Relationship between Molecular Compositions and Rheological Properties of Neat Asphalt Binder at Low and Intermediate Temperatures

The main objective of this study was to establish the relationship between asphalt binder deformation properties at intermediate and low temperatures, its molecular compositions, and mix performance. To achieve this objective, nine straight binders obtained from two asphalt suppliers were tested using the ductility and the direct tensile tests. To assess the results of these tests, selected asphalt binders were evaluated using high pressure gel permeation chromatography (HP-GPC), differential scanning calorimetry (DSC), and dynamic mechanical analysis. Measurements showed that an inverse correlation exists between binder ductility at intermediate temperatures and failure strain at low temperatures. In other words, a binder that provides high ductility at intermediate temperatures would be characterized by poor elongation properties at low temperatures. This trend was related to the binder molecular compositions as characterized by HP-GPC. An increase in the binder content of low molecular weight results in an increase in its ductility at intermediate temperatures. However, an increase in paraffinic maltene content results in the binder tending to crystallize at higher temperatures as it approaches the glassy region. This was confirmed through DSC measurements, which showed that an increase in crystalline fractions may have a negative impact on the binder stiffness at low temperatures. In general, physical properties of the binder can be strongly linked to its molecular constituents. In addition, there was a positive correlation between the binder ductility and the measured tensile strength of the mixture as well as its strain at failure. Using a binder with a high ductility resulted in a mixture with greater indirect tensile strength and a stronger ability to resist cracking at intermediate temperatures.