Durability and Environmental Performance of Alkali-Activated Tungsten Mine Waste Mud Mortars
Publication: Journal of Materials in Civil Engineering
Volume 22, Issue 9
Abstract
Some authors argue that new binders are needed to replace ordinary portland cement (OPC) for enhanced environmental and durability performance. Alkali-activated binders have emerged as an alternative to OPC binders, which seem to have superior durability and environmental impact. This paper report results of a research project on the development of alkali-activated binders using waste mud from a tungsten mine. Abrasion and acid resistance of two ordinary portland cement (OPC) strength class concrete mixtures (C20/25 and C30/37) and several tungsten mine waste mud (TMWM) mixtures were evaluated. Acid resistance was performed by submitting samples to solutions of sulfuric acid, nitric acid, and hydrochloric acid, results of weight loss are reported. Abrasion resistance was assessed by the mass loss of cubic specimens when submitted to 1,000 rotations with the Los Angeles apparatus test machine. This study indicates that TMWM binders possess higher acid and abrasion resistance than OPC based concrete mixtures. The environmental assessment of the TMWM binders shows it can be considered an inert material which indicates that it could be used as a building material.
Get full access to this article
View all available purchase options and get full access to this article.
References
Allahverdi, A., and Škvára, F. (2001a). “Nitric acid attack on hardened paste of geopolymeric cements—Part 1.” Ceramics-Silikaty, 45, 81–88.
Allahverdi, A., and Škvára, F. (2001b). “Nitric acid attack on hardened paste of geopolymeric cements—Part 2.” Ceramics-Silikaty, 45, 143–149.
Allahverdi, A., and Škvára, F. (2005). “Sulfuric acid attack on hardened paste of geopolymer cements. Part 1. Mechanism of corrosion at relatively high concentrations.” Ceramics-Silikaty, 49, 225–229.
Alonso, S., and Palomo, A. (2001). “Alkaline activation of metakaolin and calcium hydroxide mixtures: Influence of temperature, activator concentration and solids ratio.” Mater. Lett., 47, 55–62.
Bakharev, A. T. (2005). “Geopolymeric materials prepared using class F fly ash and elevated temperature curing.” Cem. Concr. Res., 35, 1224–1232.
Barbosa, F., MacKenzie, K., and Thaumaturgo, C. (2000). “Synthesis and characterisation of materials based on inorganic polymers of alumina and silica: Sodium polysialate polymers.” Int. J. Inorganic Polymers, 2, 309–317.
Buchwald, A., Dombrowski, K., and Weil, M. (2005). “The influence of calcium content on the performance of geopolymeric binder especially the resistance against acids.” Proc., World Geopolymer 2005, Geopolymer Green Chemistry and Sustainable Development Solutions, Institute Geopolimere, S. Quentin, France, 35–39.
Deutsche Institut fur Normunge (1984). “German standard methods for the examination of water, waste water and sludge. Sludge and sediments (Group S). Determination of leachability (S4).” DIN 38414-S4, Deutsche Institut fur Normunge, Berlin.
Duxson, P., Provis, J., Lukey, G., and Van Deventer, J. S. J. (2007). “The role of inorganic polymer technology in the development of ‘green concrete’.” Cem. Concr. Res., 37, 1590–1597.
Faury, J. (1958). Le Beton. Influence de ses constituents inerts. Regles á adopter pour sameilheure composition. Sa confection et son transport sur les chantier, 3rd Ed., Dunod, Paris.
Fernandez-Jimenez, A., and Palomo, A. (2005). “Composition and microstructure of alkali activated fly ash binder: Effect of the activator.” Cem. Concr. Res., 35, 1984–1992.
Ghafoori, N., and Surandar, B. M. (1995). “Abrasion resistance of concrete block pavements.” ACI Concrete Int., 1, 25–36.
Hassan, K. E., Brooks, J. J., and Al-Alawi, L. (2001). “Compatibility of repair mortars with concrete in a hot-dry environment.” Cem. Concr. Res., 23, 93–101.
He, C., Makovic, E., and Osbaeck, B. (1995). “Thermal stability and pozzolanic activity of raw and calcined illite.” Appl. Clay Sci., 9, 337–354.
Hu, S., Wang, H., Zhang, G., and Ding, Q. (2008). “Bonding and abrasion resistance of geopolymeric repair material made with steel slag.” Cem. Concr. Compos., 30, 239–244.
MacKenzie, K., Brew, D., Fletcher, R., Nicholson, C., Vagana, R., and Schmucker, M. (2005). “Towards an understanding of the synthesis mechanisms of geopolymer materials.” Proc., World Geopolymer (2005), Geopolymer Green Chemistry and Sustainable Development Solutions, Institute Geopolimere, S. Quentin, France, 41–44.
Neville, A. M. (1997). Properties of concrete, 4th Ed., Wiley, New York.
