Utilization of Lignocellulosic Waste for Acridine Orange Uptake: Insights into Multiparameter Isotherms Modeling with ANN-Aimed Formulation
Publication: Journal of Environmental Engineering
Volume 146, Issue 9
Abstract
For the first time, a comprehensive study of 35 multiparameter isotherm models was conducted to describe the dynamics of the adsorption of acridine orange (AO) dye on an abundantly available agricultural waste, i.e., overripe Abelmoschus esculentus seedpods. The purpose of this work is to assess the most reliable model for the design and development of an effective batch adsorber system. Analysis of experimental isotherm data was done by scrutinizing one-, two-, three-, four-, and five-parameter models at three different temperatures to understand specific parameters for the design process. Detailed error analysis is carried out to check the accuracy and adequacy of the best fitting isotherm model for experimental data. The isotherm data are in good agreement with the Fritz-Schlunder-V model. Later, experimental data are extensively investigated for dye-biosorbent/dye interactions through Fowler-Guggenheim, Flory-Huggins, Kiselev, Frumkin, Hill-de Boer, and El-Awady isotherm modeling. As a result, the adsorption phenomenon that provides evidence of a multilayer formation shows an attractive interaction between the adsorbed species and the adsorbent surface. Most importantly, an artificial neural network (ANN)-based empirical model was developed to illustrate the dye sequestration process. The ANN-predicted and experimentally observed results were compared () to test the accuracy of the model.
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Data Availability Statement
All data, models, and code generated or used during the study appear in the published article.
Acknowledgments
The authors express their gratitude to the Indian Institute of Technology, Kharagpur, for providing the necessary facilities for the study and to the Ministry of Human Resource Development, Government of India, for financial support. The authors also thank Prof. Debabrata Pradhan (Materials Science Centre) and Prof. Tarasankar Pal (Dept. of Chemistry) for their help in BET adsorption-desorption measurements.
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Journal of Environmental Engineering
Volume 146 • Issue 9 • September 2020
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©2020 American Society of Civil Engineers.
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Received: Aug 30, 2019
Accepted: Mar 16, 2020
Published online: Jun 26, 2020
Published in print: Sep 1, 2020
Discussion open until: Nov 26, 2020
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