Visible Light Photocatalytic Ozonation of Oxalic Acid by Composite
Publication: Journal of Environmental Engineering
Volume 144, Issue 8
Abstract
composite is prepared and characterized by X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD), X-ray fluorescence (XRF), ultraviolet–visible (UV-vis) spectroscopy, and surface area analysis. The prepared composite is used as a catalyst to examine the performance of visible light photocatalytic ozonation. The results prove that the composite has good catalytic activity for oxalic acid removal during the photocatalytic ozonation process. Compared with bare , the increases the removal of oxalic acid from 24.8 to 91.2% in 60 min. The manganese combined in the mainly exists in the form of oxide with valences of III and IV. The oxalic acid removal is partly through the oxidation by reactive oxygen species such as and partly through the charge transfer between different valences of manganese species, whereas accounts for only a negligible part of the oxalic acid removal.
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Acknowledgments
The authors thank the National Natural Science Foundation of China (No. 51208299), Innovation Program of Shanghai Municipal Education Commission (No. 15ZZ075), Cultivation Project for Chinese Natural Science Foundation (No. ZR17YQ02), Science and Technology Development Project supported by University of Shanghai for Science and Technology (Grant Nos. 16KJFZ060 & 2017KJFZ081), China Postdoctoral Science Foundation (No. 2017M611590), and the Hujiang Foundation of China (B14003) for funding support.
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©2018 American Society of Civil Engineers.
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Received: Dec 1, 2017
Accepted: Feb 8, 2018
Published online: May 30, 2018
Published in print: Aug 1, 2018
Discussion open until: Oct 30, 2018
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