Technical Notes
Aug 10, 2018

Synthetic Mining Solutions for Laboratory Testing of Geosynthetic Clay Liners

Publication: Journal of Geotechnical and Geoenvironmental Engineering
Volume 144, Issue 10

Abstract

Geosynthetic clay liners (GCLs) are increasingly used in engineering and environmental applications that include nonstandard solution chemistry. Long-term exposure of geosynthetics to nonstandard solutions in containment facilities, such as heap leach pads, municipal and hazardous solid waste containment, and so on, may cause degradation of bentonite and polymeric components and alter the hydraulic and mechanical properties of GCLs. Leachate collected from full-scale containment facilities has commonly been used in previous studies for field-focused GCL-related experiments. However, due to problems associated with using actual leachates, representative synthetic solutions often are used. A step-by-step procedure for the design, preparation, and verification of representative synthetic mining solutions for laboratory testing on GCLs is described in this study. Recipes for creating three synthetic mining solutions to simulate gold, copper, and bauxite process solutions are presented. The procedure for solution development and prepared solutions were verified via comparison of measured to calculated metals concentrations, which yield concentration differences less than 8% for all three synthetic process solutions.

Get full access to this article

View all available purchase options and get full access to this article.

Acknowledgments

Financial support for this study was provided by the Colloid Environmental Technologies Company (CETCO), Geosynthetic Research Institute (GRI), and Colorado State University (CSU). The opinions, findings, conclusions, or recommendations expressed herein are those of the authors and do not necessarily represent the views of CETCO, GRI, or CSU.

