Technical Papers
Nov 3, 2014

Thermodynamic and Experimental Studies of Hydrogen Production from Dimethyl Ether Steam Reforming Utilization of Exhaust Gas

Publication: Journal of Energy Engineering
Volume 141, Issue 4

Abstract

In this paper, a thermodynamic equilibrium analysis coupled with experimentation for the hydrogen production from dimethyl ether is performed by total Gibbs free energy minimization method. Heat requirement from the process can be achieved from the exhaust gas of the engine. The effects of temperature of exhaust gas (250–400)°C and ratio of steam to Dimethyl ether (DME) (1.5–5) on the equilibrium compositions, yield of hydrogen and energy efficiency of the system are analyzed. In this way, the most thermodynamic favorable operating conditions have been identified. Experimental study is implemented on a self-designed equipment. Experimental results over the Cu-ZnO-Al2O3-SiO2 catalyst are compared against the results obtained from thermodynamic analysis.

Get full access to this article

View all available purchase options and get full access to this article.

Acknowledgments

This work was supported by Innovation Program of Shanghai Municipal Education Commission under Grant 13YZ115.

References

Aspen Tech [Computer software]. Aspen Plus V11.1 user guide.
Choi, Y., and Stenger, H. G. (2005). “Kinetics, simulation and optimization of methanol steam reformer for fuel cell applications.” J. Power Sources, 142(1–2), 81–91.
Dokamaingam, P., and Assabumrungrat, S. (2009). “Modeling of SOFC with indirect internal reforming operation: Comparison of conventional packed-bed and catalytic coated-wall internal reformer.” Int. J. Hydrogen Energy, 34(1), 410–421.
Faungnawakij, K., Nawin, V., and Tanthapanichakoon, W. (2011). “Evaluation of the thermodynamic equilibrium of the autothermal reforming of dimethyl ether.” Int. J. Hydrogen Energy, 36(10), 5865–5874.
Feng, D. M., Wang, Y. Y., Wang, D., and Wang, J. F. (2009). “Steam reforming of dimethyl ether over Cu-ZnO-AL2O3-ZrO2+ZSM-5: A kinetic study.” Chem. Eng. J., 146(3), 477–485.
Gomes, S. R., Biona, N., Blanchard, G., Rousseau, S., and Bellière-Baca, V. (2012). “Thermodynamic and experimental studies of catalytic reforming of exhaust gas recirculation in gasoline engines.” Appl. Catal. B: Environ., 44–53.
Hemmes, K., and Patil, A. (2008). “Flexible coproduction of hydrogen and power using internal reforming solid oxide fuel cells system.” J. Fuel Cell Sci. Technol., 12(5), 1–5.
Lima, A. S., Iduvirges, C. F., and Malfatti, L. M. (2009). “Thermodynamic analysis of ethanol steam reforming using Gibbs energy minimization method: A detailed study of the conditions of carbon deposition.” Int. J. Hydrogen Energy, 34(10), 4321–4330.
Lin, S. T., Chen, Y. H., Yu, C. C., Liu, Y. C., and Lee, C. H. (2006). “Dynamic modeling and control structure design of an experimental fuel processor.” Int. J. Hydrogen Energy, 31(3), 413–426.
Loukou, A., Frenzel, I., and Klein, J. (2012). “Experimental study of hydrogen production and soot particulate matter emissions from methane rich-combustion in inert porous media.” Int. J. Hydrogen Energy, 37(1), 6686–6696.
Park, J., Bae, J., and Lee, S. (2010). “Numerical analysis of a steam reformer coupled with a combustion burner.” J. Fuel Cell Sci. Technol., 7(6), 1–6.
Park, J., and Lee, S. (2009). “Heat flux analysis of a cylindrical steam reformer by a modified Nusselt number.” Int. J. Hydrogen Energy, 34(3), 1578–1584.
Rossi, C. C. R. S., Alonso, C. G., Antunes, O. A. C., Guirardello, R., and Cardozo-Filho, L. (2009). “Thermodynamic analysis of steam reforming of ethanol and glycerine for hydrogen production.” Int. J. Hydrogen Energy, 34(1), 323–332.
Semelsberger, T. A., Borup, A. L., and Michael, A. (2005). “Thermodynamic equilibrium calculations of dimethyl ether steam reforming and dimethyl ether hydrolysis.” J. Power Soures, 152(1–2), 87–96.
Tanaka, Y. H., and Kikuchi, R. (2005). “Steam reforming of dimethyl ether over composite catalysts of AL2O3 and Cu-based spinel.” Appl. Catal. B, 57(3), 211–222.
Wang, S. Z., Ishihara, T., and Takita, Y. (2002). “Partial oxidation of dimethyl ether over various supported metal catalysts.” Appl. Catal. A, 228(1–2), 167–176.

Information & Authors

Information

Published In

Go to Journal of Energy Engineering
Journal of Energy Engineering
Volume 141Issue 4December 2015

History

Received: Apr 17, 2014
Accepted: Oct 1, 2014
Published online: Nov 3, 2014
Discussion open until: Apr 3, 2015
Published in print: Dec 1, 2015

Permissions

Request permissions for this article.

Authors

Affiliations

College of Automobile Engineering, Shanghai Univ. of Engineering Science, Shanghai 201620, China (corresponding author). E-mail: [email protected]
College of Automobile Engineering, Shanghai Univ. of Engineering Science, Shanghai 201620, China. E-mail: [email protected]
Changshui Wu [email protected]
College of Automobile Engineering, Shanghai Univ. of Engineering Science, Shanghai 201620, China. E-mail: [email protected]

Metrics & Citations

Metrics

Citations

Download citation

If you have the appropriate software installed, you can download article citation data to the citation manager of your choice. Simply select your manager software from the list below and click Download.

Cited by

View Options

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Media

Figures

Other

Tables

Share

Share

Copy the content Link

Share with email

Email a colleague

Share