Technical Papers
Sep 5, 2017

Fabrication, Characterization, and Testing of Graphene Oxide and Hydrophilic Polymer Graphene Oxide Composite Membranes in a Dead-End Flow System

Publication: Journal of Environmental Engineering
Volume 143, Issue 11

Abstract

Graphene oxide (GO) has emerged as a promising material for next-generation water treatment membranes. In this study, three types of GO membranes were produced and tested. Both GO and graphene oxide plus polyvinyl alcohol (GO/PVA) membranes were produced using the vacuum-assisted self-assembly (VASA) method, and a chitosan and graphene oxide composite membrane (CSGO) was assembled using GO as a nanoscale filler via evaporation under reduced pressure. Scanning electron micrographs (SEMs) confirmed that GO and GO/PVA membranes were particularly well ordered, whereas CSGO exhibited reduced ordering attributed to structural and composition differences of GO and CS. The fabricated membranes were tested in a dead-end flow system indicating that each membrane containing GO produced a higher flux at 413 kPa pressure relative to conventional polyamide reverse osmosis (RO) membranes used for benchmark comparison, but was lower in flux to a nanofiltration (NF) membrane. Challenging the membranes with 7.5  mg/L methylene blue solution resulted in 97.5% removal of the dye by all three of the membranes.

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Acknowledgments

This project was funded by the Army Environmental Quality/Installations program, which is funded by the Assistant Secretary of the Army (Acquisition, Logistics, and Technology) and administered by Dr. Elizabeth Ferguson (US Army Engineer Research & Development Center).

References

Bacchin, P., Aimar, P., and Field, R. W. (2006). “Critical and sustainable fluxes: Theory, experiments, and applications.” J. Membr. Sci., 281(1–2), 42–69.
Brame, J., Medina, V. F., Smith, I., and Procell, L. (2016). “Composition of CBRN decontamination effluent and development of surrogate mixtures for testing effluent treatment technologies.”, U.S. Army Engineer Research and Development Center, Vicksburg, MS.
Chen, H., Muller, M. B., Gilmore, K. J., Wallace, G. G., and Li, D. (2008). “Mechanically strong, electrically conductive and biocompatible graphene paper.” Adv. Mater., 20(18), 3557–3561.
Choi, W., Choi, J., Bang, J., and Lee, J. H. (2013). “Layer-by-layer assembly of graphene oxide nanosheets on polyamide membranes for durable reverse-osmosis applications.” ACS Appl. Mater. Interfaces, 5(23), 12510–12519.
Compton, O. C., et al. (2012). “Tuning the mechanical properties of graphene oxide paper and its associated polymer nanocomposites by controlling cooperative intersheet hydrogen bonding.” ACS Nano, 6(3), 2008–2019.
Griggs, C. S., and Medina, V. F. (2016). “Graphene and graphene oxide membranes for water treatment.” McGraw-Hill yearbook of science and technology, 11th Ed., McGraw Hill Publishers, New York.
Han, D., Yan, L., Chen, W., and Li, W. (2011). “Preparation of chitosan/graphene oxide composite film with enhanced mechanical strength in the wet state.” Carbohydr. Polym., 83(2), 653–658.
Hu, W., et al. (2010). “Graphene-based antibacterial paper.” ACS Nano, 4(7), 4317–4323.
Huang, H., Mao, Y., Ying, Y., Liu, Y., Sun, L., and Peng, X. (2013). “Salt concentration, pH and pressure controlled separation of small molecules through lamellar graphene oxide membranes.” Chem. Commun., 49(53), 5963–5965.
Huang, K., et al. (2015). “High-efficiency water-transport channels using the synergistic effect of a hydrophilic polymer and graphene oxide laminates.” Adv. Funct. Mater., 25(36), 5809–5815.
Joshi, R. K., et al. (2014). “Precise and ultrafast molecular sieving through graphene oxide membranes.” Science, 343(6172), 752–754.
Medina, V. F., Johnson, J. L., Waisner, S. A., Wade, R., and Mattei-Sosa, J. (2015). “Development of a treatment process for electrodialysis reversal reject with intermediate softening and secondary reverse osmosis.” J. Environ. Eng., 04015002.
Medina, V. F., Waisner, S. A., Johnson, J. L., Wade, R., Mattei-Sosa, J., and Brown, R. (2012). “Laboratory study for evaluating performance of unit processes to treat the electrodialysis reversal (EDR) reject stream for the proposed fort Irwin water treatment plant.”, U.S. Army Engineer Research and Development Center, Vicksburg, MS.
Mi, B. (2014). “Graphene oxide membranes for ionic and molecular sieving.” Science, 343(6172), 740–742.
Nair, R. R., Wu, H. A., Jayaram, P. N., Grigorieva, I. V., and Geim, A. K. (2012). “Unimpeded permeation of water through helium-leak-tight graphene-based membranes.” Science, 335(6067), 442–444.
Park, S., Dikin, D. A., Nguyen, S. T., and Ruoff, R. S. (2009). “Graphene oxide sheets chemically cross-linked by polyallylamine.” J. Phys. Chem. Lett. C., 113(36), 15801–15804.
Perreault, F., de Faria, A. F., and Elimelech, M. (2015). “Environmental applications of graphene-based nanomaterials.” Chem. Soc. Rev., 44(16), 5861–5896.
Putz, K. W., Compton, O. C., Segar, C., An, Z., Nguyen, S. T., and Brinson, L. C. (2011). “Evolution of order during vacuum-assisted self-assembly of graphene oxide paper and associated polymer nanocomposites.” ACS Nano, 5(8), 6601–6609.
Rinaudo, M., Pavlov, G., and Desbrières, J. (1999). “Influence of acetic acid concentration on the solubilization of chitosan.” Polymer, 40(25), 7029–7032.
Wei, N., Lv, C., and Xu, Z. (2014). “Wetting of graphene oxide: A molecular dynamics study.” Langmuir, 30(12), 3572–3578.
Wei, Z., et al. (2010). “Nanoscale tunable reduction of graphene oxide for graphene electronics.” Science, 328(5984), 1373–1376.
Yeh, C.-N., Raidongia, K., Shao, J., Yang, Q.-H., and Huang, J. (2015). “On the origin of the stability of graphene oxide membranes in water.” Nat. Chem., 7(2), 166–170.

