Technical Papers
Dec 29, 2017

Influencing Factors in the Removal of High Concentrations of Boron by Electrocoagulation

Publication: Journal of Hazardous, Toxic, and Radioactive Waste
Volume 22, Issue 2

Abstract

Electrocoagulation process efficiency to remove high concentrations of boron from surface water is studied. A glass reactor with a volume of 2.744 L installed with aluminum electrodes is used. The working parameters of initial pH (6, 7.4, 8.5, and 9); initial boron concentrations (1,998, 998, and 500  mg/L); and the presence of supporting electrolytes (15 mM of NaCl, Na2SO4, and KCl) were tested with a current density of 10  mA/cm2 for 90 min. The optimum results were achieved with the initial pH 8.5. The removal efficiencies decreased with the increasing initial boron concentration, and the highest removal rate was measured as 55% with 500  mg/L initial boron concentration. Initial boron concentration and boron removal efficiency are both found negatively correlated with the weight losses from the electrodes. As a result of principal component analysis (PCA), the presence of electrocoagulation supplying ions in the solution, the level of electric current density, and the valance of the electrolyte metal are found as the major factors influencing boron removal efficiency.

Get full access to this article

View all available purchase options and get full access to this article.

References

Bayramoglu, M., Eyvaz, M., and Kobya, M. (2007). “Treatment of textile wastewater by electrocoagulation: Economical evaluation.” Chem. Eng. J., 128(2–3), 155–161.
Brookings, D. G. (1988). Eh-pH diagrams for chemistry, Springer, Berlin.
Cengeloglu, Y., Arslan, G., Tor, A., Kocak, I., and Dursun, N. (2008). “Removal of boron from water by using reverse osmosis.” Sep. Purif. Technol., 64(2), 141–146.
Colak, M. (1995). “The Emet and Kırka Borate Mines (Turkey) 1: Mineralogy and chemistry of the clays. 2: Ceramic applications of their tailing products.” Ph.D. thesis, Fribourg Univ., Fribourg, Switzerland, 213.
Demircivi, P. (2008). “Removal of boron from waste waters by using batch and column systems.” M.Sc. thesis, Institute of Natural and Applied Sciences, İstanbul, Turkey.
Ezechi, E. H., Isa, M. H., Rahman, S., Kutty, M., and Yagup, A. (2014). “Boron removal from produced water using electrocoagulation.” Process Saf. Environ. Prot., 92(6), 509–514.
Ferreiera, O. P., Moraes, S. G., Duran, N., Cornejo, L., and Alves, O. L. (2006). “Evaluation of boron removal from water by hydrotalcite-like compounds.” Chemosphere, 62(1), 80–88.
Golder, A. K., Dhaneesh, V. S., Samantha, A. N., and Ray, S. (2008). “Removal of nickel and boron from platin rinse effluent by electrochemical and chemical techniques.” Chem. Eng. Technol., 31(1), 143–148.
Hakizimana, J. N., et al. (2017). “Electrocoagulation process in water treatment: A review of electrocoagulation modeling approaches.” Desalination, 404, 1–21.
Helvaci, C. (1977). “Geology, mineralogy and geochemistry of the borate deposits and associated rocks at the Emet Valley, Turkey.” Ph.D. thesis, Univ. of Nottingham, Nottingham, U.K., 338.
Karahan, S., Yurdakoc, M., Seki, Y., and Yurdakoc, K. (2006). “Removal of boron from aqueous solution by clays and modified clays.” J. Colloid Inerface Sci., 293(1), 36–42.
Karakas, Z. K., Yilmaz, M. T., and Yilmaz, A. E. (2012). “Boron removal from industrial waste waters by using aluminum sulfate coagulant with chemical methods.” Igdır Uni. J. Inst. Sci. Tech., 2(1), 15–22.
Kluczka, J., Trojanowska, J., Zolotajkın, M., Ciba, J., Turel, M., and Dydo, P. (2007). “Boron removal from wastewater using adsorbents.” Environ. Technol., 28(1), 105–113.
Loizou, E., Kanari, P. N., Kyriacou, G., and Aletrari, M. (2010). “Boron determination in a multi element national water monitoring program: The absence of legal limits.” J. Verbrauch Lebensm., 5(3–4), 459–463.
Mollah, M. Y. A., Schennach, R., Parga, J. R., and Cocke, D. L. (2001). “Electrocoagulation (EC): Science and applications.” J. Hazard. Mater., 84(1), 29–41.
Murray, J. (1995). “A human health risk assessment of boron in drinking water.” Regul. Toxicol. Pharmacol., 22(3), 221–230.
Oren, Y., Linder, C., Daltrophe, N., Mirsky, Y., Skorka, J., and Kedem, O. (2006). “Boron removal from desalinated seawater and brackish water by improved electrodialysis.” Desalination, 199(1–3), 52–54.
Öztürk, N., Kavak, D., and Köre, T. (2008). “Boron removal from aqueous solution by reverse osmosis.” Desalination, 223(1–3), 1–9.
Özyonar, F., and Karagözoglu, M. (2012). “Removal of turbidity from drinking water by electrocoagulation and chemical coagulation.” J. Fac. Eng. Arch. Gazi. Uni., 27(1), 81–89.
Polat, H., Vengosh, A., Pankratov, I., and Polat, M. (2004). “A new methodology for removal of boron from water by coal and fly ash.” Desalination, 164(2), 173–188.
Rajakovic, L. V., and Ristic, M. V. (1996). “Sorption of boric acid and borax by activated carbon impregnated with various compounds.” Carbon, 34(6), 769–774.
Sayıner, G., Kandemirli, F., and Dimoglo, A. (2008). “Evaluation of boron removal by electrocoagulation using iron and aluminum electrodes.” Desalination, 230(1–3), 205–212.
Solak, M., Kılıc, M., Yazıcı, H., and Pakdil, N. (2014). “Economical analysis of the treatment of marble processing wastewaters by electrocoagulation and chemical coagulation process.” DEU J. Eng. Sci., 16(2), 13–26.
SPSS version 24.0 [Computer software]. SPSS, Inc., Chicago.
Toaszewska, B., and Bodzek, M. (2013). “Desalination of geothermal waters using a hybrid UF-RO process. 1: Boron removal in pilot-scale tests.” Desalination, 319, 99–106.
Ugurlu, M. (2004). “Removal of inorganic compounds in paper mill wastewaters by using electrocoagulation.” Gazi Uni. J. Sci., 17(3), 85–99.
WHO (World Health Organization). (1998). “Guidelines for drinking-water quality. Addendum to vol 2. Health criteria and other supporting information.” Boron in drinking water, 2nd Ed., Geneva.
Wolska, J., and Bryjak, M. (2013). “Methods for boron removal from aqueous solutions: A review.” Desalination, 310, 18–24.
Yilmaz, A. E., Boncukcuoglu, R., and Kocakerim, M. M. (2007). “A quantitative comparison between electrocoagulation and chemical coagulation for boron removal from boron-containing solution.” J. Hazard. Mater., 153(1–2), 146–151.
Yılmaz, A. E., Boncukcuoglu, R., Kocakerim, M. M., and Keskinler, B. (2005). “The investigation of parameters effecting boron remocal by electrocoagulation method.” J. Hazard. Mater., B125(1–3), 160–165.
Yilmaz, A. E., Boncukcuoglu, R., Kocakerim, M. M., Yilmaz, M. T., and Paluluoglu, C. (2008). “Boron removal from geothermal waters by electrocoagulation.” J. Hazard. Mater., 153(1–2), 146–151.
Zeboudji, B., Drouiche, N., Lounici, H., Mameri, N., and Ghaffour, N. (2013). “The influence of parameters affecting boron removal by electrocoagulation process.” Sep. Sci. Technol., 48(8), 1280–1288.

