TECHNICAL PAPERS
May 7, 2011

Effect of Fly Ash and PVA Fiber on Microstructural Damage and Residual Properties of Engineered Cementitious Composites Exposed to High Temperatures

Publication: Journal of Materials in Civil Engineering
Volume 23, Issue 12

Abstract

This paper discusses the influence of high volumes of fly ash and micro polyvinyl alcohol (PVA) fibers on the fire resistance and microstructure of engineered cementitious composites (ECC). Composites containing two different contents of fly ash as a replacement for cement (55 and 70% by weight of total cementitious materials) are examined. To determine the effects of microfibers and ultrahigh ductility of ECC, ECC matrix mixtures of similar composition except PVA fiber are also produced and tested for the fire resistance. The mixtures are exposed to temperatures up to 800°C for one hour. Fire resistances of the mixtures are then quantified in terms of the residual mechanical properties (strength, stress-strain curve, deflection, and stiffness) and mass loss. The role of PVA fibers and fly ash is discussed through the analysis of microstructure and fiber-matrix interactions as a function of heat treatment. The microstructural characterization is examined before and after exposure to fire deterioration by using scanning electron microscopy and the pore size distribution is obtained by mercury intrusion porosimetry. Results indicate that adding micro PVA fiber to the ECC matrix substantially improves the fire resistance and eliminates the explosive spalling behaviors of the ECC matrix. Fire resistance of ECC mixtures is further improved with the increase of fly ash content.

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Acknowledgments

The authors gratefully acknowledge the financial assistance of the Scientific and Technical Research Council (TUBITAK) of Turkey provided under Project: UNSPECIFIEDMAG-108M495, Gaziantep University Scientific Research Centre provided under Project: MF.10.09, The Council of Higher Education of Turkey, and the Natural Sciences and Engineering Research Council (NSERC)NSERC of Canada, the Canada Research Chair Program. Support from the U.S. National Science Foundation (NSFNSF CI-Team OCI 0636300) for international collaborative research on ECC is gratefully acknowledged.

