TECHNICAL PAPERS
Feb 16, 2011

Influence of Metakaolin on Resistivity of Cement Mortar to Magnesium Chloride Solution

Publication: Journal of Materials in Civil Engineering
Volume 23, Issue 9

Abstract

An experimental study for the resistance of mortar paste specimens incorporating 0, 5, 10, 15, 20, 25, and 30% metakaolin (Mk, produced by firing kaolin at 820°C for 2 h) to the magnesium chloride solution was reported. Results confirmed that mortar specimens with a high replacement level of metakaolin showed higher resistance to magnesium solution. The reduction of calcium hydroxide and the increase of secondary calcium silicate hydrate (CSH) in the cement matrix results from the pozzolanic reaction of Mk. The compressive strength values of the blended ordinary portland cement (OPC) mortars specimens improved relative to those containing no Mk, up to 25% by weight OPC substitution, and then decreased up to 30% by weight Mk. Scanning electron microscope microstructures indicate a good improvement for the matrix structure of the blended cement mortars, in which a denser structure was observed.

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References

Ambroise, J., Maximilien, S., and Pera, J. (1994). “Properties of metakaolin blended cements.” Adv. Cem. Based Mater., 1, 161–168.
Ambroise, J., Murat, M., and Pera, J. (1985). “Hydration reaction and hardening of calcined clays and related minerals. V. Extension of the research and general conclusions.” Cem. Concr. Res., 15, 261–268.
Asbridge, A. H., Chadbourn, G. A., and Page, C. L. (2001). “Effects of metakaolin and the interfacial transition zone on the diffusion of chloride ions through cement mortars.” Cem. Concr. Res., 31(11), 1567–1572.
Asbridge, A. H., Page, C. L., and Page, M. M. (2002). “Effects of metakaolin, water/binder ratio and interfacial transition zones on the microhardness of cement mortars.” Cem. Concr. Res., 32(9), 1365–1369.
ASTM. (2007). “Standard test method for compressive strength of hydraulic cement mortars.” C109M-07, West Conshohocken, PA.
Badogiannis, E., and Tsivilis, S. (2009). “Exploitation of poor Greek kaolins: Durability of metakaolin concrete.” Cem. Concr. Compos., 31(2), 128–133.
Boddy, A., Hooton, R. D., and Gruber, K. A. (2001). “Long-term testing of the chloride-penetration resistance of concrete containing high-reactive metakaolin.” Cem. Concr. Res., 31(5), 759–765.
Cachim, P., Velosa, A. L., and Rocha, F. (2010). “Effect of Portuguese metakaolin on hydraulic lime concrete using different curing conditions.” Constr. Build. Mater., 24, 71–78.
Cohen, M. D., and Bentur, A. (1988). “Durability of portland cement–silica fume pastes in magnesium sulfate and sodium sulfate solutions.” ACI Mater. J., 85(3), 148–157.
Crennan, J. M., Dyczek, J. R. L., and Taylor, H. F. W. (1972). “Quantitative phase compositions of autoclaved cement-quartz cubes.” Cem. Concr. Res., 2(3), 277–289.
Dhir, R. K., and Jones, M. R. (1999). “Development of chloride-resisting concrete using fly ash.” Fuel, 78, 137–142.
Egyptian Organization for Standardization (EOS). (1992). “Concrete building units used in non load and load bearing walls.” Egyptian Standards 1292, Cairo, Egypt.
Gruber, K. A., Ramlochan, T., Boddy, A., Hooton, R. D., and Thomas, M. D. A. (2001). “Increasing concrete durability with high-reactive metakaolin.” Cem. Concr. Compos., 23(6), 479–484.
Janotka, I., Puertas, F., Palacios, M., Kuliffayová, M., and Varga, C. (2010). “Metakaolin sand–blended-cement pastes: Rheology, hydration process and mechanical properties.” Constr. Build. Mater., 24(5), 791–802.
Kakali, G., Perraki, T., Tsivilis, S., and Badogiannis, E. (2001). “Thermal treatment of kaolin: The effect of mineralogy on the pozzolanic activity.” Appl. Clay Sci., 20, 73–80.
Khatib, J. M., and Wild, S. (1996). “Pore size distribution of metakaolin paste.” Cem. Concr. Res., 26, 1545–1553.
Kim, H. S., Lee, S. H., and Moon, H. Y. (2007). “Strength properties and durability aspects of high strength concrete using Korean metakaolin.” Constr. Build. Mater., 21, 1229–1237.
Klimesch, D. S., and Ray, A. (1997). “Use of the second-derivative differential thermal curve in the evaluation of cement-quartz pastes with metakaolin addition autoclaved at 180°C.” Thermochim. Acta, 307, 167–176.
Kostuch, J. A., Walters, G. V., and Jones, T. R. (1993). “High performance concretes incorporating metakaolin: A review.” Concrete 2000 II. Economic and durable construction through excellence, R. K. Dhir and M. Roderick Jones, eds., Vol. 2, Dundee University, Scotland, 1799–1811.
Lee, S. T., Moon, H. Y., Hooton, R. D., and Kim, J. P. (2005). “Effect of solution concentrations and replacement levels of metakaolin on the resistance of mortars exposed to magnesium sulfate solutions.” Cem. Concr. Res., 35(7), 1314–1323.
Perá, J., Dejean, J., and Ambroise, J. (1990). “Composite materials with textile reinforcement for use in building construction.” Proc., Int. Symp., P. Hamelin and G. Verchery, eds., Lyon, France, 1, 191–202.
Ramachandran, V. S. (1969). Applications of differential thermal analysis in cement chemistry, Chemical Publishing, New York, 55–80.
Saikia, N., Kato, S., and Kojima, T. (2006). “Thermogravimetric investigation on the chloride binding behaviour of MK-lime paste.” Thermochim. Acta, 444, 16–25.
Siddique, R., and Klaus, J. (2009). “Influence of metakaolin on the properties of mortar and concrete: A review.” Appl. Clay Sci., 43, 392–400.
Taha, A. S., El-Didamony, H., Abo-El-Enein, S. A., and Amer, H. A. (1981). “Physicochemical properties of supersulphated cement pastes.” Zement-Kalk-Gips, 34, 351–353.
Wild, S., Khatib, J. M., and Jones, A. (1996). “Relative strength, pozzolanic activity and cement hydration in superplasticised metakaolin concrete.” Cem. Concr. Res., 26(10), 1537–1544.

Information & Authors

Information

Published In

Go to Journal of Materials in Civil Engineering
Journal of Materials in Civil Engineering
Volume 23Issue 9September 2011
Pages: 1295 - 1301

History

Received: Apr 27, 2010
Accepted: Feb 15, 2011
Published online: Feb 16, 2011
Published in print: Sep 1, 2011

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Authors

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H. M. Khater [email protected]
Housing and Building National Research Centre (HBNRC), 87 El-Tahreer St., Dokki, Giza, P.O. Box 1770, Cairo, Egypt. E-mail: [email protected]

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