Abstract

During in situ groundwater remediation, reactions occur in a narrow reaction front in which the amendment and contaminant are close enough to mix. Active spreading, in which injection or extraction wells create spatially variable velocity fields, can be used to increase the surface area of the reaction front, thereby enhancing reaction. This study used four active spreading flow fields that are building blocks to more complex remediation hydraulics to evaluate how the flow field and the plume position control contaminant degradation in both homogeneous and heterogeneous aquifers. At the plume scale, reaction depended on mechanical dispersion across the reaction front, which is proportional to both the local velocity and the local contaminant concentration gradient. Mechanical dispersion and, consequently, the amount of degradation, was highest when the reaction front was perpendicular to the local velocity, producing a high local dispersion coefficient. This effect was amplified where flow was diverging due to sharpening of the concentration gradient.

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Data Availability Statement

All data, models, and code generated or used during the study appear or are cited herein.

Acknowledgments

The authors gratefully acknowledge review suggestions from the editor and anonymous referees whose feedback rendered significant advancement to this work. Funding was provided by the National Science Foundation under Grant Nos. EAR-1417005 and EAR-1417017.

References

Aref, H., et al. 2017. “Frontiers of chaotic advection.” Rev. Mod. Phys. 89 (2): 025007. https://doi.org/10.1103/RevModPhys.89.025007.
Bandopadhyay, A., T. Le Borgne, Y. Méheust, and M. Dentz. 2017. “Enhanced reaction kinetics and reactive mixing scale dynamics in mixing fronts under shear flow for arbitrary Damköhler numbers.” Adv. Water Resour. 100 (Feb): 78–95. https://doi.org/10.1016/j.advwatres.2016.12.008.
Bellin, A., G. Severino, and A. Fiori. 2011. “On the local concentration probability density function of solutes reacting upon mixing.” Water Resour. Res. 47 (1): W01514. https://doi.org/10.1029/2010WR009696.
Berkowitz, B., A. Cortis, M. Dentz, and H. Scher. 2006. “Modeling non-Fickian transport in geological formations as a continuous time random walk.” Rev. Geophys. 44 (2): RG2003. https://doi.org/10.1029/2005RG000178.
Chiogna, G., O. A. Cirpka, P. Grathwohl, and M. Rolle. 2011. “Relevance of local compound-specific transverse dispersion for conservative and reactive mixing in heterogeneous porous media.” Water Resour. Res. 47 (7): 11. https://doi.org/10.1029/2010WR010270.
Chiogna, G., D. L. Hochstetler, A. Bellin, P. K. Kitanidis, and M. Rolle. 2012. “Mixing, entropy and reactive solute transport.” Geophys. Res. Lett. 39 (20): L20405. https://doi.org/10.1029/2012GL053295.
Cho, M., F. Solano, N. Thomson, M. Trefry, D. Lester, and G. Metcalfe. 2019. “Field trials of chaotic advection to enhance reagent delivery.” Ground Water Monit. Rem. 39 (3): 23–39. https://doi.org/10.1111/gwmr.12339.
Cirpka, O. A., F. P. J. de Barros, G. Chiogna, M. Rolle, and W. Nowak. 2011. “Stochastic flux-related analysis of transverse mixing in two-dimensional heterogeneous porous media.” Water Resour. Res. 47 (6): 45. https://doi.org/10.1029/2010WR010279.
de Anna, P., M. Dentz, A. Tartakovsky, and T. Le Borgne. 2014. “The filamentary structure of mixing fronts and its control on reaction kinetics in porous media flows.” Geophys. Res. Lett. 41 (13): 4586–4593. https://doi.org/10.1002/2014GL060068.
de Barros, F. P., M. Dentz, J. Koch, and W. Nowak. 2012. “Flow topology and scalar mixing in spatially heterogeneous flow fields.” Geophys. Res. Lett. 39 (8): L08404. https://doi.org/10.1029/2012GL051302.
de Dreuzy, J.-R., J. Carrera, M. Dentz, and T. Le Borgne. 2012. “Time evolution of mixing in heterogeneous porous media.” Water Resour. Res. 48 (6): W06511. https://doi.org/10.1029/2011WR011360.
Deutsch, D., and A. Journel. 1992. GSLIB: Geostatistical software library and user’s guide. New York: Oxford University Press.
Engdahl, N. B., D. A. Benson, and D. Bolster. 2014. “Predicting the enhancement of mixing-driven reactions in nonuniform flows using measures of flow topology.” Phys. Rev. E 90 (5): 051001. https://doi.org/10.1103/PhysRevE.90.051001.
Engdahl, N. B., T. R. Ginn, and G. E. Fogg. 2013. “Scalar dissipation rates in non-conservative transport systems.” J. Contam. Hydrol. 149 (Jun): 46–60. https://doi.org/10.1016/j.jconhyd.2013.03.003.
Gramling, C. M., C. F. Harvey, and L. C. Meigs. 2002. “Reactive transport in porous media: A comparison of model prediction with laboratory visualization.” Environ. Sci. Technol. 36 (11): 2508–2514. https://doi.org/10.1021/es0157144.
Harbaugh, A. W., C. D. Langevin, J. D. Hughes, R. N. Niswonger, and L. F. Konikow. 2017. MODFLOW-2005 version 1.12.00, the U.S. Geological Survey modular groundwater model: US Geological Survey software release. Reston, VA: USGS. https://doi.org/10.5066/F7RF5S7G.
Le Borgne, T., M. Dentz, D. Bolster, J. Carrera, J.-R. de Dreuzy, and P. Davy. 2010. “Non-Fickian mixing: Temporal evolution of the scalar dissipation rate in heterogeneous porous media.” Adv. Water Resour. 33 (12): 1468–1475. https://doi.org/10.1016/j.advwatres.2010.08.006.
Le Borgne, T., M. Dentz, and J. Carrera. 2008a. “Lagrangian statistical model for transport in highly heterogeneous velocity fields.” Phys. Rev. Lett. 101 (9): 090601. https://doi.org/10.1103/PhysRevLett.101.090601.