Pacheco-Torgal, F., Castro Gomes, J. P., and Jalali, S. (2005). “Geopolymeric binder using tungsten mine waste: Preliminary investigation.” Proc., Geopolymer 2005 World Congress, Institute Geopolimere, S. Quentin, France, 93–98.
Pacheco-Torgal, F., Castro Gomes, J. P., and Jalali, S. (2007). “Effect of aggregates on strength and microstructure of geopolymeric mine waste mud binders.” Cem. Concr. Res., 37, 933–941.
Pacheco-Torgal, F., Castro Gomes, J. P., and Jalali, S. (2008a). “Alkali-activated binders: A review part 2 about materials and binders manufacture.” Constr. Build. Mater., 22, 1315–1322.
Pacheco-Torgal, F., Castro Gomes, J. P., and Jalali, S. (2008b). “Investigations of tungsten mine waste geopolymeric binders. Strength and microstructure.” Constr. Build. Mater., 22, 2212–2219.
Pacheco-Torgal, F., Castro Gomes, J. P., and Jalali, S. (2008c). “Investigations on mix design of tungsten mine waste geopolymeric binders.” Constr. Build. Mater., 22, 1939–1949.
Pacheco-Torgal, F., Castro Gomes, J. P., and Jalali, S. (2008d). “Properties of tungsten mine waste geopolymeric binder.” Constr. Build. Mater., 22, 1201–1211.
Pacheco-Torgal, F., and Jalali, S. (2010). “Influence of sodium carbonate addition on the thermal reactivity of tungsten mine waste mud based binders.” Constr. Build. Mater., 24, 56–60.
Pinto, A. (2004). “Metakaolin alkali-activated based binders.” Ph.D. thesis, Univ. of Minho, Guimarães, Portugal.
Pinto, A., Fernandes, P., and Jalali, S. (2002). “Geopolymer manufacture and applications—Main problems when using concrete technology.” Proc., 2002 Geopolymer Conf., Institute Geopolimere, Melbourne, Australia.
Provis, J. (2009). “Immobilisation of toxic wastes in geopolymers.” Geopolymers, structure, processing, properties and applications, J. Provis and J. Van Deventer, eds., Woodhead Publishing Limited Abington Hall, Cambridge, U.K., 421–440.
Salvador, S. (1995). “Pozzolanic properties of flash-calcined kaolinite. A comparative study with soak-calcinated products.” Cem. Concr. Res., 25, 102–112.
Salvador, S. (2000). “A semi-mobile flash dryer/calciner unit manufacture pozzolana from raw clay soils—Application to soil stabilization.” Constr. Build. Mater., 14, 109–117.
Vance, E., and Perera, D. (2009). “Geopolymers for nuclear waste immobilization.” Geopolymers, structure, processing, properties and applications, J. Provis and J. Van Deventer, eds., Woodhead Publishing Limited Abington Hall, Cambridge, U.K., 401–420.
Vinsova, H., Jedinakova-Krizova, V., Gric, L., and Sussmilch, J. (2007). “Immobilization of toxic contaminants into aluminosilicate matrixes.” Proc., 2007 Alkali Activated Materials—Research, Production and Utilization 3rd Conf., Agentura Action, Prague, 735–736.
Weng, L., Sagoe-Crentsil, K., Brown, T., and Song, S. (2005). “Effects of aluminates on the formation of geopolymers.” Mater. Sci. Eng., 117, 163–168.
Wu, H. -C., and Sun, P. (2007). “New building materials from fly ash-based lightweight inorganic polymer.” Constr. Build. Mater., 21, 211–217.
Xu, H., and Van Deventer, J. S. J. (2000). “The geopolymerisation of alumino-silicate minerals.” Int. J. Min. Process., 59, 247–266.
Yip, C. K., Lukey, G. C., and Van Deventer, S. J. S. (2005). “The coexistence of geopolymeric gel and calcium silicate hydrate gel at the early stage of alkaline activation.” Cem. Concr. Res., 35, 1688–1697.
Yip, C. K., and Van Deventer, S. J. S. (2003). “Microanalysis of calcium silicate hydrate gel formed within a geopolymeric binder.” J. Mater. Sci., 38, 3851–3860.
Zivica, V., and Bazja, A. (2001). “Acid attack of cement based materials—A review. Part 1 principle of acid attack.” Cem. Concr. Res., 15, 331–340.
Information & Authors
Information
Published In
Copyright
© 2010 ASCE.
History
Received: Feb 15, 2009
Accepted: Jan 28, 2010
Published online: Aug 13, 2010
Published in print: Sep 2010
Authors
Metrics & Citations
Metrics
Citations
Download citation
If you have the appropriate software installed, you can download article citation data to the citation manager of your choice. Simply select your manager software from the list below and click Download.