Application of Carbon Microsphere Loaded with Magnetite Nanoparticles for the Removal of a Cationic Azo Dye: Efficiency and Mechanism
Publication: Journal of Environmental Engineering
Volume 147, Issue 2
Abstract
Methylene blue (MB), a cationic azo dye, is harmful to the environment and human health. In this study, carbon microspheres (CMS)@magnetite was prepared to remove MB. The performance of CMS@magnetite on MB removal and adsorption mechanisms was studied. Transmission electron microscopy, Fourier transform infrared spectroscopy, X-ray photoelectron spectroscopy, Brunauer-Emmett-Teller, X-ray diffraction, and vibrating-sample magnetometry were used to characterize the CMS@magnetite before and after adsorption with MB. The effects of different dosages and initial pH values on MB removal by CMS@magnetite were studied through batch experiments. Results reflected that CMS@magnetite had high removal efficiency on MB. In addition, adsorption isotherms, kinetics, and thermodynamics models were also studied. MB adsorption behavior was better described by the Langmuir model. The experimental data of MB adsorption by CMS@magnetite had a higher fitting degree with a pseudo-second-order kinetic model. In addition, reuse experiments were studied, which showed the advantage of good recycling ability of CMS@magnetite. MB was removed by CMS@magnetite through electrostatic adsorption and interaction. Because of high removal efficiency, easy separation, and high performance of recycling, CMS@magnetite can be potentially used to remove MB wastewater.
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Data Availability Statement
All data, models, and code generated or used during the study appear in the published article.
Acknowledgments
This research was supported by the National Natural Science Foundation of China (No. 51978174), and the Natural Science Foundation of Guangdong Province (No. 2018A030313099).
References
Afshariani, F., and A. Roosta. 2019. “Experimental study and mathematical modeling of biosorption of methylene blue from aqueous solution in a packed bed of microalgae Scenedesmus.” J. Cleaner Prod. 225 (Jul): 133–142. https://doi.org/10.1016/j.jclepro.2019.03.275.
Ahmed, M. J. K., and M. Ahmaruzzaman. 2015. “A facile synthesis of –charcoal composite for the sorption of a hazardous dye from aquatic environment.” J. Environ. Manage. 163 (Nov): 163–173. https://doi.org/10.1016/j.jenvman.2015.08.011.
Ai, L., C. Zhang, F. Liao, Y. Wang, M. Li, L. Meng, and J. Jiang. 2011. “Removal of methylene blue from aqueous solution with magnetite loaded multi-wall carbon nanotube: Kinetic, isotherm and mechanism analysis.” J. Hazard. Mater. 198 (Dec): 282–290. https://doi.org/10.1016/j.jhazmat.2011.10.041.
Ajmal, Z., M. Usman, I. Anastopoulos, A. Qadeer, R. Zhu, A. Wakeel, and R. Dong. 2020. “Use of nano-/micro-magnetite for abatement of cadmium and lead contamination.” J. Environ. Manage. 264 (Jun): 110477. https://doi.org/10.1016/j.jenvman.2020.110477.
Alver, E., A. Ü. Metin, and F. Brouers. 2020. “Methylene blue adsorption on magnetic alginate/rice husk bio-composite.” Int. J. Biol. Macromol. 154 (Jul): 104–113. https://doi.org/10.1016/j.ijbiomac.2020.02.330.
Arora, C., S. Soni, S. Sahu, J. Mittal, P. Kumar, and P. K. Bajpai. 2019. “Iron based metal organic framework for efficient removal of methylene blue dye from industrial waste.” J. Mol. Liq. 284 (Jun): 343–352. https://doi.org/10.1016/j.molliq.2019.04.012.
Bharti, V., et al. 2019. “Biodegradation of methylene blue dye in a batch and continuous mode using biochar as packing media.” Environ. Res. 171 (Apr): 356–364. https://doi.org/10.1016/j.envres.2019.01.051.
Chang, B., D. Guan, Y. Tian, Z. Yang, and X. Dong. 2013. “Convenient synthesis of porous carbon nanospheres with tunable pore structure and excellent adsorption capacity.” J. Hazard. Mater. 262 (Nov): 256–264. https://doi.org/10.1016/j.jhazmat.2013.08.054.
Chen, F., R. Liu, S. Xiao, and C. Zhang. 2014. “Solvothermal synthesis in ethylene glycol and adsorption property of magnetic microspheres.” Mater. Res. Bull. 55 (Jul): 38–42. https://doi.org/10.1016/j.materresbull.2014.03.034.
