Technical Papers
Dec 14, 2017

Methane Transport through Simulated Landfill Covers with a PE Geofilm or Ethylene-Vinyl Alcohol, LLDPE, or PVC Geomembrane

Publication: Journal of Environmental Engineering
Volume 144, Issue 2

Abstract

Methane transport was evaluated using column tests for simulated interim cover profiles composed of soil only or soil over a geomembrane (GM). Tests were conducted with a co-extruded GM of ethylene-vinyl alcohol (EVOH), a linear low-density polyethylene (LLDPE) GM, a polyvinyl chloride (PVC) GM, or a polyethylene (PE) geofilm used in conjunction with one of three soils (clay, silt, or sand). Methane breakthrough from the simulated covers with LLDPE and PVC GMs (6–8 days) was approximately three times more rapid relative to the cover with the EVOH GM (22 days). Breakthrough from the simulated cover with a geofilm (2 days) was ten times more rapid relative to the cover with the EVOH GM. Methane diffusion coefficients for the co-extruded EVOH GM obtained by inversion of the column data were 190–290 times lower than diffusion coefficients for the conventional GMs and the 0.1-mm PE geofilm. Soil type had minimal influence on methane transport through the interim covers relative to GM type. Predictions made with a numerical model parameterized using diffusion coefficients obtained from the column tests indicate that methane fluxes from interim landfill covers with an EVOH GM are approximately two orders of magnitude lower than methane fluxes from an interim cover with a conventional GM and six orders magnitude of lower than with soil alone.

Get full access to this article

View all available purchase options and get full access to this article.

Acknowledgments

Financial support for this study was provided by Kuraray Co., Ltd. Support for Benson was provided by the U.S. Department of Energy through the Consortium for Risk Evaluation with Stakeholder Participator (CRESP). The opinions, findings, and conclusions expressed herein are solely those of the authors and may not reflect those of Kuraray Co., Ltd.

