Technical Papers
Dec 20, 2011

Estimating Moisture Sensitivity of Warm Mix Asphalt Modified with Zycosoil as an Antistrip Agent Using Surface Free Energy Method

Publication: Journal of Materials in Civil Engineering
Volume 24, Issue 7

Abstract

With increasing interest in the use of warm mix asphalt (WMA) in the paving industry, more studies in this field for improvement of WMA properties seem to be necessary. In past decade, several studies focusing on use of Sasobit and asphamin as warm additives in asphalt mixtures have been conducted; however, the effects of these additives on moisture susceptibility of asphalt mixture are still not fully understood. In this study, the moisture susceptibility of WMA evaluated with and without a new nanotechnology material as antistrip additive (namely Zycosoil) by determining the micromechanisms that affect the adhesion bond between the aggregate and asphalt binder and the cohesion strength of the asphalt binder using the surface free energy (SFE) concept and laboratory testing analysis. Indeed, the primary goal of this research was to decrease the moisture damage in WMA. Two types of aggregates, limestone and granite, and two types of WMA additives, namely Sasobit and aspha-min, in addition to as Zycosoil as an antistrip additive were evaluated in this study. Moisture sensitivity index, which is the percentage of the aggregate surface exposed to water (P) as calculated by using the measured SFE and dynamic modulus results, was considered an index for the moisture susceptibility of mixtures. The findings suggest that WMA additives cause an increase in the acid component and a reduction in the SFE base components of asphalt binder. This causes decreased adhesion between acidic aggregate that is more moisture damange and asphalt binder. Moreover, Zycosoil additives cause an increase in the adhesion SFE between asphalt binder, modified with WMA additives and aggregates in the presence of water. A dynamic modulus test of Zycosoil performance yielded similar results, suggesting that using this material causes the ratio of the dynamic modulus values for wet/dry condition to increase significantly in samples made with WMA additives. For these reasons, the percentage of aggregate surface area wetted by water, index P, decreased when Zycosoil was used in all samples.

