Technical Papers
Jun 25, 2019

Heavy Metal Removal and Leaching from Pervious Concrete Filter: Influence of Operating Water Head and Reduced Graphene Oxide Addition

Publication: Journal of Environmental Engineering
Volume 145, Issue 9

Abstract

The effects of an operating water head (OWH) and reduced graphene oxide (RGO) addition on the pervious concrete filter (PCF) and heavy metals interaction were investigated in the present study. Five simulated wastewaters containing Cd, Zn, Cu, Pb, and these four ions mixed together were filtered by PCF monoliths, considering the influence of three OWHs, viz. 30 cm, 7.5 cm, and trickling water head. The metal ions fixation degree increased with decreasing levels of OWH, which indicates that empty bed contact time influences PCF performance. Additionally, heavy metals removal and leaching from 0.06 wt% RGO modified PCF (G-PCF) and plain PCF were examined by first passing the five wastewater samples, immediately followed with strong acidic water, while maintaining the same flow and time. As a consequence of acid water passage, the fixated ions were seen to leach out from PCFs, but the RGO’s strong reinforcement substantially reduced such leaching degree and additionally improved the simultaneous removal of four heavy metals. Although the estimated cost of G-PCF was relatively higher than plain PCF, both these filters appear highly efficient and inexpensive, unlike treatment units that are currently used by the electroplating industry for heavy metals removal.

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Acknowledgments

The authors thank the Civil Engineering Department of the Indian Institute of Technology (IIT) Madras for supporting our research and Professor Pradeep’s Research Group of IIT Madras for providing access to their ICP-MS facility, which is sincerely acknowledged.