References

Abichou, T., et al. (2006). “Methane flux and oxidation at two types of intermediate landfill covers.” Waste Manage., 26(11), 1305–1312.
Aitchison, E. (1993). “Options for reducing-methane emission from landfill sites.” Methane and nitrous oxide: Methods in national emissions inventories and options for control, A. R. van Amstel, ed., International IPCC Workshop, Amersfoort, Netherlands, Z-230.
ASTM. (2013a). “Standard test method for index puncture resistance of geomembranes and related products.” ASTM D4833 M-07, West Conshohocken, PA.
ASTM. (2013b). “Standard test method for tear resistance (graves tear) of plastic film and sheeting.” ASTM D1004-13, West Conshohocken, PA.
ASTM. (2015a). “Standard test method for determining tensile properties of nonreinforced polyethylene and nonreinforced flexible polypropylene geomembranes.” ASTM D6693 M-04, West Conshohocken, PA.
ASTM. (2015b). “Standard test method for measuring core thickness of textured geomembranes.” ASTM D5944 M-10, West Conshohocken, PA.
Benson, C. H., Edil, T. B., and Wang, X. (2012). “Evaluation of a final cover slide at a landfill with recirculating leachate.” Geotext. Geomembr., 35(11–12), 100–106.
Boeckx, P., Van Cleemput, O., and Villaralvo, I. (1996). “Methane emission from a landfill and the methane oxidation capacity of its covering soil.” Soil Biol. Biochem., 28(10–11), 1397–1405.
Bogner, J., and Matthews, E. (2003). “Global methane emissions from landfills: New methodology and annual estimates 1980-1996.” Global Biogeochem. Cycles, 17(2), 1065.
Byun, Y. J., et al. (2007). “Physical and chemical properties of γ-irradiated EVOH film.” Radiat. Phys. Chem., 76(6), 974–981.
Currie, J. A. (1961). “Gaseous diffusion in porous media. Part 3: Wet granular materials.” Br. J. Appl. Phys, 12(6), 275–281.
Czepiela, P. M., et al. (2003). “The influence of atmospheric pressure on landfill methane emissions.” Waste Manage., 23(7), 593–598.
Didier, G., Bouazza, A., and Cazaus, D. (2000). “Gas permeability of geosynthetic clay liners.” Geotext. Geomembr., 18(2–4), 235–250.
Eun, J., Tinjum, J. M., Benson, C. H., and Edil, T. B. (2014). “Volatile organic compound (VOC) transport through composite liner with co-extruded geomembrane containing ethylene vinyl-alcohol (EVOH).” Geo-Congress 2014, ASCE, Reston, VA.
Eun, J., Tinjum, J. M., Benson, C. H., and Edil, T. B. (2017a). “Comparison of volatile organic compound transport in composite liners with HDPE and ethylene-vinyl alcohol coextruded geomembranes.” J. Geotech. Geoenviron. Eng., 04017010.
Eun, J., Tinjum, J. M., Benson, C. H., and Edil, T. B. (2017b). “Equivalent transport parameters for volatile organic compounds (VOCs) in co-extruded geomembrane containing ethylene-vinyl alcohol (EVOH).” J. Geotech. Geoenviron. Eng., in press.
Foose, G. J., Benson, C. H., and Edil, T. B. (2001). “Analytical equations for predicting concentration and mass flux from composite liners.” Geosynthetics Int., 8(6), 551–575.
Foose, G. J., Benson, C. H., and Edil, T. B. (2002). “Comparison of solute transport in three composite liners.” J. Geotech. Geoenviron. Eng., 391–403.
Freeze, R. A., and Cherry, J. A. (1979). Ground water, Prentice-Hall, Englewood Cliffs, NJ.
George, S. C., and Thomas, S. (2001). “Transport phenomena through polymeric systems.” Prog. Polym. Sci., 26(6), 985–1017.
Grabel, A. R., and Siemer, E. G. (1968). “Effects of bulk density, aggregate size, and soil water suction on oxygen diffusion, redox potentials, and elongation of corn roots.” Soil Sci. Soc. Am. J., 32(2), 180–186.
Gradwell, M. W. (1961). “A laboratory study of the diffusion of oxygen through pasture topsoils.” New Zealand J. Sci., 4(2), 250–270.
Hashimoto, I., Deshpande, K. B., and Thomas, H. C. (1964). “Peclet numbers and retardation factors for ion exchange columns.” Ind. Eng. Chem. Fundam., 3(3), 213–218.
Haxo, H. E. (1990). “Determining the transport through geomembranes of various permeants in different applications.” ASTM STP1081, West Conshohocken, PA.
Haxo, H. E., and Lahey, T. P. (1988). “Transport of dissolved organics from dilute aqueous solutions through flexible membrane liners.” Hazard. Waste Hazard. Mater., 5(4), 275–294.
Haxo, H. E., Miedema, J. A., and Nelson, N. A. (1984). “Permeability of polymeric membrane lining materials.” Proc., Int. Conf. on Geomembrane, Denver, 151–156.
Haxo, H. E., and Pierson, P. (1991). “Permeability testing.”, RILEM, New York.
Kim, H., and Benson, C. H. (2004). “Contribution of advective and diffusive oxygen transport through multilayer composite caps over mine waste.” J. Contam. Hydrol., 71(1–4), 193–218.
Lin, H., and Freeman, B. D. (2004). “Gas solubility, diffusivity and permeability in poly (ethylene oxide).” J. Membr. Sci., 239(1), 105–117.
Machaels, A. S., and Bixler, H. J. (1961). “Flow of gases through polyethylene.” J. Polym. Sci., 50, 413–439.
Mackie, K. R., and Cooper, C. D. (2009). “Landfill gas emission prediction using Voronoi diagrams and importance sampling.” Environ. Model. Software, 24(10), 1223–1232.
Mark, H. F., and Gaylord, N. G. (1964). Encyclopedia of polymer and technology: Plastics, resins, rubbers, fibers, Interscience Publishers, New York.
McWatters, R. S., and Rowe, R. K. (2010). “Diffusive transport of VOCs through LLDPE and two coextruded geomembrane.” J. Geotech. Geoenviron. Eng., 1167–1177.
McWatters, R. S., and Rowe, R. K. (2011). “Sorption and diffusion of BTEX through thin-film EVOH.” Geo-Frontiers 2011: Advances in Geotechnical Engineering, ASCE, Reston, VA.
McWatters, R. S., and Rowe, R. K. (2015). “Permeation of volatile organic compounds through thin film membranes and coextruded LLDPE/EVOH/LLDPE geomembranes.” J. Geotech. Geoenviron. Eng., 04014091.
Mor, S., Ravindra, K., De Visscher, A., Dahiya, R. P., and Chandra, A. (2006). “Municipal solid waste characterization and its assessment for potential methane generation: A case study.” Sci. Total Environ., 371(1–3), 1–10.
Park, M. G., Edil, T. B., and Benson, C. H. (2012). “Modeling volatile organic compound transport in composite liners.” J. Geotech. Geoenviron. Eng., 641–657.
Pierson, P., and Barroso, M. (2002). “A pouch test for characterizing gas permeability of geomembranes.” Geosynth. Int., 9(4), 345–372.
Sangam, H., and Rowe, R. (2005). “Effect of surface fluorination on diffusion through a high density polyethylene geomembrane.” J. Geotech. Geoenviron. Eng., 694–704.
Sangam, H. P., and Rowe, R. K. (2001). “Migration of dilute aqueous organic pollutants through HDPE geomembranes.” Geotext. Geomembr., 19(6), 329–357.
Stark, T. D., and Choi, H. (2005). “Methane gas migration through geomembranes.” Geosynth. Int., 12(1), 1–6.
Trembaly, P., Savard, M. M., Vermette, J., and Paquin, R. (2006). “Gas permeability, diffusivity and solubility of nitrogen, helium, methane, carbon dioxide and formaldehyde in dense polymeric membranes using a new on-line permeation apparatus.” J. Membr. Sci., 282, 245–256.
USEPA (U.S. Environmental Protection Agency). (1998). “Greenhouse gas emissions from the management of selected materials.” EPA530-R-98-013, Washington, DC.
USEPA (U.S. Environmental Protection Agency). (2014). “Inventory of U.S. greenhouse gas emissions and sinks: 1990-2014 U.S. Environmental Protection Agency.” ⟨https://www.epa.gov/sites/production/files/2016-04/documents/us-ghg-inventory-2016-main-text.pdf⟩ (Apr. 15, 2016).
Wypych, G. (2008). PVC degradation and stabilization, 1st Ed., ChemTec, ON, Canada.
Zhang, Q., Lin, W., Chen, Q., and Yang, G. (2000). “Phase structure of EVOH copolymers as revealed by variable temperature solid state high resolution. 13C NMR spectroscopy.” Macromolecules, 33(23), 8904–8906.
Zhang, Z., Britt, I. J., and Tung, M. A. (1999). “Water absorption in EVOH films and its influence on glass transition temperature.” J. Polym. Sci., Part B. Polym. Phys., 37(7), 691–699.