Information & Authors

Information

Published In

Go to Journal of Hazardous, Toxic, and Radioactive Waste
Journal of Hazardous, Toxic, and Radioactive Waste
Volume 22Issue 2April 2018

History

Received: Aug 8, 2017
Accepted: Sep 11, 2017
Published online: Dec 29, 2017
Published in print: Apr 1, 2018
Discussion open until: May 29, 2018

Permissions

Request permissions for this article.

Authors

Affiliations

E. Duyusen Güven, Ph.D. [email protected]
Research Assistant, Dept. of Environmental Engineering, Dokuz Eylul Univ., Buca, Izmir 35390, Turkey. E-mail: [email protected]
Erkan Güler, Ph.D. [email protected]
Research Assistant, Dept. of Mining Engineering, Dokuz Eylul Univ., Buca, Izmir 35390, Turkey. E-mail: [email protected]
Görkem Akıncı, Ph.D. [email protected]
Associate Professor, Dept. of Environmental Engineering, Dokuz Eylul Univ., Buca, Izmir 35390, Turkey (corresponding author). E-mail: [email protected]
Ayşenur Bölükbaş [email protected]
Dept. of Environmental Engineering, Dokuz Eylul Univ., Buca, Izmir 35390, Turkey. E-mail: [email protected]

Metrics & Citations

Metrics

Citations

Download citation

If you have the appropriate software installed, you can download article citation data to the citation manager of your choice. Simply select your manager software from the list below and click Download.

Cited by

View Options

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Media

Figures

Other

Tables

Share

Share

Copy the content Link

Share with email

Email a colleague

Share