References

ACI (American Concrete Institute). 2010. Report on pervious concrete. ACI 522R. Farmington Hills, MI: ACI.
Ahmaruzzaman, M. 2011. “Industrial wastes as low-cost potential adsorbents for the treatment of wastewater laden with heavy metals.” Adv. Colloid Interface Sci. 166 (1): 36–59. https://doi.org/10.1016/j.cis.2011.04.005.
ASTM. 2012. Standard test method for density and void content of freshly mixed pervious concrete. ASTM C1688. West Conshohocken, PA: ASTM.
Bae, S., F. Hikaru, M. Kanematsu, C. Yoshizawa, T. Noguchi, Y. Yu, and J. Ha. 2018. “Removal of hexavalent chromium in portland cement using ground granulated blast-furnace slag powder.” Materials 11 (1): 11. https://doi.org/10.3390/ma11010011.
BIS (Bureau of Indian Standards). 1959. Methods of tests for strength of concrete. IS 516. New Delhi, India: BIS.
BIS (Bureau of Indian Standards). 1970. Specification for coarse and fine aggregates from natural sources for concrete. IS 383. New Delhi, India: BIS.
BIS (Bureau of Indian Standards). 2013. Ordinary portland cement, 53 grade—Specification. IS 12269. New Delhi, India: BIS.
CPCB (Central Pollution Control Board). 2008. Status of water treatment plants in India. Kolkata, India: CPCB.
CPCB (Central Pollution Control Board). 2015. Global good practices in industrial wastewater treatment and disposal/reuse, with special reference to common effluent treatment plants. Kolkata, India: CPCB.
CWC (Central Water Commission). 2014. Status of trace and toxic metals in Indian rivers. New Delhi, India: CWC.
Ekolu, S. O., F. Z. Azene, and S. Diop. 2014. “A concrete reactive barrier for acid mine drainage treatment.” Proc. Inst. Civ. Eng. 167 (7): 373. https://doi.org/10.1680/wama.13.00035.
Fahim, N. F., B. N. Barsoum, A. E. Eid, and M. S. Khalil. 2006. “Removal of chromium(III) from tannery wastewater using activated carbon from sugar industrial waste.” J. Hazard. Mater. 136 (2): 303–309. https://doi.org/10.1016/j.jhazmat.2005.12.014.
Gaitero, J., Y. Sáez de Ibarra, E. Erkizia, and I. Campillo. 2006. “Silica nanoparticle addition to control the calcium-leaching in cement-based materials.” Phys. Status Solidi A 203 (6): 1313–1318. https://doi.org/10.1002/pssa.200566168.
Gaitero, J., W. Zhu, and I. Campillo. 2009. Multi-scale study of calcium leaching in cement pastes with silica nanoparticles: Nanotechnology in Construction 3, 193–198. Berlin: Springer.
Giergiczny, Z., and A. Król. 2008. “Immobilization of heavy metals (Pb, Cu, Cr, Zn, Cd, Mn) in the mineral additions containing concrete composites.” J. Hazard. Mater. 160 (2): 247–255. https://doi.org/10.1016/j.jhazmat.2008.03.007.
Guo, B., B. Liu, J. Yang, and S. Zhang. 2017. “The mechanisms of heavy metal immobilization by cementitious material treatments and thermal treatments: A review.” J. Environ. Manage. 193: 410–422. https://doi.org/10.1016/j.jenvman.2017.02.026.
Haselbach, L., C. Poor, and J. Tilson. 2014. “Dissolved zinc and copper retention from stormwater runoff in ordinary portland cement pervious concrete.” Constr. Build. Mater. 53: 652–657. https://doi.org/10.1016/j.conbuildmat.2013.12.013.
Hills, C. D., and S. J. T. Pollard. 1997. “The influence of interference effects on the mechanical, microstructural and fixation characteristics of cement-solidified hazardous waste forms.” J. Hazard. Mater. 52 (2): 171–191. https://doi.org/10.1016/S0304-3894(96)01806-7.
Hummers, W. S., and R. E. Offeman. 1958. “Preparation of graphitic oxide.” J. Am. Chem. Soc. 80 (6): 1339. https://doi.org/10.1021/ja01539a017.
Jiang, W., A. Sha, J. Xiao, Y. Li, and Y. Huang. 2015. “Experimental study on filtration effect and mechanism of pavement runoff in permeable asphalt pavement.” Constr. Build. Mater. 100: 102–110. https://doi.org/10.1016/j.conbuildmat.2015.09.055.
Li, D., M. B. Muller, S. Gilje, R. B. Kaner, and G. G. Wallace. 2008. “Processable aqueous dispersions of graphene nanosheets.” Nat. Nanotechnol. 3 (2): 101–105. https://doi.org/10.1038/nnano.2007.451.
Luck, J. D., S. R. Workman, M. S. Coyne, and S. F. Higgins. 2008. “Solid material retention and nutrient reduction properties of pervious concrete mixtures.” Biosyst. Eng. 100 (3): 401–408. https://doi.org/10.1016/j.biosystemseng.2008.03.011.
Madsen, H. T., and E. G. Søgaard. 2013. “Anvendelse på Danske Vandværker” [Groundwater chemistry and treatment: Application to Danish Waterworks]. In Water treatment, 223–246. London: INTECH Open.
Mondal, P., S. Shah, L. Marks, and J. Gaitero. 2010. “Comparative study of the effects of microsilica and nanosilica in concrete.” Transportation Res. Rec. 2141 (1): 6–9. https://doi.org/10.3141/2141-02.
Murugan, M., M. Santhanam, S. S. Gupta, T. Pradeep, and S. P. Shah. 2016. “Influence of 2D rGO nanosheets on the properties of OPC paste.” Cem. Concr. Compos. 70: 48–59. https://doi.org/10.1016/j.cemconcomp.2016.03.005.