Chen, Q., and Q. Wu. 2015. “Preparation of carbon microspheres decorated with silver nano-particles and their ability to remove dyes from aqueous solution.” J. Hazard. Mater. 283 (Dec): 193–201. https://doi.org/10.1016/j.jhazmat.2014.09.024.
Das, N., and D. Charumathi. 2012. “Remediation of synthetic dyes from wastewater using yeast—An overview.” Ind. J. Biotechnol. 11 (4): 369–380.
Dashamiri, S., M. Ghaedi, A. Asfaram, F. Zare, and S. Wang. 2017. “Multi-response optimization of ultrasound assisted competitive adsorption of dyes onto –nanoparticle loaded activated carbon: Central composite design.” Ultrason. Sonochem. 34 (Jan): 343–353. https://doi.org/10.1016/j.ultsonch.2016.06.007.
Fu, F., Z. Cheng, D. D. Dionysiou, and B. Tang. 2015. “Fe/Al bimetallic particles for the fast and highly efficient removal of Cr(VI) over a wide pH range: Performance and mechanism.” J. Hazard. Mater. 298 (Nov): 261–269. https://doi.org/10.1016/j.jhazmat.2015.05.047.
Gong, J., B. Wang, G. Zeng, C. Yang, C. Niu, Q. Niu, W. Zhou, and Y. Liang. 2009. “Removal of cationic dyes from aqueous solution using magnetic multi-wall carbon nanotube nanocomposite as adsorbent.” J. Hazard. Mater. 164 (2–3): 1517–1522. https://doi.org/10.1016/j.jhazmat.2008.09.072.
Gusmão, K. A. G., L. V. A. Gurgel, T. M. S. Melo, and L. F. Gil. 2013. “Adsorption studies of methylene blue and gentian violet on sugarcane bagasse modified with EDTA dianhydride (EDTAD) in aqueous solutions: Kinetic and equilibrium aspects.” J. Environ. Manage. 118 (Mar): 135–143. https://doi.org/10.1016/j.jenvman.2013.01.017.
Horikawa, T., N. Sakao, T. Sekida, J. Hayashi, D. D. Do, and M. Katoh. 2012. “Preparation of nitrogen-doped porous carbon by ammonia gas treatment and the effects of N-doping on water adsorption.” Carbon 50 (5): 1833–1842. https://doi.org/10.1016/j.carbon.2011.12.033.
Huang, J., Y. Li, X. Jia, and H. Song. 2019. “Preparation and tribological properties of core-shell microspheres.” Tribol. Int. 129 (Jan): 427–435. https://doi.org/10.1016/j.triboint.2018.08.036.
Jaseela, P. K., J. Garvasis, and A. Joseph. 2019. “Selective adsorption of methylene blue (MB) dye from aqueous mixture of MB and methyl orange (MO) using mesoporous titania ()–polyvinyl alcohol (PVA) nanocomposite.” J. Mol. Liq. 286 (Jul): 110908. https://doi.org/10.1016/j.molliq.2019.110908.
Joshi, S., V. K. Garg, N. Kataria, and K. Kadirvelu. 2019. “Applications of nanoparticles for dye removal from simulated wastewater.” Chemosphere 236 (Dec): 124280. https://doi.org/10.1016/j.chemosphere.2019.07.011.
Kataria, N., and V. K. Garg. 2019. “Application of EDTA modified carbon nanocomposites to ameliorate methylene blue and brilliant green dye laden water.” Environ. Res. 172 (May): 43–54. https://doi.org/10.1016/j.envres.2019.02.002.
Kiayi, Z., T. B. Lotfabad, A. Heidarinasab, and F. Shahcheraghi. 2019. “Microbial degradation of azo dye carmoisine in aqueous medium using saccharomyces cerevisiae ATCC 9763.” J. Hazard. Mater. 373 (Jul): 608–619. https://doi.org/10.1016/j.jhazmat.2019.03.111.
Kushwaha, A. K., N. Gupta, and M. C. Chattopadhyaya. 2014. “Removal of cationic methylene blue and malachite green dyes from aqueous solution by waste materials of Daucus carota.” J. Saudi Chem. Soc. 18 (3): 200–207. https://doi.org/10.1016/j.jscs.2011.06.011.
Li, C., H. Liu, X. Jiang, G. I. N. Waterhouse, Z. Zhang, and L. Yu. 2018. “Hierarchical with a flower-like morphology: A highly efficient and reusable dye adsorbent.” Synth. Met. 246 (Dec): 45–56. https://doi.org/10.1016/j.synthmet.2018.09.010.