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Published In

Go to Journal of Environmental Engineering
Journal of Environmental Engineering
Volume 143Issue 11November 2017

History

Received: Aug 31, 2016
Accepted: Apr 20, 2017
Published online: Sep 5, 2017
Published in print: Nov 1, 2017
Discussion open until: Feb 5, 2018

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Authors

Affiliations

Victor F. Medina, M.ASCE [email protected]
Research Engineer and Team Leader, U.S. Army Engineer Research and Development Center, Environmental Laboratory, 3909 Halls Ferry Rd., Vicksburg, MS 39180 (corresponding author). E-mail: [email protected]
Christopher S. Griggs [email protected]
Research Chemist, U.S. Army Engineer Research and Development Center, Environmental Laboratory, 3909 Halls Ferry Rd., Vicksburg, MS 39180. E-mail: [email protected]
Brooke Petery [email protected]
Research Engineer, U.S. Army Engineer Research and Development Center, Environmental Laboratory, 3909 Halls Ferry Rd., Vicksburg, MS 39180; formerly, Master’s Candidate, Biomedical Engineering Program, Catholic Univ. of America, 620 Michigan Ave., N.E., Washington, DC 20064. E-mail: [email protected]; [email protected]
Jose Mattei-Sosa [email protected]
Research Chemical Engineer, U.S. Army Engineer Research and Development Center, Environmental Laboratory, 3909 Halls Ferry Rd., Vicksburg, MS 39180. E-mail: [email protected]
Luke Gurtowski [email protected]
Research Engineer, U.S. Army Engineer Research and Development Center, Environmental Laboratory, 3909 Halls Ferry Rd., Vicksburg, MS 39180. E-mail: [email protected]
Scott A. Waisner [email protected]
Research Engineer, U.S. Army Engineer Research and Development Center, Environmental Laboratory, 3909 Halls Ferry Rd., Vicksburg, MS 39180. E-mail: [email protected]
Jay Blodget
Cadet, Army Reserve Officer Training Corps, Dept. of Bioengineering and Biomedical Engineering, Pennsylvania State Univ., 2nd Brigade, 212 Wagner Bldg., University Park, PA 16802-3801.
Robert Moser [email protected]
Research Engineer, U.S. Army Engineer Research and Development Center, Geotechnical and Structures Laboratory, 3909 Halls Ferry Rd., Vicksburg, MS 39180. E-mail: [email protected]

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