References

ASTM. (1994). “Standard specification for coal fly ash and raw or calcined natural pozzolan for the use of mineral admixtures in portland cement concrete.” C618, West Conshohocken, PA.
Chan, Y. N., Luo, X., and Sun, W. (2000). “Compressive strength and pore structure of high-performance concrete after exposure to high temperature up to 800°C.” Cement Concrete Res., 30(2), 247–251.
Chan, Y. N. S., Peng, G. F., and Anson, M. (1999). “Fire behavior of high performance concrete made with silica fume at different moisture contents.” ACI Mater. J., 96(3), 405–409.
Dias, W. P. S., Khoury, G. A., and Sullivan, P. J. E. (1990). “Mechanical properties of hardened cement paste exposed to temperatures up to 700°C (1292°F).” ACI Mater. J., 87(2), 160–166.
Gowripalan, N., Salonga, P., and Dolan, C. (1997). “Residual strength of HPC subjected to high temperatures.” HPC: Design and materials and recent advances in concrete technology, ACI SP-172, American Concrete Institute, Detroit, MI, 171–191.
Kalifa, P., Menneteau, F. D., and Quenard, D. (2000). “Spalling and pore pressure in HPC at high temperatures.” Cement Concrete Res., 30(12), 1915–1927.
Khoury, G. A. (1992). “Compressive strength of concrete at high temperatures: A reassessment.” Mag. Concrete Res., 44(161), 291–309.
Khoury, G. A., Grainger, B. N., and Sullivan, P. J. E. (1985). “Transient thermal strain of concrete: Literature review, conditions within specimen and behavior of individual constituents.” Mag. Concrete Res., 37(132), 131–144.
Kunieda, M., and Rokugo, K. (2006). “Recent progress on HPFRCC in Japan: Required performance and applications.” J. Adv. Concr. Technol., 4(1), 19–33.
Lam, L., Wong, Y. L., and Poon, C. S. (1998). “Effect of fly ash and silica fume on compressive and fracture behaviors of concrete.” Cement Concrete Res., 28(2), 271–280.
Lepech, M. D., and Li, V. C. (2008). “Large scale processing of engineered cementitious composites.” ACI Mater. J., 105(4), 358–366.
Li, V. C. (1998). “ECC-tailored composites through micromechanical modeling.” Proc., Int. Symp. on Fiber Reinforced Concrete: Present and the Future, CSCE, Montreal, 64–97.
Li, V. C. (2003). “On engineered cementitious composites (ECC)–A review of the material and its applications.” Adv. Concrete Technol., 1(3), 215–230.
Li, V. C., Wang, S., and Wu, C. (2001). “Tensile strain-hardening behavior of PVA-ECC.” ACI Mater. J., 98(6), 483–492.
Mohamedbhai, G. T. G. (1986). “Effect of exposure time and rates of heating and cooling on residual strength of heated concrete.” Mag. Concrete Res., 38(136), 151–158.
Nasser, K. W., and Marzouk, H. M. (1979). “Properties of mass concrete containing fly ash at high temperatures.” ACI Mater. J., 76(4), 537–551.
Nishida, A., Yamazaki, N., Inoue, H., Schneider, U., and Diederichs, U. (1995). “Study on the properties of high strength concrete with short polypropylene fibers for spalling resistance.” Proc., Int. Symp. on Concrete Under Severe Environment, Vol. 2, K. Sakai, N. Banthia, and O. E. Gjorv, eds., 1141–1150.
Petzold, A., and Rohr, M. (1970). Concrete for high temperatures, McLaren and Sons, London.
Phan, L. T. (1996). “Fire performance of high strength concrete: A report of the state-of-the-art.” U.S. Dept. of Commerce, Building and Fire Research Laboratory, NIST, Gaithersburg, MD.
Poon, C. S., Azhar, S., Anson, M., and Wong, Y. L. (2003). “Performance of metakaolin concrete at high temperatures.” Cement Concrete Res., 25(1), 83–9.
Poon, C. S., Lam, L., and Wong, Y. L. (1999). “Effects of fly ash and silica fume on interfacial porosity of concrete.” J. Mater. Civ. Eng., 11(3), 197–205.
Poon, C. S., Shui, Z. H., and Lam, L. (2004). “Compressive behavior of fiber reinforced high-performance concrete subjected to elevated temperatures.” Cement Concrete Res., 34(12), 2215–2222.
Rostasy, R. S., Weiss, R., and Wiedemann, G. (1980). “Changes of pore structure of cement mortar due to temperatures.” Cement Concrete Res., 10(2), 157–164.
Şahmaran, M., Lachemi, M., and Li, V. C. (2010). “Assessing the mechanical properties and microstructure of fire-damaged engineered cementitious composites.” ACI Mater. J., 107(3), 297–304.
Şahmaran, M., and Li, V. C. (2009). “Durability properties of micro-cracked ECC containing high volumes fly ash.” Cement Concrete Res., 39(11), 1033–1043.
Şahmaran, M., Yaman, I. O., and Tokyay, M. (2007). “Development of high volume low-lime and high-lime fly-ash-incorporated self consolidating concrete.” Mag. Concrete Res., 59(2), 97–106.
Sarvaranta, L., and Mikkola, E. (1994a). “Fibre mortar composites in fire conditions.” Fire Mater., 18(1), 45–50.
Sarvaranta, L., and Mikkola, E. (1994b). “Fibre mortar composites under fire conditions: Effects of ageing and moisture content of specimens.” Mater. Struct., 27(9), 532–538.
Taylor, H. F. W. (1964). The chemistry of cements, Academic Press, London.
Univ. of Michigan, ACE MRL. (2008). “Some ECC applications.” 〈http://ace-mrl.engin.umich.edu/NewFiles/eccapp.html〉 (Oct. 11, 2010).
Wang, S., and Li, V. C. (2007). “Engineered cementitious composites with high-volume fly ash.” ACI Mater. J., 104(3), 233–241.
Wu, B., Su, X. P., Li, U., and Yuan, J. (2002). “Effect of high temperature on residual mechanical properties of confined and unconfined high strength concrete.” ACI Mater. J., 99(4), 399–407.
Xu, Y., Wong, Y. L., Poon, C. S., and Anson, M. (2001). “Impact of high temperature on PFA concrete.” Cement Concrete Res., 31(7), 1065–1073.
Xu, Y., Wong, Y. L., Poon, C. S., and Anson, M. (2003). “Influence of PFA on cracking of concrete and cement paste after exposure to high temperatures.” Cement Concrete Res., 33(12), 2009–2016.
Yang, E., Şahmaran, M., Yang, Y., and Li, V. C. (2009). “Rheological control in the production of engineered cementitious composites.” ACI Mater. J., 106(4), 357–366.
Yang, E. H., Yang, Y., and Li, V. C. (2007). “Use of high volumes of fly ash to improve ECC mechanical properties and material greenness.” ACI Mater. J., 104(6), 620–628.
Yigang, X., Wong, Y. L., Poon, C. S., and Anson, M. (2000). “Residual properties of PFA concrete subjected to high temperatures.” Proc., Int. Symp. on High Performance Concrete.

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Go to Journal of Materials in Civil Engineering
Journal of Materials in Civil Engineering
Volume 23Issue 12December 2011
Pages: 1735 - 1745

History

Received: Feb 4, 2011
Accepted: May 6, 2011
Published online: May 7, 2011
Published in print: Dec 1, 2011

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Authors

Affiliations

Mustafa Şahmaran [email protected]
Associate Professor, Dept. of Civil Engineering, Gaziantep Univ., Gaziantep, Turkey (corresponding author). E-mail: [email protected]
Erdoğan Özbay
Postdoctoral Fellow, Ryerson Univ., Dept. of Civil Engineering, Toronto, and Assistant Professor, Dept. of Civil Engineering, Mustafa Kemal Univ., Iskenderun, Hatay, Turkey.
Hasan E. Yücel
Ph.D. candidate, Dept. of Civil Engineering, Gaziantep Univ., Gaziantep, Turkey.
Mohamed Lachemi
Professor, Ryerson Univ., Dept. of Civil Engineering, Toronto.
Victor C. Li
Professor, Dept. of Civil and Environmental Engineering, Univ. of Michigan, Ann Arbor, MI.

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