TECHNICAL PAPERS
Sep 27, 2010

Influence of the Oxidation Process of Carbon Material on the Mechanical Properties of Cement Mortars

Publication: Journal of Materials in Civil Engineering
Volume 23, Issue 3

Abstract

The present research investigates how the addition of processed carbon materials affects the mechanical properties of cement mortars. Five types of oxidation treatments (air at 250°C, air at 410°C, ozone, H2O2, and HNO3) were applied to graphite powder, powdered carbon fiber, and short carbon fiber to assess the influence of the modification of the carbon material surface in the interaction between cement paste and carbon material. The best oxidation treatment in terms of mechanical strength improvement was oxidation by air at 410°C because this procedure yielded the highest amount of oxygen surface functional groups, thus producing a better interaction with cement paste. Ozone treatment has also been shown to produce a high level of improvement in mechanical properties, but in this case the properties are improved because of the rough surface of the carbon materials.

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Acknowledgments

The writers would like to thank Spain’s Ministerio de Educación y Ciencia and Ministerio de Ciencia e Innovación for the support provided through projects UNSPECIFIEDBIA2006-10703 and UNSPECIFIEDMAT2009-10866, respectively. The writers also greatly appreciate the help given by J. Rivera-Utrilla from the Inorganic Chemistry Department of the Univ. of Granada (Spain). E. Zornoza would like to thank Spain’s Ministerio de Ciencia e Innovación of Spanish Government for financial support through the Juan de la Cierva Program.

References

Brewis, D., Comyn, J., Fowler, J. R., Briggs, D., and Gibson, V. A. (1979). “Surface treatments of carbon-fibers studied by X-Ray photoelectron-spectroscopy.” Fibre Sci. Technol., 12(1), 41–52.
Chen, P. W., Fu, X. L., and Chung, D. D. L. (1997). “Microstructural and mechanical effects of latex, methylcellulose, and silica fume on carbon fiber reinforced cement.” ACI Mater. J., 94(2), 147–155.
Chung, D. D. L. (2000). “Cement reinforced with short carbon fibers: A multifunctional material.” Composites Part B, 31(6-7), 511–526.
Chung, D. D. L. (2005). “Dispersion of short fibers in cement.” J. Mater. Civ. Eng., 17(4), 379–383.
Cuervo, M. R., et al. (2008). “Effect of carbon nanofiber functionalization on the adsorption properties of volatile organic compounds.” J. Chromatogr. A, 1188(2), 264–273.
Donnet, J. B., and Ehrburger, P. (1977). “Carbon fibre in polymer reinforcement.” Carbon, 15(3), 143–152.
Fu, X., Lu, X., and Chung, D. D. L. (1996a). “Improving the bond strength between carbon fiber and cement by fiber surface treatment and polymer addition to cement mix.” Cem. Concr. Res., 26(7), 1007–1012.
Fu, X., Lu, W., and Chung, D. D. L. (1996b). “Improving the tensile strength properties of carbon fiber reinforced cement by ozone treatment of the fiber.” Cem. Concr. Res., 26(10), 1485–1488.
Fu, X., Lu, X., and Chung, D. D. L. (1998a). “Improving the strain-sensing ability of carbon fiber-reinforced cement by ozone treatment of the fibers.” Cem. Concr. Res., 28(2), 183–187.
Fu, X., Lu, W., and Chung, D. D. L. (1998b). “Ozone treatment of carbon fiber for reinforcing cement.” Carbon, 36(9), 1337–1345.
Ivorra, S., Garcés, P., Catalá, G., Andión, L. G., and Zornoza, E. (2010). “Effect of silica fume particle size on mechanical properties of short carbon fiber reinforced concrete.” Mater. Des., 31(3), 1553–1558.
Lee, J. S., and Kang, T. J. (1997). “Changes in physico-chemical and morphological properties of carbon fiber by surface treatment.” Carbon, 35(2), 209–216.
Li, J., Vergne, M. J., Mowles, E. D., Zhong, W. H., Hercules, D. M., and Lukehart, C. M. (2005). “Surface functionalization and characterization of graphitic carbon nanofibers (GCNFs).” Carbon, 43(14), 2883–2893.
Rand, B., and Robinson, R. (1977). “Surface characteristics of carbon fibres from PAN.” Carbon, 15(4), 257–263.
Ruiz-Martinez, J., Ramos-Fernandez, E. V., Sepulveda-Escribano, A., and Rodriguez-Reinoso, F. (2007). “Effect of thermal treatments on the surface chemistry of oxidized activated carbons.” Stud. Surf. Sci. Catal., 160, 129–136.
Serrano-Ruiz, J. C., Ramos-Fernandez, E. V., Silvestre-Albero, J., Sepulveda-Escribano, A., and Rodriguez-Reinoso, F. (2008). “Preparation and characterization of CeO2 highly dispersed on activated carbon.” Mater. Res. Bull., 43(7), 1850–1857.
Sugama, T., Kukacka, L. E., Carciello, N., and Galen, B. (1988). “Oxidation of carbon fiber surfaces for improvement in fiber-cement interfacial bond at a hydrothermal temperature of 300°C.” Cem. Concr. Res., 18(2), 290–300.
Sugama, T., Kukacka, L. E., Carciello, N., and Stathopoulos, D. (1989). “Interfacial reactions between oxidized carbon fibers and cements.” Cem. Concr. Res., 19(3), 355–365.
Vickers, P. E., Watts, J. F., Perruchot, C., and Chehimi, M. M. (2000). “The surface chemistry and acid-base properties of a PAN-based carbon fibre.” Carbon, 38(5), 675–689.
Xu, B., Wang, X. S., and Lu, Y. (2006). “Surface modification of polyacrylonitrile-based carbon fiber and its interaction with imide.” Appl. Surf. Sci., 253(5), 2695–2701.
Xu, Y., and Chung, D. D. L. (1999). “Carbon fiber reinforced cement improved by using silane-treated carbon fibers.” Cem. Concr. Res., 29(5), 773–776.
Zhou, J. H., Sui, Z. J., Li, P., Chen, D., Dal, Y. C., and Yuan, W. K. (2006). “Structural characterization of carbon nanofibers formed from different carbon-containing gases.” Carbon, 44(15), 3255–3262.

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Go to Journal of Materials in Civil Engineering
Journal of Materials in Civil Engineering
Volume 23Issue 3March 2011
Pages: 321 - 329

History

Received: Sep 11, 2009
Accepted: Sep 23, 2010
Published online: Sep 27, 2010
Published in print: Mar 1, 2011

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Dept. Ingeniería de la Construcción, Obras Públicas e Infraestructura Urbana, Univ. de Alicante, Carretera de San Vicente, s/n, 03690 Alicante, Spain. E-mail: [email protected]
E. V. Ramos-Fernández [email protected]
Dept. Química Inorgánica, Univ. de Alicante, Carretera de San Vicente, s/n, 03690 Alicante, Spain. E-mail: [email protected]
Dept. Ingeniería de la Construcción, Obras Públicas e Infraestructura Urbana, Univ. de Alicante, Carretera de San Vicente, s/n, 03690 Alicante, Spain. E-mail: [email protected]
L. G. Andión [email protected]
Dept. Ingeniería de la Construcción, Obras Públicas e Infraestructura Urbana, Univ. de Alicante, Carretera de San Vicente, s/n, 03690 Alicante, Spain. E-mail: [email protected]
Dept. Ingeniería de la Construcción, Obras Públicas e Infraestructura Urbana, Univ. de Alicante, Carretera de San Vicente, s/n, 03690 Alicante, Spain (corresponding author). E-mail: [email protected]

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