Le Borgne, T., M. Dentz, and J. Carrera. 2008b. “Spatial Markov processes for modeling Lagrangian particle dynamics in heterogeneous porous media.” Phys. Rev. E 78 (2): 026308. https://doi.org/10.1103/PhysRevE.78.026308.
Le Borgne, T., M. Dentz, and E. Villermaux. 2013. “Stretching, coalescence, and mixing in porous media.” Phys. Rev. Lett. 110 (20): 204501. https://doi.org/10.1103/PhysRevLett.110.204501.
Le Borgne, T., T. R. Ginn, and M. Dentz. 2014. “Impact of fluid deformation on mixing-induced chemical reactions in heterogeneous flows.” Geophys. Res. Lett. 41 (22): 7898–7906. https://doi.org/10.1002/2014GL062038.
Lester, D. R., G. Metcalfe, and M. G. Trefry. 2013. “Is chaotic advection inherent to porous media flow?” Phys. Rev. Lett. 111 (17): 174101. https://doi.org/10.1103/PhysRevLett.111.174101.
Lester, D. R., M. Rudman, G. Metcalfe, M. G. Trefry, A. Ord, and B. Hobbs. 2010. “Scalar dispersion in a periodically reoriented potential flow: Acceleration via Lagrangian chaos.” Phys. Rev. E 81 (4): 046319. https://doi.org/10.1103/PhysRevE.81.046319.
Mays, D. C., and R. M. Neupauer. 2012. “Plume spreading in groundwater by stretching and folding.” Water Resour. Res. 48 (7): W07501. https://doi.org/10.1029/2011WR011567.
Meunier, P., and E. Villermaux. 2010. “The diffusive strip method for scalar mixing in two dimensions.” J. Fluid Mech. 662 (Nov): 134–172. https://doi.org/10.1017/S0022112010003162.
Neupauer, R. M., and D. C. Mays. 2015. “Engineered injection and extraction for in situ remediation of sorbing solutes in groundwater.” J. Environ. Eng. 141 (6): 04014095. https://doi.org/10.1061/(ASCE)EE.1943-7870.0000923.
Neupauer, R. M., L. J. Sather, D. C. Mays, J. P. Crimaldi, and E. J. Roth. 2020. “Contributions of pore-scale mixing and mechanical dispersion to reaction during active spreading by radial groundwater flow.” Water Resour. Res. 56 (7): e2019WR026276. https://doi.org/10.1029/2019WR026276.
Orfanidis, S. J. 1995. Introduction to signal processing. Upper Saddle River, NJ: Prentice-Hall, Inc.
Ou, J.-J., and W. Ranz. 1983. “Mixing and chemical reactions: A contrast between fast and slow reactions.” Chem. Eng. Sci. 38 (7): 1005–1013. https://doi.org/10.1016/0009-2509(83)80021-9.
Perez, L. J., J. J. Hidalgo, A. Puyguiraud, J. Jiménez-Martínez, and M. Dentz. 2020. “Assessment and prediction of pore-scale reactive mixing from experimental conservative transport data.” Water Resour. Res. 56 (6): e2019WR026452. https://doi.org/10.1029/2019WR026452.
Piscopo, A. N., R. M. Neupauer, and D. C. Mays. 2013. “Engineered injection and extraction to enhance reaction for improved in situ remediation.” Water Resour. Res. 49 (6): 3618–3625. https://doi.org/10.1002/wrcr.20209.
Porta, G. M., S. Chaynikov, J.-F. Thovert, M. Riva, A. Guadagnini, and P. M. Adler. 2013. “Numerical investigation of pore and continuum scale formulations of bimolecular reactive transport in porous media.” Adv. Water Resour. 62 (2): 243–253. https://doi.org/10.1016/j.advwatres.2013.09.007.
Raje, D. S., and V. Kapoor. 2000. “Experimental study of bimolecular reaction kinetics in porous media.” Environ. Sci. Technol. 34 (7): 1234–1239. https://doi.org/10.1021/es9908669.
Rodríguez-Escales, P., D. Fernàndez-Garcia, J. Drechsel, A. Folch, and X. Sanchez-Vila. 2017. “Improving degradation of emerging organic compounds by applying chaotic advection in managed aquifer recharge in randomly heterogeneous porous media.” Water Resour. Res. 53 (5): 4376–4392. https://doi.org/10.1002/2016WR020333.
Rolle, M., C. Eberhardt, G. Chiogna, O. A. Cirpka, and P. Grathwohl. 2009. “Enhancement of dilution and transverse reactive mixing in porous media: Experiments and model-based interpretation.” J. Contam. Hydrol. 110 (3–4): 130–142. https://doi.org/10.1016/j.jconhyd.2009.10.003.
Salamon, P., D. Fernàndez-Garcia, and J. J. Gómez-Hernández. 2006. “Modeling mass transfer processes using random walk particle tracking.” Water Resour. Res. 42 (11): W11417. https://doi.org/10.1029/2006WR004927.
Speetjens, M. F. M., G. Metcalfe, and M. Rudman. 2021. “Lagrangian transport and chaotic advection in three-dimensional laminar flows.” Appl. Mech. Rev. 73 (3): 1. https://doi.org/10.1115/1.4050701.
Suthersan, S., C. Divine, and S. Potter. 2009. “Remediating large plumes: Overcoming the scale challenge.” Groundwater Monit. Rem. 29 (1): 45–50. https://doi.org/10.1111/j.1745-6592.2008.01226.x.
Suthersan, S., E. Killenbeck, S. Potter, C. Divine, and M. LeFrancois. 2015. “Resurgence of pump and treat solutions: Directed groundwater recirculation.” Groundwater Monit. Rem. 35 (2): 23–29. https://doi.org/10.1111/gwmr.12114.
Trefry, M. G., D. R. Lester, G. Metcalfe, A. Ord, and K. Regenauer-Lieb. 2012. “Toward enhanced subsurface intervention methods using chaotic advection.” J. Contam. Hydrol. 127 (1–4): 15–29. https://doi.org/10.1016/j.jconhyd.2011.04.006.
Yoon, Y. E., and F. W. Schwartz. 1999. “Oxidative degradation and kinetics of chlorinated ethylenes by potassium permanganate.” J. Contam. Hydrol. 37 (3–4): 343–365. https://doi.org/10.1016/S0169-7722(98)00166-1.
Zhang, P., S. L. DeVries, A. Dathe, and A. C. Bagtzoglou. 2009. “Enhanced mixing and plume containment in porous media under time-dependent oscillatory flow.” Environ. Sci. Technol. 43 (16): 6283–6288. https://doi.org/10.1021/es900854r.

