Publications, Park Ridge, NJ.
Richardson, I. G. (2000). “The nature of the hydration products in hardened cement pastes.” Cement Concrete Comp., 22(2), 97–113.
Richardson, I. G., Brough, A. R., Brydson, R., Groves, G. W., and Dobson, C. M. (1993). “Location of aluminum in substituted calcium silicate hydrate (C-S-H) gels as determined by Si29 and Al27 NMR and EELS.” J. Am. Ceram. Soc., 76(9), 2285–2288.
Richardson, I. G., and Groves, G. (1997). “The structure of the calcium silicate hydrate phases present in hardened pastes of white Portland cement/blast-furnace slag blends.” J. Mater. Sci., 32(18), 4793–4802.
Rodríguez, E. D., Soriano, L., Payá, J., Borrachero, M. V., and Monzó, J. M. (2011). “Increase of the reactivity of densified silica fume by sonication treatment.” Ultrason. Sonochem., 19(5), 1099–1107.
Roy, D. M., Arjunan, P., and Silsbee, M. R. (2001). “Effect of silica fume, metakaolin, and low-calcium fly ash on chemical resistance of concrete.” Cement Concrete Res., 31(12), 1809–1813.
Sakai, E., Kakinuma, Y., Yamamoto, K., and Daimon, M. (2009). “Relation between the shape of silica fume and the fluidity of cement paste at low water to powder ratio.” J. Adv. Concrete Technol., 7(1), 13–20.
Sanchez de Rojas, M. I., Rivera, J., and Frı́as, M. (1999). “Influence of the microsilica state on pozzolanic reaction rate.” Cement Concrete Res., 29(6), 945–949.
Shi, C. (2004). “Effect of mixing proportions of concrete on its electrical conductivity and the rapid chloride permeability test (ASTM C1202 or ASSHTO T277) results.” Cement Concrete Res., 34(3), 537–545.
Skibsted, J., Henderson, E., and Jakobsen, H. J. (1993). “Characterization of calcium aluminate phases in cements by aluminum MAS27 NMR spectroscopy.” Inorg. Chem., 32(6), 1013–1027.
Skibsted, J., Jakobsen, H. J., and Hall, C. (1994). “Direct observation of aluminium guest ions in the silicate phases of cement minerals by Al27 MAS NMR spectroscopy.” J. Chem. Soc. Faraday Trans., 90(14), 2095–2098.
Song, H.-W., Pack, S.-W., Nam, S.-H., Jang, J.-C., and Saraswathy, V. (2010). “Estimation of the permeability of silica fume cement concrete.” Constr. Build. Mater., 24(3), 315–321.
Spanish Association for Standardization and Certification (AENOR). (2000). “Methods of test for mortar for masonry—Part 3: Determination of consistence of fresh mortar (by flow table).” UNE-EN 1015-3:1999, Madrid, Spain (in Spanish).
Spanish Association for Standardization and Certification (AENOR). (2005). “Methods of testing cement—Part 1: Determination of strength.” UNE-EN 196-1:2005, Madrid, Spain (in Spanish).
Spanish Association for Standardization and Certification (AENOR). (2007). “Methods of test for mortar for masonry—Part 11: Determination of flexural and compressive strength of hardened mortar.” UNE-EN 1015-11:2000/A1:2007, Madrid, Spain (in Spanish).
Sun, G., Brough, A. R., and Young, J. F. (1999). “Si NMR Study of the hydration of Ca3SiO5 and β-Ca2SiO4 in the presence of silica fume.” J. Am. Ceram. Soc., 82(11), 3225–3230.
Taylor, H. F. W. (1997). Cement chemistry, Thomas Telford, London.
U.S. Environmental Protection Agency (USEPA)/U.S. Dept. of Transportation/U.S. Dept. of Energy. (2008). “Study on increasing the usage of recovered mineral components in federally funded projects involving procurement of cement or concrete.”, Washington, DC.
Wang, L. H., Zhen, H., Xinhua, C., and Xiaorun, C. (2011). “Investigation of hydration and pozzolanic reaction in silica fume-cement paste.” Advances in construction materials through science and engineering, Springer, New York.
Washburn, E. (1921). “Note on method of determining the distribution of pore sizes in porous materials.” Proc. Natl. Acad. Sci., 7(4), 115–116.
Yajun, J., and Cahyadi, J. H. (2003). “Effects of densified silica fume on microstructure and compressive strength of blended cement pastes.” Cement Concrete Res., 33(10), 1543–1548.
Zanni, H., Cheyrezy, M., Maret, V., Philippot, S., and Nieto, P. (1996). “Investigation of hydration and pozzolanic reaction in Reactive Powder Concrete (RPC) using Si29 NMR.” Cement Concrete Res., 26(1), 93–100.

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Go to Journal of Materials in Civil Engineering
Journal of Materials in Civil Engineering
Volume 24Issue 10October 2012
Pages: 1295 - 1304

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Received: Nov 16, 2011
Accepted: Feb 16, 2012
Published online: Feb 21, 2012
Published in print: Oct 1, 2012

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Erich D. Rodríguez [email protected]
Instituto de Ciencia y Tecnología del Hormigón, Universitat Politècnica de València, 46022 Valencia, Spain (corresponding author). E-mail: [email protected], [email protected]
Susan A. Bernal [email protected]
Dept. of Chemical and Biomolecular Engineering, Univ. of Melbourne, Victoria 3010, Australia. E-mail: [email protected]
John L. Provis [email protected]
Dept. of Chemical and Biomolecular Engineering, Univ. of Melbourne, Victoria 3010, Australia. E-mail: [email protected]
Jordi Payá [email protected]
Instituto de Ciencia y Tecnología del Hormigón, Universitat Politècnica de València, 46022 Valencia, Spain. E-mail: [email protected]
José M. Monzó [email protected]
Instituto de Ciencia y Tecnología del Hormigón, Universitat Politècnica de València, 46022 Valencia, Spain. E-mail: [email protected]
María Victoria Borrachero [email protected]
Instituto de Ciencia y Tecnología del Hormigón, Universitat Politècnica de València, 46022 Valencia, Spain. E-mail: [email protected]

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