Prediction of Arsenic Removal by Electrocoagulation: Model Development by Factorial Design
Publication: Journal of Hazardous, Toxic, and Radioactive Waste
Volume 15, Issue 1
Abstract
Model was developed by two-level five-factor full-factorial designed-experiment to predict arsenic removal from contaminated water by electrocoagulation. Five factors, namely arsenic concentration (As), solution volume ; current , electrode area , and current processing time were investigated. Among the factors, arsenic concentration (As) and volume have negative effect, and area , time , and current have positive effect on arsenic removal. Within the studied levels of the factors, variance analysis at 5% significance level indicated that electrode area is not significant in arsenic removal by electrocoagulation. The model predicted reasonably good arsenic removal from low (0.288 mg/L) and high (0.882 mg/L) initial arsenic concentrations in presence of naturally cooccurring solutes in the groundwater. For the range of operating variables studied, optimum removal of arsenic (98.56%) is obtained at higher arsenic concentration (1.18 mg/L), lower volume (1 L), higher current (3 A), and higher current processing time (120 s).
Get full access to this article
View all available purchase options and get full access to this article.
References
Addy, S. A. (2008). “Electrochemical arsenic remediation for rural Bangladesh.” Ph.D. dissertation, Univ. of California, Berkeley, Calif.
American Public Health Association (APHA). (1995). Standard methods for the examination of water and wastewater, 19th Ed., Washington, D.C.
Balasubramanian, N., and Madhavan, K. (2001). “Arsenic removal from industrial effluent through electrocoagulation.” Chem. Eng. Technol., 24(5), 519–521.
Basha, C. A., Selvi, S. J., Ramasamy, E., and Chellammal, S. (2008). “Removal of arsenic and sulphate from the copper smelting industrial effluent.” Chem. Eng. J., 141(1–3), 89–98.
Daniel, C. (1959). “Use of half-normal plots in interpreting factorial two level experiments.” Technometrics, 1(4), 311–342.
Gomes, J. A. G., et al. (2007). “Arsenic removal by electrocoagulation using combined Al-Fe electrode system and charactization of products.” J. Hazard Mater., 139(2), 220–231.
Hansen, H. K., Nunez, P., and Jil, C. (2008). “Removal of arsenic from wastewater by airlift electrocoagulation. Part I: Batch reactor experiments.” Sep. Sci. Technol., 43(1), 212–224.
Hansen, H. K., Nunez, P., Raboy, D., Schippacasse, I., and Grandon, R. (2007). “Electrocoagulation in wastewater containing arsenic: Comparing different process designs.” Electrochim. Acta, 52(10), 3464–3470.
Kartinen, E. O., Jr., and Martin, C. J. (1995). “An overview of arsenic removal processes.” Desalination, 103(1–2), 79–88.
Kim, Y., Kim, C., Choi, I., Rengaraj, S., and Yi, J. (2004). “Arsenic removal using mesoporous alumina prepared via a templating method.” Environ. Sci. Technol., 38(3), 924–931.
Kumar, P. R., Chaudhari, S., Khilar, K. C., and Mahajan, S. P. (2004). “Removal of arsenic from water by electrocoagulation.” Chemosphere, 55(9), 1245–1252.
Martinez-Villafane, J. F., and Montero-Ocampo, C. (2010). “Optimisation of energy consumption in arsenic electro-removal from groundwater by the Taguchi method.” Sep. Purif. Tech., 70, 302–305.
Martinez-Villafane, J. F., Montero-Ocampo, C., and Garcia-Lara, A. M. (2009). “Energy and electrode consumption analysis of electrocoagulation for the removal of arsenic from underground water.” J. Hazard. Mater., 172(2–3), 1617–1622.
Mollah, M. Y. A., Morkovsky, P., Gomes, J. A. G., Kesmez, M., Parga, J., and Cocke, D. L. (2004). “Fundamentals, present and future perspectives of electrocoagulation.” J. Hazard. Mater., 114(1–3), 199–210.
Montgomery, D. C. (1997). “Design and analysis of experiments.” 4th Ed., Wiley, New York, 232–233.
Tallman, D. E., and Shaikh, A. U. (1980). “Redox stability of inorganic arsenic (III) and arsenic (V) in aqueous solution.” Anal. Chem., 52(1), 196–199.
U.S. EPA. (2002). “Implementation guidance for the arsenic rule.” EPA Rep. No. 816-D-02-005, Office of Groundwater and Drinking Water, Cincinnati.
Weng, Y. H., Chaung-Hsieh, L. H., Lee, H. H., Li, K. C., and Huang, C. P. (2005). “Removal of arsenic and humic substances (HSs) by electro-ultrafiltration (EUF).” J. Hazard. Mater. B, 122(1–2), 171–176.
Zouboulis, A. I., and Katsoyiannis, I. (2002). “Removal of arsenates from contaminated water by coagulation-direct filtration.” Sep. Sci. Technol., 37(12), 2859–2873.
Information & Authors
Information
Published In
Copyright
© 2011 ASCE.
History
Received: May 14, 2010
Accepted: Aug 11, 2010
Published online: Aug 31, 2010
Published in print: Jan 2011
Authors
Metrics & Citations
Metrics
Citations
Download citation
If you have the appropriate software installed, you can download article citation data to the citation manager of your choice. Simply select your manager software from the list below and click Download.