TECHNICAL PAPERS
Jul 26, 2010

Removal of Hexachlorobenzene from Kaolin by Electrokinetics Coupled with Cu/Fe PRB

Publication: Journal of Hazardous, Toxic, and Radioactive Waste
Volume 15, Issue 3

Abstract

This study deals with the remediation of clayed soils contaminated with hydrophobic organic compounds (HOCs) by using electrokinetics (EK) coupled with a permeable reactive barrier (PRB) technique. Hexachlorobenzene (HCB) and kaolin were selected as the typical HOCs and clay, respectively, and microscale Cu/Fe particles were synthesized as the functional materials of PRB. Furthermore, Triton X-100 was used as the solubility-enhanced agent to promote the movement and removal of contaminants. Four bench-scale EK tests were conducted with or without Cu/Fe PRB. The results reveal that coupling EK with Cu/Fe PRB greatly promoted the overall removal of HCB from soil, compared with EK alone. Other than the electroosmotic flow, the adsorption/reductive degradation by Cu/Fe PRB may also be responsible for the HCB removal (over 82% of HCB passing by the PRB was removed). Our investigation suggests that the integration of EK and Cu/Fe PRB is of great promise to promote the application of EK technique in the remediation of HOC-contaminated soils.

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Acknowledgments

This work was supported by the National Natural Science Foundation of China (Grants NNSFC20777024 and NNSFC40801114).

References

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Go to Journal of Hazardous, Toxic, and Radioactive Waste
Journal of Hazardous, Toxic, and Radioactive Waste
Volume 15Issue 3July 2011
Pages: 175 - 179

History

Received: Feb 26, 2010
Accepted: Jul 23, 2010
Published online: Jul 26, 2010
Published in print: Jul 1, 2011

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Authors

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Jinzhong Wan [email protected]
Environmental Science Research Institute, Huazhong Univ. of Science and Technology, Wuhan, 430074, P. R. China (corresponding author). E-mail: [email protected]
Zhirong Li
Environmental Science Research Institute, Huazhong Univ. of Science and Technology, Wuhan, 430074, P. R. China.
Songhu Yuan
Environmental Science Research Institute, Huazhong Univ. of Science and Technology, Wuhan, 430074, P. R. China.
Xiaohua Lu
Environmental Science Research Institute, Huazhong Univ. of Science and Technology, Wuhan, 430074, P. R. China.

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