Muthu, M., and M. Santhanam. 2018. “Effect of reduced graphene oxide, alumina and silica nanoparticles on the deterioration characteristics of portland cement paste exposed to acidic environment.” Cem. Concr. Compos. 91: 118–137. https://doi.org/10.1016/j.cemconcomp.2018.05.005.
Muthu, M., M. Santhanam, and M. Kumar. 2018. “Pb removal in pervious concrete filter: Effects of accelerated carbonation and hydraulic retention time.” Constr. Build. Mater. 174: 224–232. https://doi.org/10.1016/j.conbuildmat.2018.04.116.
Napia, C., T. Sinsiri, C. Jaturapitakkul, and P. Chindaprasirt. 2012. “Leaching of heavy metals from solidified waste using portland cement and zeolite as a binder.” Waste Manage. 32 (7): 1459–1467. https://doi.org/10.1016/j.wasman.2012.02.011.
Pan, Z., L. He, L. Qiu, A. H. Korayem, G. Li, J. W. Zhu, F. Collins, D. Li, W. H. Duan, and M. C. Wang 2015. “Mechanical properties and microstructure of a graphene oxide-cement composite.” Cem. Concr. Compos. 58: 140–147. https://doi.org/10.1016/j.cemconcomp.2015.02.001.
Paria, S., and P. K. Yuet. 2006. “Solidification-stabilization of organic and inorganic contaminants using portland cement: A literature review.” Environ. Rev. 14 (4): 217–255. https://doi.org/10.1139/a06-004.
Sanchez, F., and K. Sobolev. 2010. “Nanotechnology in concrete–A review.” Constr. Build. Mater. 24 (11): 2060–2071. https://doi.org/10.1016/j.conbuildmat.2010.03.014.
Sen Gupta, S., V. Manoj Siva, S. Krishnan, T. S. Sreeprasad, P. K. Singh, T. Pradeep, and S. K. Das. 2011. “Thermal conductivity enhancement of nanofluids containing graphene nanosheets.” J. Appl. Phys. 110 (8): 084302. https://doi.org/10.1063/1.3650456.
Shabalala, A. N., S. O. Ekolu, S. Diop, and F. Solomon. 2017. “Pervious concrete reactive barrier for removal of heavy metals from acid mine drainage–Column study.” J. Hazard. Mater. 323: 641–653. https://doi.org/10.1016/j.jhazmat.2016.10.027.
Sitko, R., E. Turek, B. Zawisza, E. Malicka, E. Talik, J. Heimann, A. Gagor, B. Feist, and R. Wrzalik. 2013. “Adsorption of divalent metal ions from aqueous solutions using graphene oxide.” Dalton Trans. 42 (16): 5682–5689. https://doi.org/10.1039/c3dt33097d.
Solpuker, U., J. Sheets, Y. Kim, and F. W. Schwartz. 2014. “Leaching potential of pervious concrete and immobilization of Cu, Pb and Zn using pervious concrete.” J. Contam. Hydrol. 161: 35–48. https://doi.org/10.1016/j.jconhyd.2014.03.002.
Sonebi, M., and M. Bassuoni. 2013. “Investigating the effect of mixture design parameters on pervious concrete by statistical modelling.” Constr. Build. Mater. 38: 147–154. https://doi.org/10.1016/j.conbuildmat.2012.07.044.
Sreeprasad, T. S., S. S. Gupta, S. M. Maliyekkal, and T. Pradeep. 2013. “Immobilized graphene-based composite from asphalt: Facile synthesis and application in water purification.” J. Hazard. Mater. 246: 213–220. https://doi.org/10.1016/j.jhazmat.2012.12.022.
Sreeprasad, T. S., S. M. Maliyekkal, K. Lisha, and T. Pradeep. 2011. “Reduced graphene oxide-metal/metal oxide composites: facile synthesis and application in water purification.” J. Hazard. Mater. 186 (1): 921–931. https://doi.org/10.1016/j.jhazmat.2010.11.100.
Sreeprasad, T. S., and T. Pradeep. 2012. “Graphene for environmental and biological applications.” Int. J. Mod. Phys. B 26 (21): 1242001. https://doi.org/10.1142/S0217979212420015.
Stumm, W., and J. J. Morgan. 2012. Aquatic chemistry: Chemical equilibria and rates in natural waters. New York: Wiley.
Tantawy, M. A., S. A. Ahmed, E. M. Abdalla, and M. I. Qassim. 2016. “Immobilization of copper ions laden kaolin waste: Influence of thermal treatment on its immobilization in cement paste.” J. Mater. Cycles Waste Manage. 18 (2): 263–272. https://doi.org/10.1007/s10163-014-0328-9.
Wang, M., R. Wang, H. Yao, S. Farhan, S. Zheng, and C. Du. 2016. “Study on the three dimensional mechanism of graphene oxide nanosheets modified cement.” Constr. Build. Mater. 126: 730–739. https://doi.org/10.1016/j.conbuildmat.2016.09.092.
Wang, Y., F. Han, and J. Mu. 2018. “Solidification/stabilization mechanism of Pb(II), Cd(II), Mn(II) and Cr(III) in fly ash based geopolymers.” Constr. Build. Mater. 160: 818–827. https://doi.org/10.1016/j.conbuildmat.2017.12.006.
Wang, Z., Z. Chen, J. Chang, J. Shen, J. Kang, and Q. Chen. 2015. “Fabrication of a low-cost cementitious catalytic membrane for p-chloronitrobenzene degradation using a hybrid ozonation-membrane filtration system.” Chem. Eng. J. 262: 904–912. https://doi.org/10.1016/j.cej.2014.10.033.
Wei, D., and Y. Liu. 2010. “Controllable synthesis of graphene and its applications.” Adv. Mater. 22 (30): 3225–3241. https://doi.org/10.1002/adma.200904144.
Żak, R., and J. Deja. 2015. “Spectroscopy study of Zn, Cd, Pb and Cr ions immobilization on C-S–H phase.” Spectrochim. Acta Part A Mol. Biomol. Spectrosc. 134: 614–620. https://doi.org/10.1016/j.saa.2014.06.069.
Zha, X., H. Wang, P. Xie, C. Wang, P. Dangla, and J. Ye. 2016. “Leaching resistance of hazardous waste cement solidification after accelerated carbonation.” Cem. Concr. Compos. 72: 125–132. https://doi.org/10.1016/j.cemconcomp.2016.06.001.