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References

AASHTO. (2004). “Standard method of test for resistance of compacted hot mix asphalt (hma) to moisture-induced damage.” T283, Washington, DC.
Arabani, M., and Hamedi, Gh. H. (2011). “Using the surface free energy method to evaluate the effects of polymeric aggregate treatment on moisture damage in hot mix asphalt.” J. Mater. Civ. Eng.JMCEE7, 23(6), 802–818.
ASTM. (1989). “Test method for resistance of plastic flow of bituminous mixtures using marshall apparatus.” D1559, West Conshohocken, PA.
ASTM. (2000). “Standard test method for theoretical maximum specific gravity and density of bituminous paving mixture.” D2041, West Conshohocken, PA.
ASTM. (2010). “Standard test method for bulk specific gravity and density of non-absorptive compacted bituminous mixtures.” D2726, West Conshohocken, PA.
Bhasin, A., and Little, D. N. (2007). “Characterization of aggregate surface energy using the universal sorption device.” J. Mater. Civ. Eng.JMCEE7, 19(8), 634–641.
Caro, S., Masad, E., Airey, G., Bhasin, A., and Little, D. (2008). “Probabilistic analysis of fracture in asphalt mixtures caused by moisture damage.” Transportation Research Record 2057, Transportation Research Board, Washington, DC, 28–36.
Cheng, D. (2002). “Surface free energy of asphalt-aggregate system and performance analysis of asphalt concrete.” Ph.D. dissertation, Civil Engineering, Texas A&M Univ., College Station, TX.
Estakhri, C., Button, J., and Alvarez, A. E. (2010). Field and laboratory investigation of warm mix asphalt in Texas, Texas A&M Univ., College Station, TX.
Eurovia Services. (2011). 〈www.eurovia.com/en/produit/135.aspx〉 (Mar. 5, 2008).
Fowkes, F. M. (1964). “Attractive forces at interfaces.” Ind. Eng. Chem., 56(12), 40–52.
Good, R. J., and Van Oss, C. J. (1971). “The modern theory of contact angle and the hydrogen bond components of surface energies.” Modern approach to wettability, Plenum Press, New York.
Hefer, A. W., Bhasin, A., and Little, D. N. (2006). “Bitumen surface energy characterization using a contact angle approach.” J. Mater. Civ. Eng.JMCEE7, 18(6), 759–767.
Hossain, Z., Bhudhala, A., Zaman, M., O’Rear, E., Cross, C., and Lewis, S. (2009). “Evaluation of the use of warm mix asphalt as a viable paving material in the United States.” Cooperative Agreement: DTFH61-06-H-00044: Task 3, College of Engineering, Univ. of Oklahoma, Norman, OK.
Howson, J., Masad, E., Bhasin, A., and Branco, V. C. (2007). “System for the evaluation of moisture damage using fundamental material.” Rep. No. FHWA/TX-07/0-4524-01-1, Texas Transportation Institute, Texas A&M Univ., College Station, TX.
Hurley, G. C., and Prowell, B. D. (2005a). “Evaluation of Sasobit for use in warm mix asphalt.” NCAT Rep. 05-06, National Center for Asphalt Technology, Auburn, AL.
Hurley, G. C., and Prowell, B. D. (2005b). “Evaluation of aspha-minfi zeolite for use in warm mix asphalt.” NCAT Rep. 05-04, National Center for Asphalt Technology, Auburn, AL.
Kiggundu, B. M., and Roberts, F. L. (1988). “Stripping in HMA mixtures: State-of-the-art and critical review of test methods.” Rep. No. 88–02, National Center for Asphalt Technology, Auburn Univ., Auburn, GA.
Mercado, A. E. (2007). “Influence of fundamental material properties and air void structure on moisture damage of asphalt mixes.” Ph.D. dissertation, Civil Engineering, Texas A&M Univ., College Station, TX.
Peltonen, P. V. (1992). “Road aggregate choice based on silicate quality and bitumen adhesion.” J. Transp. Eng.JTPEDI, 118(1), 50–61.
Robertson, E. R. (1991). “Chemical properties of asphalt and their relationship to pavement performance.” Strategic Research Highway Program (SHRP) Rep. 91-510, National Research Council, Washington, DC.
Salem (2003). “Warm mix asphalt shows promise for cost reduction, environmental benefit.” Centerline, Asphalt Pavement Association of Oregon, Salem, OR.
Sampath, A. (2010). “Comprehensive evaluation of four warm asphalt mixture regarding viscosity, tensile strength, moisture sensitivity, dynamic modulus and flow number.” M.S. thesis, Graduate College, Univ. of Iowa, Iowa City, IA.
Sasobit Technology. (2011). “Sasol wax.” 〈http://www.sasolwax.com/Sasobit_Technology.html〉, (Jan. 18, 2011).
Schapery, R. A. (1984). “Correspondence principles and a generalized j integral for large deformation and fracture analysis of viscoelastic media.” Int. J. Fract.IJFRAP, 25(3), 195–223.
Shah, B. (2003). “Evaluation of moisture damage within asphalt concrete mixes.” M.S. thesis, Texas A&M Univ., College Station, TX.
Shihui, S., Ho-Ming, C., and Hai, H. (2010). “Characterization of fatigue and healing in asphalt binders.” J. Mater. Civ. Eng.JMCEE7, 22(9), 846–852.
Tarrer, A. R., and Wagh, V. (1991). “The effect of the physical and chemical characteristics of the aggregate on bonding.” SHRP-A/UIR-91-507, Strategic Highway Research Program, National Research Council, Washington, DC.
Wasiuddin, N. M., Howell, D. C., Fogle, C. M., Zaman, M. M., and O’Rear, E. A. (2006). “Acid-base characteristics of an asphalt binder with and without anti-strip additives.” Proc., Airfield and Highway Pavements Conference, ASCE, Reston, VA.
Wasiuddin, N. M., Zaman, M. M., and O’Rear, E. A. (2008). “Effect of Sasobit and aspha-min on wettability and adhesion between asphalt binders and aggregates.” Transportation Research Record 2051, Transportation Research Board, Washington, DC, 80–89.
Wilhelmy, L. (1863). “Über die Abhangigkeit der Capillaritats-Constanten des Alkohols von Substanz und Gestalt des benetzten festen Körpers.” Ann. Phys. (Berlin)ANPYA2, 195(6), 177–217 (in German).
Witczak, M. W., Kaloush, K., Pellinen, T., and El-Basyouny, M. (2002). “Appendix A: Test method for dynamic modulus of asphalt concrete mixtures for permanent deformation.” Transportation Research Record 465, Transportation Research Board, National Cooperative Highway Research Program (NCHRP), National Research Council, Washington, DC.
Zaumanis, M. (2010). “Warm mix asphalt investigation.” M.S. thesis, Dept. of Civil Engineering, Technical Univ. of Denmark, Kgs. Lyngby, Denmark.

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Go to Journal of Materials in Civil Engineering
Journal of Materials in Civil Engineering
Volume 24Issue 7July 2012
Pages: 889 - 897

History

Received: Jul 19, 2011
Accepted: Dec 15, 2011
Published online: Dec 20, 2011
Published in print: Jul 1, 2012

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Authors

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Associate Professor, Dept. of Civil Engineering, Univ. of Guilan, P. O. Box 3756, Rasht, Iran (corresponding author). E-mail: [email protected]
Graduate Student, Dept. of Civil Engineering, Univ. of Guilan, Rasht, Iran. E-mail: [email protected]
Gh. H. Hamedi, M.Sc. [email protected]
Dept. of Civil Engineering, Univ. of Guilan, Rasht, Iran. E-mail: [email protected]

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