Information & Authors

Information

Published In

Go to Journal of Environmental Engineering
Journal of Environmental Engineering
Volume 144Issue 2February 2018

History

Received: Jan 3, 2017
Accepted: Jun 26, 2017
Published online: Dec 14, 2017
Published in print: Feb 1, 2018
Discussion open until: May 14, 2018

Permissions

Request permissions for this article.

ASCE Technical Topics:

Authors

Affiliations

Jongwan Eun, M.ASCE [email protected]
Assistant Professor, Dept. of Civil Engineering, Univ. of Nebraska-Lincoln, Lincoln, NE 68588 (corresponding author). E-mail: [email protected]
James M. Tinjum, M.ASCE [email protected]
Associate Professor, Engineering Professional Development and Geological Engineering, Univ. of Wisconsin-Madison, Madison, WI 53706. E-mail: [email protected]
Craig H. Benson, F.ASCE [email protected]
Dean, School of Engineering and Applied Science and Hamilton Endowed Chair in Engineering, Univ. of Virginia, Charlottesville, VA 22904. E-mail: [email protected]
Tuncer B. Edil, Dist.M.ASCE [email protected]
Professor Emeritus, Dept. of Civil and Environmental and Geological Engineering, Univ. of Wisconsin-Madison, Madison, WI 53706. E-mail: [email protected]

Metrics & Citations

Metrics

Citations

Download citation

If you have the appropriate software installed, you can download article citation data to the citation manager of your choice. Simply select your manager software from the list below and click Download.

Cited by

View Options

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Media

Figures

Other

Tables

Share

Share

Copy the content Link

Share with email

Email a colleague

Share