References

Abdelaal, F. B., R. K. Rowe, M. Smith, and R. Thiel. 2011 “OIT depletion in HDPE geomembranes used in contact with solutions having very high and low pH.” In Proc., 14th Pan-American Conf. of Soil Mechanics and Geotechnical Engineering, 2–6. Toronto: Canadian Geotechnical Society.
ASTM. 2011. Standard specification for reagent water. ASTM D1193-06. West Conshohocken, PA: ASTM.
Benson, C. H., A. H. Ören, and W. P. Gates. 2010. “Hydraulic conductivity of two geosynthetic clay liners permeated with a hyperalkaline solution.” Geotext. Geomembr. 28 (2): 206–218. https://doi.org/10.1016/j.geotexmem.2009.10.002.
Benson, C. H., X. Wang, F. W. Gassner, and D. C. F. Foo. 2008. “Hydraulic conductivity of two geosynthetic clay liners permeated with an aluminia residue leachate.” In Proc., Geoamericas, 2–5. Cancun, Mexico: International Geosynthetics Society.
Bouazza, A., and J. J. Bowders. 2010. Geosynthetic clay liners for waste containment facilities, 239. Boca Raton, FL: CRC.
Bradshaw, S. L., C. H. Benson, and T. L. Rauen. 2016. “Hydraulic conductivity of geosynthetic clay liners to recirculated municipal solid waste leachates.” J. Geotech. Geoenviron. Eng. 142 (2): 04015074. https://doi.org/10.1061/(ASCE)GT.1943-5606.0001387.
Gräfe, M., G. Power, and C. Klauber. 2011. “Bauxite residue issues: III. Alkalinity and associated chemistry.” Hydrometallurgy 108 (1–2): 60–79. https://doi.org/10.1016/j.hydromet.2011.02.004.
Griffin, B. A., and J. J. Jurinak. 1973. “Estimation of activity coefficients from the electrical conductivity of natural aquatic systems and soil extracts.” Soil Sci. 116 (1): 26–30. https://doi.org/10.1097/00010694-197307000-00005.
Gulec, S. B., C. H. Benson, and T. B. Edil. 2005. “Effect of acidic mine drainage on the mechanical and hydraulic properties of three geosynthetics.” J. Geotech. Geoenviron. Eng. 131 (8): 937–950. https://doi.org/10.1061/(ASCE)1090-0241(2005)131:8(937).
Gulec, S. B., T. B. Edil, and C. H. Benson. 2004. “Effect of acid mine drainage on the polymer properties of a HDPE geomembrane.” Geosynthetics Int. 11 (2): 60–72. https://doi.org/10.1680/gein.2004.11.2.60.
Guyonnet, D., N. Touze-Foltz, V. Norotte, C. Pothier, G. Didier, H. Gailhanou, and F. Warmont. 2009. “Performance-based indicators for controlling geosynthetic clay liners in landfill applications.” Geotext. Geomembr. 27 (5): 321–331. https://doi.org/10.1016/j.geotexmem.2009.02.002.
Hornsey, W. P., J. Scheirs, W. P. Gates, and A. Bouazza. 2010. “The impact of mining solutions/liquors on geosynthetics.” Geotext. Geomembr. 28 (2): 191–198. https://doi.org/10.1016/j.geotexmem.2009.10.008.
Jeon, H. Y. 2006. “Chemical resistance and transmissivity of nonwoven geotextiles in waste leachate solutions.” Polym. Test. 25 (2): 176–180. https://doi.org/10.1016/j.polymertesting.2005.11.003.
Jo, H. Y., C. H. Benson, C. D. Shackelford, J. M. Lee, and T. B. Edil. 2005. “Long-term hydraulic conductivity of a geosynthetic clay liner permeated with inorganic salt solutions.” J. Geotech. Geoenviron. Eng. 131 (4): 405–417. https://doi.org/10.1061/(ASCE)1090-0241(2005)131:4(405).
Jo, H. Y., T. Katsumi, C. H. Benson, and T. B. Edil. 2001. “Hydraulic conductivity and swelling of nonprehydrated GCLs permeated with single-species salt solutions.” J. Geotech. Geoenviron. Eng. 127 (7): 557–567. https://doi.org/10.1061/(ASCE)1090-0241(2001)127:7(557).
Kashir, M., and E. K. Yanful. 2001. “Hydraulic conductivity of bentonite permeated with acid mine drainage.” Can. Geotech. J. 38 (5): 1034–1048. https://doi.org/10.1139/t01-027.
Katsumi, T., H. Ishimori, A. Ogawa, K. Yoshikawa, K. Hanamoto, and R. Fukagawa. 2007. “Hydraulic conductivity of nonprehydrated geosynthetic clay liners permeated with inorganic solutions and waste leachates.” Soils Found. 47 (1): 79–96. https://doi.org/10.3208/sandf.47.79.
Katsumi, T., H. Ishimori, M. Onikata, and R. Fukagawa. 2008. “Long-term barrier performance of modified bentonite materials against sodium and calcium permeant solutions.” Geotext. Geomembr. 26 (1): 14–30. https://doi.org/10.1016/j.geotexmem.2007.04.003.
Kolstad, D. C., C. H. Benson, T. B. Edil, and H. Y. Jo. 2004. “Hydraulic conductivity of a dense prehydrated GCL permeated with aggressive inorganic solutions.” Geosynthetics Int. 11 (3): 233–241. https://doi.org/10.1680/gein.2004.11.3.233.
Lange, K., R. K. Rowe, and H. Jamieson. 2007. “Metal retention in geosynthetic clay liners following permeation by different mining solutions.” Geosynthetics Int. 14 (3): 178–187. https://doi.org/10.1680/gein.2007.14.3.178.
Lange, K., R. K. Rowe, and H. Jamieson. 2009. “Diffusion of metals in geosynthetic clay liners.” Geosynthetics Int. 16 (1): 11–27. https://doi.org/10.1680/gein.2009.16.1.11.
Lange, K., R. K. Rowe, and H. Jamieson. 2010. “The potential role of geosynthetic clay liners in mine water treatment systems.” Geotext. Geomembr. 28 (2): 199–205. https://doi.org/10.1016/j.geotexmem.2009.10.003.
Mazzieri, F., G. Di Emidio, E. Fratalocchi, M. Di Sante, and E. Pasqualini. 2013. “Permeation of two GCLs with an acidic metal-rich synthetic leachate.” Geotext. Geomembr. 40 (Oct): 1–11. https://doi.org/10.1016/j.geotexmem.2013.07.011.
Norotte, V., G. Didier, D. Guyonnet, and E. Gaucher. 2004. “Evolution of GCL hydraulic performance during contact with landfill leachate.” In Proc., 2nd Symp. on Advances in Geosynthetic Clay Liner Technology West Conshohocken, PA: ASTM.
Petrov, R. J., and R. K. Rowe. 1997. “Geosynthetic clay liner (GCL)-chemical compatibility by hydraulic conductivity testing and factors impacting its performance.” Can. Geotech. J. 34 (6): 863–885. https://doi.org/10.1139/t97-055.
Plumb, R. H. 1999. Characterization of mine leachates and the development of a ground-water monitoring strategy for mine sites. Washington, DC: US Environmental Protection Agency, Office of Research and Development.
Renman, R., W. Jiankang, and C. Jinghe. 2006. “Bacterial heap-leaching: Practice in Zijinshan copper mine.” Hydrometallurgy 83 (1): 77–82. https://doi.org/10.1016/j.hydromet.2006.03.048.
Rosin-Paumier, S., N. Touze-Foltz, and A. Pantet. 2011. “Impact of a synthetic leachate on permittivity of GCLs measured by filter press and oedopermeameter tests.” Geotext. Geomembr. 29 (3): 211–221. https://doi.org/10.1016/j.geotexmem.2010.11.001.
Rowe, R. K., S. Rimal, and H. Sangam. 2009. “Ageing of HDPE geomembrane exposed to air, water and leachate at different temperatures.” Geotext. Geomembr. 27 (2): 137–151. https://doi.org/10.1016/j.geotexmem.2008.09.007.
Ruhl, J. L., and D. E. Daniel. 1997. “Geosynthetic clay liners permeated with chemical solutions and leachates.” J. Geotech. Geoenviron. Eng. 123 (4): 369–381. https://doi.org/10.1061/(ASCE)1090-0241(1997)123:4(369).
Scalia, J., and C. H. Benson. 2010. “Hydraulic conductivity of geosynthetic clay liners exhumed from landfill final covers with composite barriers.” J. Geotech. Geoenviron. Eng. 137 (1): 1–13. https://doi.org/10.1061/(ASCE)GT.1943-5606.0000407.
Shackelford, C. D. 1994. “Waste-soil interactions that alter hydraulic conductivity.” In Hydraulic conductivity and waste contaminant transport in soil, edited by D. E. Daniel and S. J. Trautwein, 111–168. West Conshohocken, PA: ASTM.
Shackelford, C. D., C. H. Benson, T. Katsumi, T. B. Edil, and L. Lin. 2000. “Evaluating the hydraulic conductivity of GCLs permeated with nonstandard liquids.” Geotext. Geomembr. 18 (2–4): 133–161. https://doi.org/10.1016/S0266-1144(99)00024-2.
Shackelford, C. D., G. W. Sevick, and G. R. Eykholt. 2010. “Hydraulic conductivity of geosynthetic clay liners to tailings impoundment solutions.” Geotext. Geomembr. 28 (2): 149–162. https://doi.org/10.1016/j.geotexmem.2009.10.005.
Thiel, R., and M. E. Smith. 2004. “State of the practice review of heap leach pad design issues.” Geotext. Geomembr. 22 (6): 555–568. https://doi.org/10.1016/j.geotexmem.2004.05.002.
Tian, K., C. H. Benson, and W. J. Likos. 2016. “Hydraulic conductivity of geosynthetic clay liners to low-level radioactive waste leachate.” J. Geotech. Geoenviron. Eng. 142 (8): 04016037. https://doi.org/10.1061/(ASCE)GT.1943-5606.0001495.
USEPA. 1992a. Mine site visit: Colosseum mine. Washington, DC: US Environmental Protection Agency, Office of Solid Waste.
USEPA. 1992b. Mine site visit: Newmount gold company rain facility. Washington, DC: US Environmental Protection Agency, Office of Solid Waste.
USEPA. 1999. Characterization of mine leachates and the development of a ground-water monitoring strategy for mine sites, 20460. Washington, DC: US Environmental Protection Agency, Office of Research and Development.
USEPA. 2008. Public review draft, remedial investigation report Arimetco Facilities Operable Unit 8, Anaconda Copper Yerington Mine. San Francisco: US Environmental Protection Agency.
Water Management Consultants. 2006. Fort Knox Mine, closure management plan for the proposed heap leach facility. Denver: Water Management Consultants.