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Go to Journal of Environmental Engineering
Journal of Environmental Engineering
Volume 145Issue 9September 2019

History

Received: Jun 22, 2018
Accepted: Dec 26, 2018
Published online: Jun 25, 2019
Published in print: Sep 1, 2019
Discussion open until: Nov 25, 2019

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Research Fellow, School of Civil and Environmental Engineering, Nanyang Technological Univ., 50 Nanyang Ave., Singapore 639798. ORCID: https://orcid.org/0000-0002-9961-9334
Krishnan Chandrasekharapuram Ramakrishnan https://orcid.org/0000-0001-8330-1586
Ph.D. Candidate, Center of Excellence in Advanced Materials and Green Technologies, Amrita Vishwa Vidyapeetham, Amritanagar, Ettimadai, Coimbatore, Tamil Nadu 641112, India. ORCID: https://orcid.org/0000-0001-8330-1586
Manu Santhanam, M.ASCE [email protected]
Professor, Building Technology and Construction Management Division, Dept. of Civil Engineering, Indian Institute of Technology Madras, Chennai, Tamil Nadu 600036, India (corresponding author). Email: [email protected]
Professor, Dept. of Chemical Engineering and Materials Science, Amrita Vishwa Vidyapeetham, Amritanagar, Ettimadai, Coimbatore, Tamil Nadu 641112, India. ORCID: https://orcid.org/0000-0003-0276-4808
Mathava Kumar
Associate Professor, Environmental and Water Resources Engineering Division, Dept. of Civil Engineering, Indian Institute of Technology Madras, Chennai, Tamil Nadu 600036, India.

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