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Go to Journal of Hydrologic Engineering
Journal of Hydrologic Engineering
Volume 27Issue 5May 2022

History

Received: Apr 30, 2021
Accepted: Jan 11, 2022
Published online: Mar 10, 2022
Published in print: May 1, 2022
Discussion open until: Aug 10, 2022

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Lauren J. Sather, Ph.D. [email protected]
Scientist II, West Yost Associates, Lake Forest, CA 92630. Email: [email protected]
Roseanna M. Neupauer, Ph.D., M.ASCE https://orcid.org/0000-0002-4918-810X [email protected]
P.E.
Professor, Univ. of Colorado Boulder, 1111 Engineering Dr., UCB 428, Boulder, CO 80309-0428 (corresponding author). ORCID: https://orcid.org/0000-0002-4918-810X. Email: [email protected]
David C. Mays, Ph.D., M.ASCE https://orcid.org/0000-0002-5218-1670
P.E.
Professor, Univ. of Colorado Denver, Campus Box 113, P.O. Box 173364, Denver, CO 80217-3364. ORCID: https://orcid.org/0000-0002-5218-1670
John P. Crimaldi, Ph.D.
Professor, Univ. of Colorado Boulder, 1111 Engineering Dr., UCB 428, Boulder, CO 80309-0428.
Eric J. Roth, Ph.D.
Postdoctoral Fellow, Univ. of Colorado Anschutz Medical Campus, Aurora, CO 80056.

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Cited by

  • Experiments and Simulations on Plume Spreading by Engineered Injection and Extraction in Refractive Index Matched Porous Media, Water Resources Research, 10.1029/2022WR032943, 59, 2, (2023).
  • A Primer on the Dynamical Systems Approach to Transport in Porous Media, Transport in Porous Media, 10.1007/s11242-022-01811-6, 146, 1-2, (55-84), (2022).

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