Information & Authors

Information

Published In

Go to Journal of Geotechnical and Geoenvironmental Engineering
Journal of Geotechnical and Geoenvironmental Engineering
Volume 144Issue 10October 2018

History

Received: Jun 13, 2017
Accepted: Apr 25, 2018
Published online: Aug 10, 2018
Published in print: Oct 1, 2018
Discussion open until: Jan 10, 2019

Permissions

Request permissions for this article.

Authors

Affiliations

Shahin Ghazizadeh [email protected]
Graduate Research Assistant, Dept. of Civil and Environmental Engineering, Colorado State Univ., Fort Collins, CO 80523. Email: [email protected]
Christopher A. Bareither [email protected]
Assistant Professor, Dept. of Civil and Environmental Engineering, Colorado State Univ., Fort Collins, CO 80523 (corresponding author). Email: [email protected]
Joseph Scalia [email protected]
Assistant Professor, Dept. of Civil and Environmental Engineering, Colorado State Univ., Fort Collins, CO 80523. Email: [email protected]
Charles D. Shackelford [email protected]
Professor and Head, Dept. of Civil and Environmental Engineering, Colorado State Univ., Fort Collins, CO 80523. Email: [email protected]

Metrics & Citations

Metrics

Citations

Download citation

If you have the appropriate software installed, you can download article citation data to the citation manager of your choice. Simply select your manager software from the list below and click Download.

Cited by

View Options

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Media

Figures

Other

Tables

Share

Share

Copy the content Link

Share with email

Email a colleague

Share