Li, X., et al. 2016. “Quaternized magnetic nanoparticles enhance the chemosensitization of multidrug-resistant gastric carcinoma by regulating cell autophagy activity in mice.” J. Biomed. Nanotechnol. 12 (May): 1–14. https://doi.org/10.1166/jbn.2016.2232.
Li, Y., A. R. Zimmerman, F. He, J. Chen, L. Han, H. Chen, X. Hu, and B. Gao. 2020. “Solvent-free synthesis of magnetic biochar and activated carbon through ball-mill extrusion with nanoparticles for enhancing adsorption of methylene blue.” Sci. Total Environ. 722 (Jun): 137972. https://doi.org/10.1016/j.scitotenv.2020.137972.
Liu, S., J. Sun, and Z. Huang. 2010. “Carbon spheres/activated carbon composite materials with high Cr(VI) adsorption capacity prepared by a hydrothermal method.” J. Hazard. Mater. 173 (1–3): 377–383. https://doi.org/10.1016/j.jhazmat.2009.08.086.
Lu, J., F. Fu, L. Zhang, and B. Tang. 2018. “Insight into efficient co-removal of Se(IV) and Cr(VI) by magnetic mesoporous carbon microspheres: Performance and mechanism.” Chem. Eng. J. 346 (Aug): 590–599. https://doi.org/10.1016/j.cej.2018.04.077.
Maazinejad, B., O. Mohammadnia, G. A. M. Ali, A. S. H. Makhlouf, M. N. Nadagouda, M. Sillanpää, A. M. Asiri, S. Agarwal, V. K. Gupta, and H. Sadegh. 2020. “Taguchi () orthogonal array study based on methylene blue removal by single-walled carbon nanotubes-amine: Adsorption optimization using the experimental design method, kinetics, equilibrium and thermodynamics.” J. Mol. Liq. 298 (Jan): 112001. https://doi.org/10.1016/j.molliq.2019.112001.
Mishra, S., and A. Maiti. 2018. “The efficacy of bacterial species to decolourise reactive azo, anthroquinone and triphenylmethane dyes from wastewater: A review.” Environ. Sci. Pollut. Res. 25 (9): 8286–8314. https://doi.org/10.1007/s11356-018-1273-2.
Mubarak, N. M., Y. T. Fo, H. S. Al-Salim, J. N. Sahu, E. C. Abdullah, S. Nizamuddin, N. S. Jayakumar, and P. Ganesan. 2015. “Removal of methylene blue and orange-G from wastewater using magnetic biochar.” Int. J. Nanosci. 14 (4): 1550009. https://doi.org/10.1142/S0219581X1550009X.
Nguyen, C. H., C. C. Fu, and R. S. Juang. 2018. “Degradation of methylene blue and methyl orange by palladium-doped photocatalysis for water reuse: Efficiency and degradation pathways.” J. Cleaner Prod. 202 (Nov): 413–427. https://doi.org/10.1016/j.jclepro.2018.08.110.
Ogura, M., S. Y. Shinomiya, J. Tateno, Y. Nara, M. Nomura, E. Kikuchi, and M. Matsukata. 2001. “Alkali-treatment technique—New method for modification of structural and acid-catalytic properties of ZSM-5 zeolites.” Appl. Catal. A: Gen. 219 (1–2): 33–43. https://doi.org/10.1016/S0926-860X(01)00645-7.
Pang, J., F. Fu, Z. Ding, J. Lu, N. Li, and B. Tang. 2017. “Adsorption behaviors of methylene blue from aqueous solution on mesoporous birnessite.” J. Taiwan Inst. Chem. Eng. 77 (Aug): 168–176. https://doi.org/10.1016/j.jtice.2017.04.041.
Rani, S., and G. D. Varma. 2015. “Superparamagnetism and metamagnetic transition in nanoparticles synthesized via co-precipitation method at different pH.” Phys. B 472 (Sep): 66–77. https://doi.org/10.1016/j.physb.2015.05.016.
Ryu, J., Y. W. Suh, D. J. Suh, and D. J. Ahn. 2010. “Hydrothermal preparation of carbon microspheres from mono-saccharides and phenolic compounds.” Carbon 48 (7): 1990–1998. https://doi.org/10.1016/j.carbon.2010.02.006.
Saini, J., V. K. Garg, R. K. Gupta, and N. Kataria. 2017. “Removal of orange G and rhodamine B dyes from aqueous system using hydrothermally synthesized zinc oxide loaded activated carbon (ZnO-AC).” J. Environ. Chem. Eng. 5 (1): 884–892. https://doi.org/10.1016/j.jece.2017.01.012.
Shao, M., F. Ning, J. Zhao, M. Wei, D. G. Evans, and X. Duan. 2012. “Preparation of double hydroxide core-shell microspheres for magnetic separation of proteins.” J. Am. Chem. Soc. 134 (2): 1071–1077. https://doi.org/10.1021/ja2086323.
Sun, X., J. Liu, and Y. Li. 2006. “Use of carbonaceous polysaccharide microspheres as templares for fabricating metal oxide hollow spheres.” Chem. Eur. J. 12 (7): 2039–2047. https://doi.org/10.1002/chem.200500660.
Sun, X., L. Yang, Q. Li, J. Zhao, X. Li, X. Wang, and H. Liu. 2014. “Amino-functionalized magnetic cellulose nanocomposite as adsorbent for removal of Cr(VI): Synthesis and adsorption studies.” Chem. Eng. J. 241 (Apr): 175–183. https://doi.org/10.1016/j.cej.2013.12.051.
Tomul, F., Y. Arslan, F. T. Başoğlu, Y. Babuçcuoğlu, and H. N. Tran. 2019. “Efficient removal of anti-inflammatory from solution by Fe-containing activated carbon: Adsorption kinetics, isotherms, and thermodynamics.” J. Environ. Manage. 238 (May): 296–306. https://doi.org/10.1016/j.jenvman.2019.02.088.
Wang, P., M. Cao, C. Wang, Y. Ao, J. Hou, and J. Qian. 2014. “Kinetics and thermodynamics of adsorption of methylene blue by a magnetic graphene-carbon nanotube composite.” Appl. Surf. Sci. 290 (Jan): 116–124. https://doi.org/10.1016/j.apsusc.2013.11.010.
Wu, Q., W. Li, J. Tan, X. Nan, and S. Liu. 2015. “Hydrothermal synthesis of magnetic mesoporous carbon microspheres from carboxymethylcellulose and nickel acetate.” Appl. Surf. Sci. 332 (Mar): 354–361. https://doi.org/10.1016/j.apsusc.2015.01.195.
Xia, H., Y. Wan, G. Yuan, Y. Fu, and X. Wang. 2013. “ core-shell nanotubes as promising anode materials for lithium-ion batteries.” J. Power Sources 241 (Nov): 486–493. https://doi.org/10.1016/j.jpowsour.2013.04.126.
Xie, X., N. Liu, F. Yang, Q. Zhang, X. Zheng, Y. Wang, and J. Liu. 2018. “Comparative study of antiestrogenic activity of two dyes after Fenton oxidation and biological degradation.” Ecotoxicol. Environ. Saf. 164 (Nov): 416–424. https://doi.org/10.1016/j.ecoenv.2018.08.012.
Yang, Y., S. Qi, and J. Wang. 2012. “Characterization of a microwave absorbent prepared by coprecipitation reaction of iron oxide on the surface of graphite nanosheet.” Mater. Sci. Eng. 177 (20): 1734–1740. https://doi.org/10.1016/j.mseb.2012.08.027.
Zargar, B., H. Parham, and M. Rezazade. 2011. “Fast removal and recovery of methylene blue by activated carbon modified with magnetic iron oxide nanoparticles.” J. Chin. Chem. Soc. 58 (5): 694–699. https://doi.org/10.1002/jccs.201190108.
Zhang, L., F. Fu, and B. Tang. 2019. “Adsorption and redox conversion behaviors of Cr(VI) on goethite/carbon microspheres and akaganeite/carbon microspheres composites.” Chem. Eng. J. 356 (Jan): 151–160. https://doi.org/10.1016/j.cej.2018.08.224.
Zhao, F., E. Repo, D. Yin, Y. Meng, S. Jafari, and M. Sillanpää. 2015. “EDTA-cross-linked -cyclodextrin: An environmentally friendly bifunctional adsorbent for simultaneous adsorption of metals and cationic dyes.” Environ. Sci. Technol. 49 (17): 10570–10580. https://doi.org/10.1021/acs.est.5b02227.
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Received: Jul 14, 2020
Accepted: Sep 14, 2020
Published online: Nov 20, 2020
Published in print: Feb 1, 2021
Discussion open until: Apr 20, 2021
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